Hall Anomaly, Quantum Oscillations and Possible Lifshitz Transitions in Kondo Insulator YbB 12 : Evidence for Unconventional Charge Transport
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75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Engineering topics
Asaba, Tomoya
Publications and source records attributed to Asaba, Tomoya.
Physical properties of YbFe 5 P 3 with a quasi-one-dimensional crystal structure
We report basic physical properties of the quasi-one-dimensional heavy-fermion compound Yb Fe 5 P 3 . Its magnetic susceptibility follows a modified Curie-Weiss behavior at high temperatures with a Weiss temperature between - 5 and - 21 K depending on the direction of the applied magnetic field. Our single crystals of Yb Fe 5 P 3 are good metals with a room-temperature resistivity of ~ 140 μ Ω cm and a residual resistivity of less than 2 μ Ω cm. Below ~ 2 K the resistivity reflects the presence of strong quantum fluctuations, which is supported by specific heat measurements that show a similar strong enhancement in C / T at low temperatures reaching 1.5 J/mol K 2 below T = 0.5 K. No magnetic ordering is observed down to 80 mK. Magnetic fields up to 8 T rapidly suppress the magnetic fluctuations, while resistivity measurements under pressures up to 2.54 GPa indicate the enhancement of quantum fluctuations, although still no order is observed down to 0.3 K. Density functional theory calculations suggest the presence of electronically quasi-one-dimensional (1D) Fermi surface sheets together with three-dimensional electronic pockets. We suggest that the quasi-1D nature of this compound leads to an extended regime of large quantum fluctuations within the paramagnetic state prior to reaching a magnetic instability.
36 MATERIALS SCIENCE↗
Predicting and Synthesizing Interface Stabilized 2D Layers
The compound (Pb 2 MnSe 3 ) 0.6 VSe 2 was predicted to be kinetically stable based on density functional theory (DFT) calculations on an island of Pb 2 MnSe 3 between layers of VSe 2 . This approach provides a high degree of freedom by not forcing interlayer lattice match, making it ideal to investigate the likelihood of formation of new incommensurate layer misfit structures. The free space around the island is critical, as it allows atoms to diffuse and hence exploring the local energy landscape around the initial configuration. (Pb 2 MnSe 3 ) 0.6 VSe 2 was synthesized via a near diffusionless reaction from precursors where a repeating sequence of elemental layers matches the local composition and layer sequence of the predicted compound. The VSe 2 layer consists of a Se–V–Se trilayer with octahedral coordination of the V atoms. The Pb 2 MnSe 3 layer consists of three rock-salt-like planes, with a MnSe layer between the planes of PbSe. The center MnSe plane stabilizes the puckering of the outer PbSe layers. Electrical properties indicate that (Pb 2 Mn 1 Se 3 ) 0.6 VSe 2 undergoes a charge density wave transition at ~100 K and orders ferromagnetically at 35 K. Overall, the combination of theory and experiment enables a faster convergence to new heterostructures than either approach in isolation.
36 MATERIALS SCIENCE↗
Unusual high-field metal in a Kondo insulator
Strong electronic interactions in condensed-matter systems often lead to unusual quantum phases. One such phase occurs in the Kondo insulator YbB12, the insulating state of which exhibits phenomena that are characteristic of metals, such as magnetic quantum oscillations, a gapless fermionic contribution to heat capacity and itinerant-fermion thermal transport. To understand these phenomena, it is informative to study their evolution as the energy gap of the Kondo insulator state is closed by a large magnetic field. Here we show that clear quantum oscillations are observed in the resulting high-field metallic state in YbB12; this is despite it possessing relatively high resistivity, large effective masses and huge Kadowaki–Woods ratio, a combination that normally precludes quantum oscillations. Both quantum oscillation frequency and cyclotron mass display a strong field dependence. By tracking the Fermi surface area, we conclude that the same quasiparticle band gives rise to quantum oscillations in both insulating and metallic states. These data are understood most simply by using a two-fluid picture in which neutral quasiparticles—contributing little or nothing to charge transport—coexist with charged fermions. Overall, our observations of the complex field-dependent behaviour of the fermion ensemble inhabiting YbB 12 provide strong constraints for existing theoretical models.
36 MATERIALS SCIENCE↗
Proximate Quantum Spin Liquid on Designer Lattice
Complementary to bulk synthesis, here we propose a designer lattice with extremely high magnetic frustration and demonstrate the possible realization of a quantum spin liquid state from both experiments and theoretical calculations. In an ultrathin (111) CoCr 2 O 4 slice composed of three triangular and one kagome cation planes, the absence of a spin ordering or freezing transition is demonstrated down to 0.03 K, in the presence of strong antiferromagnetic correlations in the energy scale of 30 K between Co and Cr sublattices, leading to the frustration factor of similar to 1000. Persisting spin fluctuations are observed at low temperatures via low-energy muon spin relaxation. Our calculations further demonstrate the emergence of highly degenerate magnetic ground states at the 0 K limit, due to the competition among multiply altered exchange interactions. Furthermore, these results collectively indicate the realization of a proximate quantum spin liquid state on the synthetic lattice.
77 NANOSCIENCE AND NANOTECHNOLOGY↗