Anion Binding as a Strategy for the Synthesis of Porous Salts
Not Available
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Engineering topics
Antonio, Alexandra M.
Publications and source records attributed to Antonio, Alexandra M..
Manipulating solvent and solubility in the synthesis, activation, and modification of permanently porous coordination cages
Not Available
Deegan, Meaghan M.↗
Atomically Precise Crystalline Materials Based on Kinetically Inert Metal Ions via Reticular Mechanopolymerization
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99 GENERAL AND MISCELLANEOUS↗
Porous metal–organic alloys based on soluble coordination cages
Surface-functionalized porous coordination cages can be used to create homogeneous mixed-cage alloys with high levels of tunability and processability.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Tuning the Porosity, Solubility, and Gas-Storage Properties of Cuboctahedral Coordination Cages via Amide or Ester Functionalization
Abstract not provided
Taggart, Garrett A.↗
Using Low-Pressure Methane Adsorption Isotherms for Higher-Throughput Screening of Methane Storage Materials
Not provided.
Materials Science↗
Atomically Precise Crystalline Materials Based on Kinetically Inert Metal Ions via Reticular Mechanopolymerization
Abstract Atomistic control of the coordination environment of lattice ions and the distribution of metal sites within crystalline mixed‐metal coordination polymers remain significant synthetic challenges. Herein is reported the mechanochemical synthesis of a reticular family of crystalline heterobimetallic metal–organic frameworks (MOFs) is now achieved by polymerization of molecular Ru 2 [II,III] complexes, featuring unprotected carboxylic acid substituents, with Cu(OAc) 2 . The resulting crystalline heterobimetallic MOFs are solid solutions of Ru 2 and Cu 2 sites housed within [M 3 L 2 ] phases. The developed mechanochemical strategy is modular and allows for systematic control of the primary coordination sphere of the Ru 2 sites within an isoreticular family of materials. This strategy is anticipated to provide a rational approach to atomically precise mixed‐metal materials.
Gao, Wen‐Yang↗