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Baumgardner, D.

Publications and source records attributed to Baumgardner, D..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2008

Formation of Large (Approximately 100 micrometers) Ice Crystals Near the Tropical Tropopause

Recent high-altitude aircraft measurements with in situ imaging instruments indicated the presence of relatively large (approx.100 microns length), thin (aspect ratios of approx.6:1 or larger) hexagonal plate ice crystals near the tropical tropopause in very low concentrations (<0.01/L). These crystals were not produced by deep convection or aggregation. We use simple growth-sedimentation calculations as well as detailed cloud simulations to evaluate the conditions required to grow the large crystals. Uncertainties in crystal aspect ratio leave a range of possibilities, which could be constrained by knowledge of the water vapor concentration in the air where the crystal growth occurred. Unfortunately, water vapor measurements made in the cloud formation region near the tropopause with different instruments ranged from <2 ppmv to approx.3.5 ppmv. The higher water vapor concentrations correspond to very large ice supersaturations (relative humidities with respect to ice of about 200%). If the aspect ratios of the hexagonal plate crystals are as small as the image analysis suggests (6:1, see companion paper (Lawson et al., 2008)) then growth of the large crystals before they sediment out of the supersaturated layer would only be possible if the water vapor concentration were on the high end of the range indicated by the different measurements (>3 ppmv). On the other hand, if the crystal aspect ratios are quite a bit larger (approx.10:1), then H2O concentrations toward the low end of the measurement range (approx.2-2.5 ppmv) would suffice to grow the large crystals. Gravity-wave driven temperature and vertical wind perturbations only slightly modify the H2O concentrations needed to grow the crystals. We find that it would not be possible to grow the large crystals with water concentrations less than 2 ppmv, even with assumptions of a very high aspect ratio of 15 and steady upward motion of 2 cm/s to loft the crystals in the tropopause region. These calculations would seem to imply that the measurements indicating water vapor concentrations less than 2ppmv are implausible, but we cannot rule out the possibility that higher humidity prevailed upstream of the aircraft measurements and the air was dehydrated by the cloud formation. Simulations of the cloud formation with a detailed model indicate that homogeneous freezing should generate ice concentrations larger than the observed concentrations (20/L), and even concentrations as low as 20/L should have depleted the vapor in excess of saturation and prevented growth of large crystals. It seems likely that the large crystals resulted from ice nucleation on effective heterogeneous nuclei at low ice supersaturations. Improvements in our understanding of detailed cloud microphysical processes require resolution of the water vapor measurement discrepancies in these very cold, dry regions of the atmosphere.

Jensen, E. J.↗
NASA NTRS2007

Comparison of CALIPSO-Like, LaRC, and MODIS Retrievals of Ice Cloud Properties over SIRTA in France and Florida during CRYSTAL-FACE

This study compares cirrus particle effective radius retrieved by a CALIPSO-like method with two similar methods using MODIS, MODI Airborne Simulator (MAS), and GOES imagery. The CALIPSO-like method uses lidar measurements coupled with the split-window technique that uses the infrared spectral information contained at the 8.65-micrometer, 11.15-micrometer and 12.05-micrometer bands to infer the microphysical properties of cirrus clouds. The two other methods, sing passive remote sensing at visible and infrared wavelengths, are the operational MODIS cloud products (referred to by its archival product identifier MOD06 for MODIS Terra) and MODIS retrievals performed by the CERES team at LaRC (Langley Research Center) in support of CERES algorithms; the two algorithms will be referred to as MOD06- and LaRC-method, respectively. The three techniques are compared at two different latitudes: (i) the mid-latitude ice clouds study uses 18 days of observations at the Palaiseau ground-based site in France (SIRTA: Site Instrumental de Recherche par Teledetection Atmospherique) including a ground-based 532 nm lidar and the Moderate Resolution Imaging Spectrometer (MODIS) overpasses on the Terra Platform, (ii) the tropical ice clouds study uses 14 different flight legs of observations collected in Florida, during the intensive field experiment CRYSTAL-FACE (Cirrus Regional Study of Tropical Anvils and cirrus Layers-Florida Area Cirrus Experiment), including the airborne Cloud Physics Lidar (CPL) and the MAS. The comparison of the three methods gives consistent results for the particle effective radius and the optical thickness, but discrepancies in cloud detection and altitudes. The study confirms the value of an active remote-sensing method (CALIPSO-like) for the study of sub-visible ice clouds, in both mid-latitudes and tropics. Nevertheless, this method is not reliable in optically very thick tropical ice clouds.

