Search NASA⌕ Search

Engineering topics

Barrett, J. L.

Publications and source records attributed to Barrett, J. L..

3 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Surface-catalyzed recombination into excited electronic, vibrational, rotational, and kinetic energy states: A review

Laboratory experiments in which recombined CO, CO2, D2O, OH, N2, H2, and O2 molecules desorb from surfaces in excited internal and translational states are briefly reviewed. Unequilibrated distributions predominate from the principally catalytic metal substrates so far investigated. Mean kinetic energies have been observed up to approx. 3x, and in some cases less than, wall-thermal; the velocity distributions generally vary with emission angle, with non-Lambertian particle fluxes. The excitation state populations are found to depend on surface impurities, in an as yet unexplained way.

Kofsky, I. L.↗
NASA NTRS1985

Infrared emission from desorbed NO2(*) and NO(*)

Infrared photons from the radiative cascade accompany both the gas phase NO2 continuum chemiluminescence (which originates from its 2B2 and 2B1 states) and the NO beta bands. When these upper electronic states are excited by recombination/desorption at surfaces of low Earth orbiting spacecraft, similar IR emission spectrums will be observed. The principal NO2 features (other than the long wavelength tail of its electronic transitions) are the nu sub 3 fundamental sequence near 6.2 microns and nu sub 1 + nu sub 3 intercombination bands near 3.6 microns; NO would emit the delta v=1 and delta v=2 systems above 5.3 and 2.7 microns. Because of the long radiative lifetimes of the upper vibrational states, the infrared radiances in projections parallel to the vehicle surface (which we estimate) are substantially less than those of the visible and ultraviolet glows.

Kofsky, I. L.↗
NASA NTRS1985

The NO-NO2 system at laboratory surfaces

Experiments on formation and excitation of NO2 and NO molecules at (and near) laboratory surfaces of varying degrees of characterization are reviewed. On some transition metals NO is desorbed in the B sub 2 pi state, from which it radiates the familiar beta (B yields x) bands. In contrast while an ONO intermediate is inferred from isotope interchange measurements on platinum, neither ground state nor excited NO2 has been found to be desorbed under the relatively limited number of laboratory conditions so far investigated.

Barrett, J. L.↗