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Basu, A.

Publications and source records attributed to Basu, A..

At least 19 records

Vapor Deposition and Solar Wind Implantation on Lunar Soil-Grain Surfaces as Comparable Processes

Vapor deposited patinas (VDP) on lunar soil grains consist of a thin (less than 1 micron) layer of amorphous silicate (glass) embedded with nanoscale Fe(sup 0) globules as seen in many TEM images. VDPs are also present on larger space-weathered lunar rocks; these larger samples will not be discussed here although the process of vapor deposition is common to exposed grains of all sizes. Whether or not the majority of the Fe(sup 0) globules present in lunar soils reside in vapor deposited patina is a matter of some concern. Some Fe(sup 0) globules are clearly seen to reside within the glass of agglutinates and might represent remobilized Fe(sup 0) in agglutinitic melts. remobilized Fe(sup 0) in agglutinitic melts. We argue that because VDP coatings are present only on the surfaces of lunar soil grains, their distribution as a surface correlated component (SCC) of lunar soils should parallel those of Solar Wind Elements (SWE) implanted in the outermost rinds of lunar soil grains. SWE residing in the interior of soils grains make up the volume correlated component (VCC). Relative to Fe(sup 0) in VDP, the distribution of various SWE have been studied well. The reason is understandable because instrumentation for nanoscale imaging is not ubiquitous. In this study we use the distribution of SWE in lunar soils as a guide to understanding the fate of Fe(sup 0) in VDP.

Basu, A.↗

A Critical Examination of Relative Concentrations of Volume-correlated and Surface-correlated Submicron Globules of Pure Fe-0 in Lunar Soils

Impacts on lunar soils produce melt and vapor in an approximate proportion of 7:1. The melt scavenges soil grains of diverse size, quenches and forms agglutinates, thereby converting surface correlated components of soil grains as volume correlated components; simultaneously, parts of the vapor may condense or escape. Cumulative small impacts increase the maturity of the soils, increase the abundance of agglutinates, and increase the concentration of vapor condensated material. Since the discovery of vapor deposited crystalline Fe-0 in vugs of regolith breccias and the theoretical anticipation of amorphous vapor deposits of diverse composition coating lunar soils grains, empirical evidence is gathering in support of such deposits, now commonly called vapor deposited patina (VDP). In addition, submicron globules of Fe-0 are seen to be ubiquitous in VDP. The amorphous VDP lowers the albedo of lunar soils, affects magnetic properties of soils, changes the slopes of uv-vis-ir reflectance spectra, and potentially also alters the gamma and x-ray spectra of lunar soils, compromising compositional inferences from remote sensing.

Basu, A.↗

Size Distribution of Fe0 Globules in Lunar Agglutinitic Glass

SEM-BSE measurements of the size distribution of Fe0 globules in agglutinitic glass in seven lunar soils average about 120 nm suggesting similar modes of origin. Additional information is contained in the original extended abstract.

James, C. L.↗

Production of Agglutinates in the Lunar Regolith

Shock melting of microtargets produces homogeneous domains (<10 micron) from the finer fractions of lunar soils, incorporating SWE and vapor-deposit enriched fine grains. Finest grains may or may not be assimilated in such agglutinate-forming melts.

Basu, A.↗

A Modified CIPW Norm Calculation for Lunar Mare Basalts

CIPW norms of lunar mare basalts are anomalously low in pyroxene. A modified norm calculation allowing higher Ca, Ti, Al, Cr, and Mn in di' and hy' obtains closer matches between normative and modal mineralogy.

Milliken, R. E.↗

Grain-size Distribution of Apollo 11 Soil 10084

Results of a new grain size analysis of 0.99 g of the submillimeter fraction of the soil 10084, using the JSC methodology, are: 4.28 phi =(51 micrometers) and 2.23 phi (=213 micrometers). A significant fraction (14.2%) of the soil is less than 10 micrometers in size.

