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Alyea, F. N.

Publications and source records attributed to Alyea, F. N..

29 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Meteorological control of lower stratospheric minor species variations - An observational example

Lower stratospheric air trajectories entering the region over Alaska at the approximately 125 mb level during late May, 1975 indicate a substantial shift in the geographical source regions for the air masses present during that time. This shift coincides with an approximately 25% decrease in the observed halocarbon mixing ratios at the 125 mb level as determined from a daily sequence of halocarbon profiles. Since the halocarbon species measured are essentially chemically inactive at this level, the observed variation is linked to the changing meteorological pattern.

Alyea, F. N.↗
NASA NTRS1977

Relative effects on atmospheric ozone of latitude and altitude of supersonic flight

Three calculations are reported of the potential depletion of ozone by supersonic aircraft. These calculations utilized a two-dimensional model and a three-dimensional photochemical-dynamical model of the atmosphere in which ozone and the dynamical variables of the atmosphere were derived simultaneously. All calculations were based on a continuous atmospheric injection of 1.8 million tons/yr of NO2. Injections of 45 deg N and 20 km, at equilibrium, resulted in a 36% increase in total odd nitrogen between 8 and 38 km and in global ozone depletion of approximately 12%. Injection at 45 deg N and 17 km produced a 27% increase in odd nitrogen, but, because much of this increase occurred below 20 km, the ozone depletion amounted to only 6%. Injection at 10 deg N and 29 km resulted in a 55% increase of odd nitrogen; however, although there was more depletion above 20 km altitude, there was less below that altitude, and the ozone depletion was only 12.5%. In all three calculations, at least half as much ozone depletion occurred in the Southern Hemisphere as in the Northern Hemisphere.

Cunnold, D. M.↗
NASA NTRS1976

The impact of stratospheric variability on measurement programs for minor constituents

The scales of temporal and spatial variations in stratospheric minor species concentrations and dynamical quantities are briefly reviewed. Despite the fact that the stratosphere is often considered to be a very quiescent region of the atmosphere, it exhibits transient and generally unpredictable episodes of intense activity. The resultant necessity for some degree of coordination between different observers in their choice of locations and times for measurements of minor constituents is emphasized. A specific suggestion is provided for one or more short 'International Stratospheric Periods' whose duration would depend upon the time of year. During these short periods, as many observers as possible would perform an integrated series of observations designed to optimize the usefulness of their data to atmospheric scientists.

Prinn, R. G.↗
NASA NTRS1976

Three-dimensional dynamical and chemical modelling of the upper atmosphere

Progress in coding a 3-D upper atmospheric model and in modeling the ozone perturbation resulting from the shuttle booster exhaust is reported. A time-dependent version of a 2-D model was studied and the sulfur cycle in the stratosphere was investigated. The role of meteorology in influencing stratospheric composition measurements was also studied.

Prinn, R. G.↗
NASA NTRS1975

Stratospheric distributions of odd nitrogen and odd hydrogen in a two-dimensional model

A two-dimensional pole-to-pole chemical model of the stratosphere is developed which extends from 8 to 38 km in altitude. Atmospheric motions are simulated by mean vertical and meridional winds and eddy diffusion coefficients. Seasonally averaged distributions of important odd nitrogen (NO, NO2, and HNO3) and odd hydrogen (H, OH, HO2, H2O2) compounds are computed. Photodissociation of N2O leads to production of odd nitrogen in the stratosphere, and the odd nitrogen is ultimately removed by downward transport into the troposphere and by rain-out (modeled by a rain-out lifetime of 30 days below 8-km altitude). Results are presented for a quasi-steady state in which seasonal cycles repeat themselves. These results show significant latitudinal as well as vertical variations in the predicted species which emphasize the need for at least two dimensions in accurate stratospheric modeling. Computed concentrations are compared with observations when they exist.