Chiriaco, M.↗
NASA NTRS2004

Nitric Acid Uptake on Subtropical Cirrus Cloud Particles

The redistribution of HNO3 via uptake and sedimentation by cirrus cloud particles is considered an important term in the upper tropospheric budget of reactive nitrogen. Numerous cirrus cloud encounters by the NASA WB-57F high-altitude research aircraft during the Cirrus Regional Study of Tropical Anvils and Cirrus Layers-Florida Area Cirrus Experiment (CRYSTAL-FACE) were accompanied by the observation of condensed-phase HNO3 with the NOAA chemical ionization mass spectrometer. The instrument measures HNO3 with two independent channels of detection connected to separate forward and downward facing inlets that allow a determination of the amount of HNO3 condensed on ice particles. Subtropical cirrus clouds, as indicated by the presence of ice particles, were observed coincident with condensed-phase HNO3 at temperatures of 197-224 K and pressures of 122-224 hPa. Maximum levels of condensed-phase HNO3 approached the gas-phase equivalent of 0.8 ppbv. Ice particle surface coverages as high as 1.4 # 10(exp 14) molecules/ square cm were observed. A dissociative Langmuir adsorption model, when using an empirically derived HNO3 adsorption enthalpy of -11.0 kcal/mol, effectively describes the observed molecular coverages to within a factor of 5. The percentage of total HNO3 in the condensed phase ranged from near zero to 100% in the observed cirrus clouds. With volume-weighted mean particle diameters up to 700 ?m and particle fall velocities up to 10 m/s, some observed clouds have significant potential to redistribute HNO3 in the upper troposphere.

Popp, P. J.↗
NASA NTRS2003

Radiative Forcing of the Lower Stratosphere over the Arctic by Light Absorbing Particles

Light absorbing particles (LAP), such as soot and dust, change the thermodynamic structure of the atmosphere and contribute to regional and global climate change. The lower stratosphere (LS) is particularly sensitive to the presence of LAP since the lifetime of particles in the LS may extend from months to years, in contrast to tropospheric lifetimes of at most a few days. The source of particles in the LS may be aircraft, meteorites or emissions from tropospheric sources. There has been a lack, however, of accurate, quantitative measurements made with sufficiently sensitive instruments. This limits our understanding of the origin and lifetime of aerosols in this region of the atmosphere. Here we present recent measurements in the Arctic UT/LS with a new, highly sensitive instrument that has detected black carbon (BC) mass concentrations of 20-1000 ng m(exp -3) that are 10-1000 times larger than those reported in previous studies and are at least 30 times larger than predicted masses based on fuel consumption by commercial aircraft that fly in these regions. Scattering and absorption of solar and terrestrial radiation by the particles in a layer from 8- 12 Km leads to a negative net forcing of -0.5 W sq m at the top of the atmosphere and 9C of heating in this layer during the average aerosol lifetime at these altitudes. The new measurements suggest that the influence of aircraft emissions have been underestimated or that aircraft may not be the only significant source of light absorbing particles in the UT/LS. The presence of these aerosols can cause local changes in the thermal structure of the lower stratosphere and a subsequent modification of stratosphere/tropopause exchange of gases and particles.

Baumgardner, D.↗
NASA NTRS2003

Light Absorbing Particle (LAP) Measurements in the Lower Stratosphere

This viewgraph presentation covers the capabilities and design of the Single Particle Soot Photometer (SP-2), and reviews its role on the Sage III Ozone Loss Validation Experiment (SOLVE II) field campaign during 2003. On SOLVE II the SP-2 was carried into the Arctic onboard a DC-8 aircraft, in order to determine the size distribution of light-absorbing and non light-absorbing particles in the stratosphere. Graphs and tables relate some of the results from SOLVE II.

Baumgardner, D.↗
NASA NTRS2001

Evidence for the Widespread Presence of Liquid-Phase Particles During the 1999-2000 Arctic Winter

In-situ Multi-Angle Spectrometer Probe (MASP) particle measurements have been analyzed to determine the typical behaviour of sulphate particles during the SOLVE campaign. The analysis has focussed on variations in the total particle concentration measured by MASP, which is a diagnostic that is primarily sensitive to the growth of small particles (those which are initially smaller than 0.2 micrometers in radius). At all levels of the stratosphere, the total MASP concentration varies continuously with temperature. This behaviour is well-reproduced by assuming that the sulphate aerosols are liquid ternary solutions, but cannot be reproduced if the aerosol is assumed to be frozen. This liquid-like behaviour is apparent for all measurements made during SOLVE, both inside and outside the vortex, and even at the coldest temperatures sampled during the campaign. The only anomalous measurements were made during the flight of January 14th, 2001; however, this midlatitude flight is very unlikely to contain SAT particles based on the recent warm temperatures experienced by the air. At the levels with the coldest measured temperatures, at least 90% of the particles grow as liquids. Therefore, the freezing that occurred during the 1999-2000 Arctic winter was selective, causing most of the particles to remain liquid even in the presence of a small number of frozen particles.