Basu, A.↗

Three Paradigms of Lunar Regolith Evolution

Integration of diverse datasets on the Moon may render some paradigms of lunar science either better-defended or vulnerable. We will consider three paradigms commonly used for understanding the processes of lunar regolith evolution in light of new and accumulated data. Our premise is that all data-sets should converge to a single interpretation if a concept or model is to be accepted as a paradigm. If a convergence is lacking, the paradigm needs fresh scrutiny. SteadyState: Lunar regolith evolution is currently understood in terms of comminution, agglutination, and replenishment as described by McKay and coworkers). Briefly, the model envisages continued micrometeoritic bombardment to comminute exposed soil particles to finer sizes while continued agglutination consumes finer sizes to produce larger constructional particles. Eventually, a balance between these two opposing processes achieves a steady state; soils at steady state maintain their mean grain size (M(sub z)). Episodic higher-energy impacts excavate fresh coarse material from below the soil cover, disturb the steady state, and restart the process to achieve a new steady state. It follows that the thickness of the regolith at any site would control the frequency of replenishment; indeed, the thickness of the regolith at Apollo landing sites was predicted by McKay et al. from the average M(sub z) of local soils. However, replenishment may come also from disintegrating boulders and cobbles at the lunar surface, and rates of comminution and agglutination may depend on the properties of target material. Regression between M(sub z) and I(sub s)/Fe(sup 0) (a measure of maturity or total surface exposure) of Apollo soils at different sites shows the following relations and estimated M(sub z) at a high maturity of I(sub s)/Fe(sup 0)= 100. It is possible that Apollo 12 and 15 sites have the thickest regolith and the Apollo 16 site has the thinnest. It is also possible that Apollo 12 and 15 basalts are comminuted faster than Apollo 16 highland rocks and Apollo 14 and 17 soils are products of mixed parentage. If a soil becomes continually finer as it matures until agglutination catches up, and if comminution is differential-dependent on the physical properties of the constituents, then the composition of the bulk soil has to match the composition of some "fulcrum" grain size fraction, say X Grain size fractions >X and <X will complement each other; their mass balance is the bulk soil. It appears that the 10-20-micron size fraction may be the fulcrum. In general, trace-element chemistry and IR reflectance spectra of this size fraction are closest to that of the bulk soil, regardless of maturity that is surprising. Disaggregated products of regolith breccias may also show similar relationships. If the 10-20 gm is the fulcrum (i.e., X as above) for many soil properties (e.g., major element composition, FMR, solar-wind-implanted elements), then this may be the ultimate mean grain size of lunar soils at steady state. However, different properties of soils may find steady states at different grain size fractions. The steady state of solar-wind-implanted elements, on the other hand, will climb up the grain-size scale as agglutinates transfer surface-correlated components into volume correlated components until a saturation level is reached or the rates of replenishment and implantation become equal. The same will be the case with vapor-deposited reduced metals as they too are incorporated inside constructional particles. Properties that are directly affected by soil-maturation processes will thus have different pathways of achieving steady states. Maturity, i.e., cumulative surface exposure, of lunar soils is best quantified by the amount of nanophase superparamagnetic Fe(sup 0) (np-Fe(sup 0)) normalized to Fe content (=I(sub s)/Fe(sup 0). The majority consensus (paradigm?) for the production of np-Fe(sup 0) is associated with the production of agglutinates. Because large doses of solar-wind H are implanted in all lunar soils upon exposure, any melting (e.g., during agglutinate production) triggers a chemical reduction of Fe-bearing minerals resulting in np-Fe(sup 0) production. The quantity of np-Fe(sup 0) is thus dependent on melting events, (i.e., exposure), and limited by the Fe content of the soil. All freshly produced np-Fe(sup 0) resides in agglutinitic glass, as new TEM images show. Apparently, the correction procedure developed by Lucey et al. to estimate the Fe content of the lunar surface from IR-reflectance spectra depends on accepting the above. However, the process of producing np-Fe(sup 0) may be physical rather than chemical. All np-Fe(sup 0) could be deposits from a vapor produced by micrometeoritic impact on lunar soils. If metal-O bonds in target phases are broken, O being "most volatile" will escape leaving an O-deficient vapor to facilitate the production of np-Fe(sup 0). If so, the quantity of np-Fe(sup 0) is dependent on the vaporizing events, (i.e., exposure), and limited by the efficiency of breaking metal-O bonds and the escape of 0. To the extent that strengths of metal-O bonds are dependent on the local crystal field, production of np-Fe(sup 0) may be limited by the mineral composition of target soils and not by their total Fe content. According to this model, vapor-deposited np-Fe(sup 0) should be found at any retentive sites on lunar soil grains. Indeed, TEM images show np-Fe(sup 0) on plagioclase and ilmenite. Incorporation of such pre-irradiated np-Fe(sup 0)-bearing grains into agglutinates may account for eventual increased emplacement of np-Fe(sup 0) in agglutinates. Such a paradigm shift in understanding the origin of np-Fe(sup 0) will raise questions ranging from the unquestionable use of Is/FeO as the universal maturity parameter of lunar soils to global elemental maps of the Moon from remote-sensing data. Additional information is contained in the original.