Prinn, R. G.↗
NASA NTRS1975

Stratospheric ozone destruction by aircraft-induced nitrogen oxides

The preliminary results from a three-dimensional dynamic-chemical model applied to the SST-NOx (NO + NO2) problem are reported. Simulations indicate that a depletion of about 12 per cent in total stratospheric O3 would be realized for a continuous NOx injection rate of 1.8 x 10 to the sixth power metric tons per year from a hypothetical fleet of SST's flying at an altitude of 20 km in the midlatitudes of the Northern Hemisphere. Sixteen per cent of the existing O3 would be destroyed on an annual basis. The model assumes a fleet of about 500 aircraft of the now-canceled American Boeing 2707 type; if only present Anglo-French and Russian SST models, which fly at lower, less harmful altitudes, are built, it will take a fleet of a few thousand such craft to attain an effective injection rate equal to the one above.

Alyea, F. N.↗
NASA NTRS1974

The distributions of odd nitrogen and odd hydrogen in the natural and perturbed stratosphere

In order to quantitatively illustrate the effects of quasi-horizontal transport of certain gases and of the reactions influencing their concentrations, a vertical-meridional pole-to-pole stratospheric model is presented which explicitly predicts concentrations of odd nitrogen and odd hydrogen compounds in the natural stratosphere and also in a perturbed stratosphere incorporating artificial injection of nitrogen oxides by an SST fleet. The northern hemisphere SST operations clearly have a very large local effect on the nitrogen oxide distribution and also have a significant effect on the southern hemisphere. The largest changes are seen at the point of injection of the nitrogen oxides. Results are in agreement with previous one-dimensional models.

Prinn, R. G.↗
NASA NTRS1974

First results of a general circulation model applied to the SST-NOx problem

Results of model runs, one using two-dimensional distribution of NO2 in the unperturbed stratosphere and another including an additional localized source of NO2 to approximate the effect of SSTs, are reported. The general circulation model and chemical reactions are described, and corrections in the previous latitudinal and seasonal gradients of total columnar ozone and the diffusion coefficient in the neighborhood of the tropopause are noted. Excellent agreement with previous observations was obtained. Global distributions of ozone and NO2 are described and represented in graphs. Results indicate ozone reduction of approximately 16% in the Northern Hemisphere and approximately 8% in the Southern Hemisphere, with the mid-latitude source of NO2 apparently having a blocking effect on the horizontal transport of ozone, resulting in larger reductions of ozone at high latitudes than at low ones.

Cunnold, D. M.↗
NASA NTRS1974

A general circulation model of stratospheric ozone

The paper reports on a general circulation model being developed with the ultimate objective of assessing the effect of SST operations on the atmospheric ozone distribution. The model variables are represented in the spectral domain using 79 spherical harmonics and 26 vertical levels between the ground and 70 km. Initial calculations have attempted to simulate the seasonal variations of the unperturbed global ozone distribution. The model shows the presence of a westerly stratospheric jet in the winter hemisphere with amplitudes similar to those observed in the polar night jet. Easterlies dominate in the summer hemisphere. The model also shows ozone to be transported polewards and downwards. Furthermore the annual cycle in ozone concentrations at mid-latitudes has been simulated. Preliminary comparisons are also made with other features of the dynamics and the ozone distribution in the stratosphere.

Cunnold, D. M.↗
NASA NTRS1973

Analysis of the feasibility of an experiment to measure carbon monoxide in the atmosphere

The feasibility of measuring atmospheric carbon monoxide from a remote platform using the correlation interferometry technique was considered. It has been determined that CO data can be obtained with an accuracy of 10 percent using this technique on the first overtone band of CO at 2.3 mu. That band has been found to be much more suitable than the stronger fundamental band at 4.6 mu. Calculations for both wavelengths are presented which illustrate the effects of atmospheric temperature profiles, inversion layers, ground temperature and emissivity, CO profile, reflectivity, and atmospheric pressure. The applicable radiative transfer theory on which these calculations are based is described together with the principles of the technique.

Bortner, M. H.↗