ATMOS/ATLAS-3 measurements of Stratospheric Chlorine and Reactive Nitrogen Partitioning Inside and Outside theNovember 1994 Anarctic Vortex
Gives results of studies of the reactive nitrogen family in the Antarctic stratosphere.
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Publications and source records attributed to Abbas, M. M..
Gives results of studies of the reactive nitrogen family in the Antarctic stratosphere.
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The ATMOS Fourier transform spectrometer was flown for a fourth time on the Space Shuttle as part of the ATLAS-3 instrument payload in November 1994. More than 190 sunrise and sunset occultation events provided measurements of more than 30 atmospheric trace gases at latitudes 3-49N and 65-72S, including observations both inside and outside the Antarctic polar vortex.
We compare the mixing rations of N 2 O, CFC-11, CFC-12, CCI 4 , SF 6 , and HCI in the mid-latitude stratosphere measured by the ATMOS Fourier transform spectrometer with in situ measurements acquired aboard the NASA ER-2 aircraft during November 1994. Good agreement is found between ATMOS and in situ correlations of CFC-11, CFC-12, and SF 6 with N 2 O. ATMOS observations of CCI 4 are approx. 15 percent higher than the ER-2 data, but within the systematic uncertainties.
We have compared volume mixing ration profiles of N 2 O, CFC-11, CFC-12, CCI 4 , SF 6 , and HCI measured for the mid-latitude stratosphere by the ATMOS Fourier transform spectrometer during the ATLAS-3 Space Shuttle mission of NOvember 1994 with in situ measurements acquired aboard the NASA ER-2 aircraft during the same time period.
...Descent rates for atmospheric inferred from ATMOS (Atmospheric Trace Molecule Spectroscopy)tracer observations agree well with theoretical estimates obtained using radiative heating calculations...
The stratospheric distribution of H2(O-18) in the 22 to 37 km altitude range has been obtained from balloon-based measurement of far infrared thermal emission spectra with an unapodized spectral resolution of 0.0033/cm. The analysis is based on the observed spectra of 9 isolated spectral lines in the 46 to 72/cm region obtained from four complete limb sequences. Comparison of the results with the statistically expected values indicates enhancement in the H2(O-18) concentrations increasing from 27 + or - 14 percent at 29 km to 40 + or - 23 percent at 37 km. No significant enhancement at lower altitudes was observed.
The mixing ratio profile of N2O5 has been inferred from high-resolution emission spectra obtained with a balloon-borne Fourier spectrometer. The observations were taken for the period from midnight to predawn on September 16, 1986 at 32 deg N latitude. The inferred volume mixing ratio from nighttime average spectra has a peak of about 1.8 x 10 to the -9th in the 32-35 altitude range. The inferred mixing ratio is generally less than the theoretical predictions from a one-dimensional model.
The stratospheric vertical distribution of CO is obtained from balloon-based FIR limb thermal emission spectra by analyzing several limb sequences of the R8 and R1 spectral lines at 34.588 and 49.932/cm, respectively. This constitutes the first determination of the stratospheric CO profile from IR thermal emission spectra. The results, indicating 24.6 + or - 7.6 ppbv at 21 km and 34.4 + or - 10.1 ppbv at 37 km, are compared with the remote-sensing and in situ measurements by other groups and with photochemical-dynamical model calculations.
The distribution of isotopically heavy ozone in the stratosphere has been obtained from analysis of balloon-based high-resolution thermal emission spectra in the far infrared. The mixing ratio profiles of (O-16)(O-16)(O-18) and (O-16)(O-18)(O-16), retrieved from inversion of several limb sequences of a number of spectral lines in the 39-76/cm region, indicate enhancements over the expected values in the 25- to 37-km altitude range. The ratio of total heavy isotopic ozone (10-50)3 to normal (O-48)3 shows enhancements of about 45 percent at 37 km, decreasing to a minimum of about 13 percent at 29 km, and increasing to about 18 percent at 25 km. The results from this work are compared with Mauersberger's (1987) in situ mass spectrometer measurements.
