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Armagan, G.

Publications and source records attributed to Armagan, G..

Spectroscopic characterization of dynamical processes for Tm,Ho:YAG lasers

The energy transfer processes in Tm,Ho:YAG lasers were investigated in spectral studies and measurements of the temporal response to pulsed excitation. These processes include the population of the 3H4 pump band of Tm, cross-relaxation in Tm, the transfer of energy from Tm to Ho, and various loss mechanisms. It was found that the Tm cross-relaxation is due to a dipole-dipole interaction between Tm ions and that the rate of this process is a function of temperature and ion concentration.

Armagan, G.

Investigation of loss processes of Tm and Tm,Ho in YAG

The loss of excitation from various manifolds of Tm and Tm,Ho in YAG as a function of temperature and concentration is studied. Two probable loss mechanisms - a Tm up-conversion and a Ho up-conversion - are identified. A 785-nm CW diode laser with 400-nW peak power was focused to a small spot on the sample. The emission from the sample observed at 90 deg was monitored through a monochromator with slits open to 3 mm. Intensity of emission was measured by varying the power of the excitation source using a set of neutral density filters. Power is reported as the percentage of the peak power, and the intensity curves were normalized below 20 percent of transmission. The fact that there is emission above the pump energy indicates an up-conversion from excited manifolds. Nonlinear changes in the intensity of the emission from the Tm 3F4 manifold with the pump power reveals a loss of excitation from this manifold. The linear dependence of the 5I7 manifold emission with pump power at low Tm and high Ho concentrations and the gain of energy in the 5I6 manifold of Ho indicate that the 5I7 manifold loss is due to the coupling of Tm and Ho ions.

Armagan, G.

Comparison of spectroscopic properties of Tm and Ho in YAG and YLF crystals

The paper compares the cross-relaxation, energy transfer and loss processes in Tm- and Ho-doped YAG and YLF as a function of temperature, Tm concentration, and excitation power. Significant differences in the behavior of Tm and Tm,Ho in YAG and YLF crystals were found. The cross-relaxation rates of Tm(6 pct) are faster in YLF (about 5 microsec) than YAG (about 10 microsec). The energy transfer rates between Tm and Ho are faster in YLF than YAG. The time it takes for the maximum intensity of 1.7-micron emission to drop 10 percent is 25 microsec for YLF:Tm(6 pct),Ho(0.6 pct) and 65 microsec YAG:Tm(6 pct),Ho(0.5 pct). The losses occurring with increasing pump power for 2.1-micron emission of the above samples are 30 percent less in YLF than YAG. These qualitative differences point to YLF as a valuable 2-micron laser host material.

Armagan, G.

Excited state dynamics of thulium ions in yttrium aluminum garnets

The processes that take place in the excited states of a trivalent Thulium (Tm) ion in an Yttrium Aluminum Garnet (YAG) crystal, being relevant to the use of this system for laser applications, have been the object of several studies. We have reexamined this system focusing our attention on the dynamics of Tm following its excitation in the H-3(sub 4) level. Under these conditions the system relaxes through a cross-relaxation process. H-3(sub 4) yields F-3(sub 4), H-3(sub 6) yields F-3(sub 4), whose rate depends upon both the concentration of the Tm ion and the temperature of the crystal. The excitation spectrum obtained by monitoring the 1.8 micron emission of Tm (due to the F-3(sub 4) yields H-3(sub 6) transition) indicates an increase in the contribution to this emission from the H-3(sub 4) level relative to the H-3(sub 5) level as the Tm concentration increases; this shows the increased role played by the H-3(sub 4) level in pumping the infrared emission. Correspondingly, the duration of the luminescence originating in the H-3(sub 4) level is shortened as the concentration of Tm increases. The concentration quenching of this lifetime can be fit to a model which assumes that the cross-relaxation is due to a dipole-dipole interaction; from this fit, the intrinsic Tm lifetime in the absence of cross relaxation can be derived. We have used this lifetime to calculate the rate of the cross-relaxation process. We have evaluated this rate as a function of the temperature and found it to be fastest at 77 K. We have also calculated the microscopic interaction parameters for the cross-relaxation process by using two independent experimental features: (1) the time evolution of the emission from the H-3(sub 4) level; and (2) the spectral overlap between the H-3(sub 4) yields F-3(sub 4) emission and the H-3(sub 6) yields F-3(sub 4) absorption. We have also considered the migration of excitation among the Tm ions in the F-3(sub 4) level and calculated the relevant microparameter by the use of the relevant spectral overlap. The data are consistent with the model in which the Tm ions, once excited into the H-3(sub 4) level decay by cross-relaxation to the F-3(sub 4), and then transfer rapidly their energy to other Tm ions.

Armagan, G.

Spectroscopic investigation of Cr to Tm energy transfer in yttrium aluminum garnet crystals

A series of experiments has been conducted in order to examine the nature of the energy transfer process between the Cr(3+) and Tm(3+) ions in YAG. Data are obtained on various samples doped with Cr(3+) and/or Tm(3+). These data include absorption, luminescence, excitation spectra and time-resolved response to pulsed excitation. The measurements were carried out over a range of temperatures from 78 to 350 K. The rate of nonradiative energy transfer from Cr(3+) to Tm(3+) depends on temperature, and in the region from 200 to 350 K, this dependence is due primarily to the thermal variation in the radiative decay probability of the Cr ion.

Armagan, G.

Optical materials for space based laser systems

The design features and performance characteristics of a sensitized holmium laser applicable to differential lidar and Doppler windshear measurements are presented, giving attention to the optimal choice of sensitizing/activating dopant ions. This development of a 2-micron region eye-safe laser, where holmium is sensitized by either hulium or erbium, has called for interionic energy transfer processes whose rate will not result in gain-switched pulses that are excessively long for atmospheric lidar and Doppler windshear detection. The application of diamond films for optical component hardening is noted.

Buoncristiani, A. M.