Drdla, K↗
NASA NTRS2000

Simulating Observed Ozone Loss in the Northern Hemisphere Winter

Ozone amounts observed at high Northern latitudes in late winter and early spring have been relatively very low in four of the last six years. On the face of it, this decline appears similar to that observed in the Antarctic in the mid-1980s in spite of the fact that the abundance of stratospheric chlorine is currently steady or decreasing. In order to predict the extent to which this change represents a trend, and to understand what combination of factors produces the low ozone, we need to accurately simulate these observations with models. In this presentation, we focus on the winter of 1999-2000, which exhibited some of the lowest ozone ever recorded in the Northern hemisphere. It also contained the largest-ever assembled set of atmospheric measurements and modeling activities in the SAGE III Ozone Loss and Validation Experiment/Third European Stratospheric Experiment on Ozone (SOLVE/THESEO). We use SOLVE/THESEO observations in comparison with the Goddard 3-D global model of stratospheric chemistry and transport to explore the model's capability to simulate the evolution of ozone and other species through the winter. We will discuss advective transport and mixing, chlorine activation, and denitrification, which are key processes to accurately simulating wintertime ozone. Preliminary results show that, although the model tracer transport and chlorine activation compare relatively well with observations, the magnitude of observed ozone loss is difficult to achieve in the model. Calculated ozone loss is sensitive to denitrification, which presents a major challenge to parameterization in a global model. Simulation requirements and uncertainties will be evaluated.

Kawa, S. R.↗
NASA NTRS1997

Sulfuric Acid and Soot Particle Formation in Aircraft Exhaust

A combination of CN counts, Ames wire impactor size analyses and optical particle counter data in aircraft exhaust results in a continuous particle size distribution between 0.01 micrometer and 1 micrometer particle radius sampled in the exhaust of a Boeing 757 research aircraft. The two orders of magnitude size range covered by the measurements correspond to 6-7 orders of magnitude particle concentration. CN counts and small particle wire impactor data determine a nucleation mode, composed of aircraft-emitted sulfuric acid aerosol, that contributes between 62% and 85% to the total aerosol surface area and between 31% and 34% to its volume. Soot aerosol comprises 0.5% of the surface area of the sulfuric acid aerosol. Emission indices are: EIH2SO4 = 0.05 g/kgFUEL and (0.2-0.5) g/kgFUEL (for 75 ppmm and 675 ppmm fuel-S, respectively), 2.5E4<EISOOT<1.3E-3 g/kgFUEL, and EICN 8E14 and 1.3E16 particles/kgFUEL (for 75 and 675 ppmm fuel-S). The sulfur (gas) to H2SO4 (particle) conversion efficiency is between 10% and 25%.

Pueschel, Rudolf F.↗
NASA NTRS1995

Performance of a focused cavity aerosol spectrometer for measurements in the stratosphere of particle size in the 0.06-2.0-micrometer-diameter range

A focused cavity aerosol spectrometer aboard a NASA ER-2 high-altitude aircraft provided high-resolution measurements of the size of the stratospheric particles in the 0.06-2.0-micrometer-diameter range in flights following the eruption of Mount Pinatubo in 1991. Effects of anisokinetic sampling and evaporation in the sampling system were accounted for by means adapted and specifically developed for this instrument. Calibrations with monodisperse aerosol particles provided the instrument's response matrix, which upon inversion during data reduction yielded the particle size distributions. The resultant dataset is internally consistent and generally shows agreement to within a factor of 2 with comparable measurements simultaneously obtained by a condensation nuclei counter, a forward-scattering spectrometer probe, and aerosol particle impactors, as well as with nearby extinction profiles obtained by satellite measurements and with lidar measurements of backscatter.

Jonsson, H. H.↗
NASA NTRS1994

Analysis of the physical state of one Arctic polar stratospheric cloud based on observations

During the Arctic Airborne Stratospheric Expedition (AASE) simultaneous measurements of aerosol size distribution and NO(y)(HN03 + NO + NO2 + 2(N205)) were made along ER-2 flight paths. The flow characteristics of the NO(y) instrument allow us to derive the condensed NO(y) amount (assumed to be HN03) present during polar stratospheric cloud (PSC) events. Analysis of the January 24th flight indicates that this condensed HN03 amount does not agree well with the aerosol volume if the observed PSCs are composed of solid nitric acid trihydrate (NAT), as is generally assumed. However, the composition agrees well with that predicted for liquid H2S04/HN03/H20 solution droplets using a new Aerosol Physical Chemistry Model (APCM). The agreement corresponds in detail to variations in temperature and humidity. The weight percentages of H2SO4, HN03, and H2O derived from the measurements all correspond to those predicted for ternary, liquid solutions.

