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Bakalyar, D. M.

Publications and source records attributed to Bakalyar, D. M..

Measurement of collision-induced shift and broadening of the ultraviolet transitions of OH

Using a CW tunable laser, absorption measurements were made to determine for the first time the shift and broadening of the ultraviolet transitions of OH induced by collisions with molecular nitrogen and oxygen. Similar measurements were also made for collisions with air and inert gases He, Ne, Ar, and Kr. Both the shift and broadening due to these collisions were found to depend linearly upon pressures in the range from 50 Torr up to 1 atm. The homogeneous linewidth for the P2(2) transition of OH in ambient air is determined to be 0.20 + or - 0.005/cm. Results with Ar and Kr show contributions not accounted for by the polarizability of the colliding species.

Shirinzadeh, B.↗

Shot noise limited detection of OH using the technique of laser-induced fluorescence

Nearly shot-noise limited detection of OH using the technique of laser-induced fluorescence is reported. A LIDAR configuration is used to excite fluoresence in a large volume and a narrow-bandwidth interference filter provides spectral discrimination. This arrangement alleviates the effect of ozone interference and facilitates image processing at relatively close distances. The detection limit is determined mainly by the short-noise of the solar background. Ground-based measurements in Dearborn indicate a detection limit of better than 1 x 10 to the 6th power OH/cubic cm over a forty-minute acquisition period. Under favorable conditions, a comparable detection limit was also observed for airborne measurements.

Bakalyar, D. M.↗

Shot noise limited detection of OH using the technique of laser induced fluorescence

Nearly shot-noise limited detection of OH using the technique of laser-induced fluorescence is reported. A LIDAR configuration is used to excite fluorescence in a large volume and a narrow-bandwidth interference filter provides spectral discrimination. This arrangement alleviates the effect of ozone interference and facilitates image processing at relatively close distances. The detection limit is determined mainly by the shot-noise of the solar background. Ground-based measurements in Dearborn indicate a detection limit of better than 1 x 10 to the 6th power OH/cubic cm over a forty-minute acquisition period. Under favorable conditions, a comparable detection limit was also observed for airborne measurements.

Bakalyar, D. M.↗

Absorption technique for OH measurements and calibration

An absorption technique is described which utilizes a stabilized frequency-doubled tunable dye laser and a long-path White cell with high mirror reflectivities both in the red and UV. In laboratory conditions it has been possible to routinely obtain a detection sensitivity of 3 parts in 1,000,000 over absorption paths less than 1 m in length and a detection sensitivity of approximately 6 parts in 100,000 over an absorption path of the order of 1 km. The latter number corresponds to 3,000,000 OH molecules/cu cm, and therefore the technique should be particularly useful for calibration the fluorescence instrument for OH measurements. However, the presence of atmospheric fluctuations coupled with intensity variation accompanying frequency scanning appears to degrade the detection sensitivity in outdoor ambient conditions, thus making it unlikely that this technique can be employed for direct OH monitoring.

Bakalyar, D. M.↗