Basu, A.↗

Lunar soil evolution processes and Apollo 16 core 60013/60014

Soils of the 62-cm deep Apollo 16 double drive tube 60013/14 are mature at the top and submature at the bottom. Modal analyses of 5529 grains from the 90-150 micrometers and the 500-1000 micrometers fractions from 12 levels of the core show that, in general, agglutinate abundance increases somewhat monotonically to the top and mimics the Is/FeO profile. There is a general decrease in the modal abundance of monomineralic fragments towards the top, suggesting that agglutinates were formed in part at the expense of monomineralic grains, especially feldspars, which are by far the most abundant mineral in these soils. In detail, the top 27 cm of the core differs from the bottom 21 cm, and the middle 14 cm is intermediate in its properties. In the upper segment, variations in the abundances of feldspars correspond with those of feldspathic fragmental breccias and cataclastic anorthosites; in the bottom segment, a similar but weak correspondence between feldspars and crystalline matrix breccias is observed. Mixing of the comminuted products of these three rock types likely produced the bulk of the core material. Many single feldspars in all size fractions are remarkably fresh, show no damage from shock, and are similar in appearance to the large feldspars in anorthosites and feldspathic fragmental breccias, which we consider to be the primary sources of single feldspars in this core. Major (Na, Al, Si, K, Ca) and minor (Fe, Ba) element analyses of 198 single feldspar grains indicate the presence of only one population of feldspars, which is consistent with our interpretation of feldspar provenance. Classification of 890 monomineralic feldspar, olivine, pyroxene, and glass spherules on the basis of the presence or absence of thin brownish coating--related to reworking at the surface--shows that coated grains are much more abundant in the top segment than in the bottom segment. A comparison with the mixing and maturation model (McKay et al., 1977) of soils in the core 60009/10, some 60 m away from 60013/14, shows that mixtures of an immature, nearly pure plagioclase soil (dominant in 60009/10) and another immature, crystalline breccia-rich soil (dominant in 60013/14) may have matured through in situ reworking to produce the soils under investigation. We conclude that the soils in this core are products of mixing along soil evolution Path 2 of McKay et al. (1974). Superimposed on that soil column is the reworking of the upper part, which has evolved more recently along Path 1. This core thus represents a consanguineous column of the lunar regolith with an upper reworked segment.

short duration↗

Measuring glass abundances in lunar agglutinates

The purpose of this study is to develop a standard method for measuring modal abundances of glass in single agglutinates in the lunar regolith. Not only does agglutinitic glass increase in single agglutinates as clasts of older agglutinates get incorporated into newer agglutinates with increasing maturity, but it is in this glassy phase that nanophase superparamagnetic Fe metal originates as a result of reduction reactions during the agglutination process. We report the results of two sets of independent measurements using two different methods to determine the proportion of glass in single agglutinates. We have used polished grain mounts (PGM) of five hand-picked single agglutinates from Apollo 16 soil 61181. The ISI Scanning Electron Microscope (SEM) fitted with a high-resolution Backscattered Electron (BSE) detector was used to collect high-contrast BSE images of the agglutinates. Several images were collected to represent each single agglutinate. The contrast, brightness, and focus were adjusted to optimize each image collected. Histograms of the grayscale range for all images produced four 'peaks' corresponding to epoxy, glass, crystalline phases, and metal grains. We analyzed every grid point for 12 elements with a less than 1 micron electron beam using a CAMECA SX-50 electron probe microanalyzer (EPM). If any analysis was not within about 10% of the stoichiometry of a known lunar mineral, we considered that point to be nonmineralic. Our results show that there is a remarkable correspondence in the glass percentages obtained by the two methods. The EPM method may overestimate glass because secondary fluorescence from dusty clasts in agglutinitic glass can give the appearance of nonmineralic targets. The BSE method may underestimate glass because the diversity of compositions of agglutinitic glass may not be contained under one grayscale 'peak' during image analysis.