Drdla, K.↗
NASA NTRS1993

In-situ measurements of changes in stratospheric aerosol and the N2O-aerosol relationship inside and outside of the polar vortex

Two optical particle counters on the ER-2, together covering a particle size diameter range from 0.1 microns to 23 microns, were used to measure the aerosol bulk quantities integral number, aerosol surface and volume, as well as detailed size distributions inside and outside of the polar vortex in the lower stratosphere. While AAES I (Arctic Airborne Stratospheric Expedition, (Dec. 88 - Feb. 89) was conducted in a period of relative volcanic quiescence, enhancements in aerosol number, surface and volume of factors around 10, 25 and 100 were observed during AASE 2 (Aug. 91 - Mar. 92) due to the eruption of Mt. Pinatubo. The changes in these bulk quantities as well as in the size distributions measured both outside and inside the polar vortex are presented and compared with those obtained in polar stratospheric cloud events (AASE I). Except for a shift towards larger aerosol mixing ratios the general shape of correlograms between the measured N2O and particle mixing ratios remain similar before and after the eruption. Similar correlograms are used to interpret data from vertical profiles inside and outside of the polar vortex.

Borrmann, S.↗
NASA NTRS1993

In-Situ Measurements of Changes in Stratospheric Aerosol and the N2O - Aerosol Relationship inside and outside of the Polar Vortex

Two optical particle counters on the ER-2, together covering a particle size diameter range from 0.1 micrometers to 23 micrometers, were used to measure the aerosol bulk quantities integral number, aerosol surface and volume, as well as detailed size distributions inside and outside of the polar vortex in the lower stratosphere. While AASE I (Arctic Airborne Stratospheric Expedition, (Dec. 1988 - Feb. 1989) was conducted in a period of relative volcanic quiescence, enhancements in aerosol number, surface and volume of factors around 10, 25 and 100 were observed during AASE II (Aug. 1991 - Mar. 1992) due to the eruption of Mt. Pinatubo. The changes in these bulk quantities as well as in the size distributions measured both outside and inside the the polar vortex are presented and compared with those obtained in polar stratospheric cloud events (AASE I). Except for a shift towards larger aerosol mixing ratios the general shape of correlograms between the measured N2O and particle mixing ratios remain similar before and after the eruption. Similar correlograms are used to interpret data from vertical profiles inside and outside of the polar vortex.

Borrmann, S.↗
NASA NTRS1993

In situ observations of aerosol and chlorine monoxide after the 1991 eruption of Mount Pinatubo - Effect of reactions on sulfate aerosol

Highly resolved aerosol size distributions measured from high-altitude aircraft can be used to describe the effect of the 1991 eruption of Mount Pinatubo on the stratospheric aerosol. In some air masses, aerosol mass mixing ratios increased by factors exceeding 100 and aerosol surface area concentrations increased by factors of 30 or more. Increases in aerosol surface area concentration were accompanied by increases in chlorine monoxide at mid-latitudes when confounding factors were controlled. This observation supports the assertion that reactions occurring on the aerosol can increase the fraction of stratospheric chlorine that occurs in ozone-destroying forms.

Wilson, J. C.↗
NASA NTRS1993

Chemical Loss of Ozone in the Arctic Polar Vortex in the Winter of 1991-1992

In situ measurements of chlorine monoxide, bromine monoxide, and ozone are extrapolated globally, with the use of meteorological tracers, to infer the loss rates for ozone in the Arctic lower stratosphere during the Airborne Arctic Stratospheric Expedition II (AASE II) in the winter of 1991-1992. The analysis indicates removal of 15 to 20 percent of ambient ozone because of elevated concentrations of chlorine monoxide and bromine monoxide. Observations during AASE II define rates of removal of chlorine monoxide attributable to reaction with nitrogen dioxide (produced by photolysis of nitric acid) and to production of hydrochloric acid. Ozone loss ceased in March as concentrations of chlorine monoxide declined. Ozone losses could approach 50 percent if regeneration of nitrogen dioxide were inhibited by irreversible removal of nitrogen oxides (denitrification), as presently observed in the Antarctic, or without denitrification if inorganic chlorine concentrations were to double.

Salawitch, R. J.↗
NASA NTRS1993

In situ measurements constraining the role of sulphate aerosols in mid-latitude ozone depletion

In situ measurements of stratospheric sulphate aerosol, reactive nitrogen and chlorine concentrations at middle latitudes confirm the importance of aerosol surface reactions that convert active nitrogen to a less active, reservoir form. This makes mid-latitude stratospheric ozone less vulnerable to active nitrogen and more vulnerable to chlorine species. The effect of aerosol reactions on active nitrogen depends on gas phase reaction rates, so that increases in aerosol concentration following volcanic eruptions will have only a limited effect on ozone depletion at these latitudes.

Fahey, D. W.↗