Silica Dissolution and Precipitation in Glaciated Volcanic Environments and Implications for Mars
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A. M. Rutledge↗
Engineering topics
A. M. Rutledge
Publications and source records attributed to A. M. Rutledge.
Characterizing Martian X-ray Amorphous Materials through Terrestrial Analogs
X-ray amorphous materials (i.e., lacking long-range crystallographic order) have been identified on the martian surface from orbit and in-situ. Initial models of orbital IR spectral data identified volcanic glasses [e.g., 1], but subsequent interpretations suggested that amorphous silicates are dominantly secondary in nature and formed from water-rock interactions [e.g., 2-4]. ThermalIR spectra from the Mini-Thermal Emission Spectrometer on the Spirit rover show evidence for the amorphous secondary product opaline silica[e.g., 5].X-ray diffraction (XRD) measurements by the CheMin instrument on the Mars Science Laboratory rover have identified 20-70 wt.% amorphous materials in every sample analyzed in Gale crater to date [e.g., 6]. Mass balance calculations using CheMin results and bulk elemental measurements by the Alpha Particle X-ray Spectrometer suggest the amorphous component in Gale crater is variably enriched in Si, Fe, and S[e.g., 7,8].The compositions are not consistent with pure volcanic glass, indicating water must have been involved in the formation of amorphous materials in Gale crater. We seek to better constrain the conditions under which amorphous materials on Mars formed by studying the composition and short-range atomic order of amorphous materials in terrestrial analog environments via XRD and transmission electron microscopy (TEM).
E. B. Rampe↗
Warm-Based Glacial Landforms and Past Climate Signals: Icelandic Eskers as Proxies for Small Sinuous Ridges on Mars
The surface of Mars exhibits plentiful geomorphic evidence for glacial processes, but the history of the cryosphere on Mars remains debated [e.g., 1, 2]. Recent hydrological modeling predicts that warm-based ice sheets on Mars may have resulted in subglacial incised channels (e.g., valley networks) and eskers [3]. Evidence on Mars for warm-based glaciation includes candidate moraines, bedrock channels, and candidate eskers [e.g., 4-6]. Eskers are sinuous ridges comprising glaciofluvial sediments deposited by meltwater flowing through tunnels at the bed of warm-based large glaciers [e.g., 7, 8]. They provide direct evidence of basal melting of ice and preserve glaciofluvial sediments. Warm-based glacial transport is primarily driven by meltwater and can chemically weather the underlying bedrock. An alternative signature of past climate on Mars may thus be the geochemical record, due to alteration by interactions with glacial meltwater, preserved in esker sediments and strata. At present, the sedimentology and stratigraphy of terrestrial eskers is poorly understood. This study will combine sedimentology, geochemistry, and geomorphology to better constrain the unique properties of eskers resulting from warm-based glaciation on Mars-like substrates by leveraging a natural laboratory in Iceland.
A. M. Rutledge↗