Strait, M. M.↗

Apollo 12 ropy glasses revisited

We analyzed ropy glasses from Apollo 12 soils 12032 and 12033 by a variety of techniques including SEM/EDX, electron microprobe analysis, INAA, and Ar-39-Ar-40 age dating. The ropy glasses have potassium rare earth elements phosphorous (KREEP)-like compositions different from those of local Apollo 12 mare soils; it is likely that the ropy glasses are of exotic origin. Mixing calculations indicate that the ropy glasses formed from a liquid enriched in KREEP and that the ropy glass liquid also contained a significant amount of mare material. The presence of solar Ar and a trace of regolith-derived glass within the ropy glasses are evidence that the ropy glasses contain a small regolith component. Anorthosite and crystalline breccia (KREEP) clasts occur in some ropy glasses. We also found within these glasses clasts of felsite (fine-grained granitic fragments) very similar in texture and composition to the larger Apollo 12 felsites, which have a Ar-39-Ar-40 degassing age of 800 +/- 15 Ma. Measurements of 39-Ar-40-Ar in 12032 ropy glass indicate that it was degassed at the same time as the large felsite although the ropy glass was not completely degassed. The ropy glasses and felsites, therefore, probably came from the same source. Most early investigators suggested that the Apollo 12 ropy glasses were part of the ejecta deposited at the Apollo 12 site from the Copernicus impact. Our new data reinforce this model. If these ropy glasses are from Copernicus, they provide new clues to the nature of the target material at the Copernicus site, a part of the Moon that has not been sampled directly.

Wentworth, S. J.↗

Single agglutinates: A comparative study of compositions of agglutinitic glass, whole-grain, bulk soil, and FMR

Previous workers on single agglutinates have variously interpreted the composition of agglutinitic glass to represent impact melts of (1) bulk soil, (2) mixed components in finer sizes, and (3) microtargets. Separately, Papike has argued in favor of fusion of the finest fraction of bulk soils. Thirty-four single agglutinates were hand-picked from the mature Apollo 16 soil 61181 (I(sub s)/FeO = 82) and the FMR and chemical composition (INAA for Fe, Sc, Sm, Co, Ni, and Cr) of each agglutinate particle were measured. Thirteen of these single agglutinates were selected for electron beam microanalysis and imaging. Less than 1 micron spots were analyzed (for Na, Mg, Al, Si, P, S, K, Ca, Ti, Cr, Mn, Fe, Ni, and Ba) on pure glassy areas (approximately ten in each particle) selected on the basis of optical and BSE images (avoiding all clasts and inclusions) with an electron microprobe to obtain average glass compositions of each single agglutinate.

Basu, A.↗

Optical effects of space weathering: The role of the finest fraction

The optical properties of lunar soils are different than those of rocks which they are derived. As a consequence of lunar space weathering, soils are darker and exhibit a distinctive red-sloped continuum and weaker mineral absorption bands. The accumulation of dark glass-welded aggregates (agglutinates) has been thought to account for these optical effects of space weathering on lunar soils. Spectroscopic analyses of agglutinate separates and size fractions for a suite of lunar soils presented here indicate that the agglutinate paradigm is insufficient to fully account for lunar optical alteration. It is the finest fraction of lunar soils (less than 25 microns which constitute approximately 25% wt.) that dominates the optical properties of the bulk soil. Unlike size fractions of most silicates for which the finest fraction is the brightest, the lunar soil size fractions all have comparable albedos in the short-wavelength visible. In the near infrared, however, it is the finest fraction that exhibits the steep red continuum and weak absorption bands. The properties of the finest fraction cannot be duplicated by preparing a fine fraction by grinding larger agglutinate-rich soil particles. These results suggest space weathering on airless bodies is dominated by surface correlated processes (perhaps associated with the developement of fine-grained Fe(dot) on or near the surface of grains), and the accumulation of the large agglutinates is not necessarily required to account for lunar optical alteration.

Pieters, C. M.↗

Apollo 16 core 60013/14 as a product of path 1 and path 2 regolith evolution processes

We have made a petrographic study of 12 samples along the 62 cm profile of Apollo 16 core 60013/14 taken at Station 10 near the lunar module. The basic core description and maturity variations have been discussed earlier. This core is important because it enables a stratigraphic comparison with nearby cores 60001-7 and 60009/10. These cores form a triangle with sides 35-40 m. FMR data show a maturity-match between 60009/10 and 60013/14. Unfortunately, segments of the core 60001-7 are too disturbed for any cm scale comparison. We present new data on the grain size distribution and the modal petrography for six samples from six levels of 60013 using the same approach and rationale used for 60014. We have combined the new data with our previous data on 60014 to plot the variations of grain size distributions and grain type abundances, in the 500-1000 m and 90-150 micrometers size fractions, with depth. Agglutinate abundances match the I sub s/FeO profile and both show a significant break at a depth of about 45 cm, with lower maturity material below that point. Grain size distributions show that for all analyzed samples, the mean grain size is below 90 micrometers. The two lowest samples are somewhat more coarse-grained than the rest of the core. The break at about 45 cm is the most prominent feature of the core and was described during the initial dissection as a pronounced change in color from dark to light. It now seems clear that this break is primarily one of maturity rather than of bulk chemical composition.