Thermal emission measurements of the earth's stratospheric limb were made with a cryogenically cooled high-resolution Michelson interferometer on a balloon flight launched from Palestine, TX, on Nov. 6, 1984. Infrared spectra for complete limb sequences were obtained over portions of the 700-1940/cm range with an unapodized spectral resolution of 0.03/cm for tangent heights varying from 13 to 39 km. The observed data from 1125 to 1425/cm have been analyzed for simultaneous measurement of O3, H2O, CH4, and N2O profiles. The analysis employs line-by-line and layer-by-layer radiative-transfer calculations, including curvature and refraction effects. The optimum use of geometric and spectral effects is made to obtain sharply peaked weighting functions. Contributions from stratospheric aerosol are included by measuring the light extinction within the window regions of the observed spectra. The retrieved constituent profiles are compared with measurements made with a variety of techniques by other groups. The comparison shows good agreement with the published data for all gases, indicating the capability of retrieving trace gas profiles from high-resolution thermal emission limb measurements.
Limb thermal emission spectra of the earth's stratosphere in the FIR obtained as part of the Balloon Intercomparison Campaign (BIC), have been analyzed for retrieval of trace constituent distributions. The observations analyzed here were made with a balloon-borne high-resolution Michelson interferometer operating in the 20-100/cm region, with an unapodized spectral resolution of 0.0033/cm. In this paper the vertical profiles of O3, H2O, and HDO retrieved from the observed spectra are presented and compared with the results from other BIC experiments. The retrieved profiles are found to be in good agreement with other measurements. The measurement of the HDO profile provides information about the sources of stratospheric water vapor. The variation of the D/H ratio of water vapor is derived from an analysis of HDO and H2O lines observed in the FIR spectra and is compared with the available measurements in the literature.
Far infrared limb thermal emission measurements of the earth's stratosphere were made with a high resolution spectrometer on a balloon payload launched from Palestine, TX, on Oct. 5, 1982. Several limb sequences of a portion of the observed spectra have been analyzed for retrieval of the stratospheric HCN profile from a number of spectral lines in the 32 to 56 cm region. The mixing ratio profile in the 20 to 37 km altitude range has been retrieved with 2-sigma uncertainties of about 4-5 km. The HCN volume mixing ratio is found to be about 139 pptv at 20 km, 127 pptv at 25 km, and increasing to 172 pptv at 37 km. The results are compared with measurements by other groups and with photochemical model calculations reported in the literature.
FIR limb thermal emission spectra obtained from balloon-borne measurements made as a part of the Balloon Intercomparison Campaign (BIC) have been analyzed for retrieval of stratospheric trace-constituent distributions. The measurements were made with a high-resolution Michelson interferometer and covered the 15-180/cm spectral range with an unapodized spectral resolution of 0.0033/cm. The retrieved vertical profiles of O3, H2O, HDO, HCN, CO, and isotopes of O3 are presented. The results are compared with the BIC measurements for O3 and H2O made from the same balloon gondola and with other published data. A comparison of the simultaneously retrieved profiles for several gases with the published data shows good agreement and indicates the validity of the FIR data and retrieval techniques and the accuracy of the inferred profiles.
It is pointed out that the technique of thermal emission spectroscopy provides an effective means for remote sounding of stratospheric temperature structure and constituent distributions. One procedure for measuring the stratospheric infrared spectrum involves the conduction of observations along ray paths tangent to the stratospheric limb. Thermal emission limb tangent observations have certain advantages compared to other types of observations. The techniques for determining temperature and trace gas distributions from limb thermal emission radiances are based on the assumption that the bulk of opacity lies near the tangent point. Ideally, the field of view (FOV) of the observing instrument should be very small. The effect of a finite FOV is to reduce the spatial resolution of the retrieved temperature and constituent profiles. The present investigation is concerned with the effects of the FOV on the inversion of infrared thermal emission measurements for balloon platforms. Attention is given to a convenient method for determining the weighting functions.
Thermal emission measurements of the earth's stratospheric limb from space platforms require an accurate knowledge of the observation angles for retrieval of temperature and constituent distributions. Without the use of expensive stabilizing systems, however, most observational instruments do not meet the required pointing accuracies, thus leading to large errors in the retrieval of atmospheric data. This paper describes a self-constituent method of correcting errors in pointing angles by using information contained in the observed spectrum. Numerical results based on temperature inversions of synthetic thermal emission spectra with assumed random errors in pointing angles are presented.