Basu, Sayan | Search NASA

DOE OSTI2022

Restriction-In-Motion of Surface Ligands Enhances Photoluminescence of Quantum Dots - Experiment and Theory

Here the relationship between emission and ligand restriction of a series of ZnSe/ZnS quantum dots (QDs) encapsulated in nanoparticles is investigated systematically via experiments and quantum theory. The QDs have a ZnSe core and a ZnS shell, capped with hydrophobic ligands (triotylphosphine oxide/hexadecylamine), allowing them to be entrapped in a model biomembrane, bicelle, made of zwitterionic dipalmitoyl and dihexanoyl phosphatidylcholines and charged dipalmitoyl phosphatidylglycerol. Enhanced photoluminescence is observed upon encapsulation, depending on the QD-to-lipid ratio. Transmission electron microscopy and small-angle X-ray scattering confirm that QDs are preferably situated at the rim of bicellar discs. A simplified quantum dissipation heat-bath theory is proposed to correlate the enhancement with slower nonradiative processes caused by the restriction-in-motion (RIM) of the surface ligands. However, Fõrster resonance energy transfer due to QD aggregation counteracts the effect.

36 MATERIALS SCIENCE↗

NASA NTRS2018

Improving the S/X Celestial Reference Frame in the South

We believe that the S/X celestial reference frame(CRF) can be improved in the far-south by a factor of 2 in density and a factor of 2.5 in precision. We have started a collaboration to meet these goals. We have increased the data rates on existing IV Sastrometric sessions in the south from 256 Mbps to 1 Gbps. We will use this sensitivity to detect weaker sources and to improve the precision of sources in the southern S/X CRF, while simultaneously increasing the number of sources, in particular the overlap with other frames such as K-and Ka-band in the radio and the Gaia frame in the optical. VLBI observations in the southern celestial hemisphere have always been more difﬁcult both because there are fewer radio telescopes in the south than in the north, and because there are fewer known reference sources in the south. There have been many efforts in recent years to increase the number of known reference sources in the south, in particular the LBA calibrator Survey (LCS), which has already produced a signiﬁcant improvement at X-band. The ICRF-3 is expected to make signiﬁcant improvements in the south, however the south has not yet reached parity with the north and much work remains to be done. Therefore dedicated astrometric and imaging observations have already begun to improve the southern CRF at S/Xbands.

Basu, Sayan↗