Basu, A.↗

Optical effects of space weathering on lunar soils and the role of the finest fraction

Lunar soils represent a cumulative product of space weathering and as such they exhibit distinct optical alteration. In comparison to the optical properties of similar rock powders, lunar soils are darker, have weaker diagnostic absorption bands, and exhibit a characteristic red continuum slope between 0.3 and 4.5 microns. Well-developed (mature) lunar soils have a mean grain size of about 60 microns and may contain more than 50 percent agglutinates (complex, glass-welded aggregates) which were previously believed to be the principal carriers of optical alteration resulting from space weathering. A detailed analysis of the spectral reflectance properties of the bulk soil, size separates, and agglutinate separates of several Apollo and Luna soils has been undertaken to evaluate the validity of the agglutinate paradigm for optical effects of space weathering. The data and results are summarized here which indicate that the finest fraction of natural lunar soils, rather than larger complex agglutinates, carries the principal effects of optical alteration. Bidirectional reflectance spectra were obtained using the small sample configuration of the RELAB facility, which accommodates 5-30 mg of material. Spectra are displayed with the labels for individual samples listed in order of brightness.

Pieters, C. M.↗

Petrology and provenance of Apollo 15 Station 6 core 15009 and its bearing on site geology

Petrographic and microprobe studies were conducted of six soil samples from six different levels of the 30-cm-deep single-drive tube core 15009 obtained from the regolith of the Apennine Front at Station 6 of the Apollo 15 site. A model for the near-surface stratigraphy of the site is constructed, with due account for the results of previous studies of surface and core soils. Highland rocks were found to account for 9 percent of the mineral and lithic fragments in core 15009. The observed correlation between crystalline breccia fragments and green glass indicate that the primitive regolith on the premare Apennine Front contained abundant crystalline breccia fragments that were mixed with puroclastic green glass added to that regolith early in the mare eruptive sequence. KREEP basalts were found to be the parent rocks for 40 percent of the core fragments. It is inferred that KREEP basalts of the Apennine Bench Formation underlie mare basalts at the site. Olivine-normative mare basalt fragments comprise only 14 percent of the core-15009 source rocks but are much more abundant away from the Front.

Basu, A.↗

La/Sm ratios in mare basalts as a consequence of mafic cumulate fractionation from an initial lunar magma

A model is constructed for the La/Sm ratio and the abundance of chrondrite-normalized La in different proportions of partial melts of a mafic cumulate source that might have settled to the bottom of an initial lunar magma ocean prior to any plagioclase separation. It is proposed that La/Sm ratios and chrondrite-normalized La abundances of common mare basalts are found in partial melts only if: the mafic cumulate consists mostly of clinopyroxene, a very low fraction of the cumulate melts, and the cumulate represents a moderate to high proportion of the crystallization of the initial magma ocean. Only if the partitioning of clinopyroxene is forced to mimic plagioclase (DLa is greater than DSm) do the present modeling results become compatible with the scenario for producing appropriate parent melts of mare basalts from mafic cumulates. It is found unlikely that parent melts of mare basalts were produced from mafic cumulates of an initial lunar magma ocean that had not had any plagioclase crystallization.

Shaffer, E. E.↗

The relationship between orbital, earth-based, and sample data for lunar landing sites

Results are reported of a detailed examination of data available for the Apollo lunar landing sites, including the Apollo orbital measurements of six major elements derived from XRF and gamma-ray instruments and geochemical parameters derived from earth-based spectral reflectivity data. Wherever orbital coverage for Apollo landing sites exist, the remote data were correlated with geochemical data derived from the soil sample averages for major geological units and the major rock components associated with these units. Discrepancies were observed between the remote and the soil-anlysis elemental concentration data, which were apparently due to the differences in the extent of exposure of geological units, and, hence, major rock eomponents, in the area sampled. Differences were observed in signal depths between various orbital experiments, which may provide a mechanism for explaining differences between the XRF and other landing-site data.

Clark, P. E.↗