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Baygents, J. C.

Publications and source records attributed to Baygents, J. C..

Electrohydrodynamic Interaction of a Pair of Spherical Drops

The axisymmetric electrohydrodynamic interaction between two spherical emulsion drops has been examined, using the leaky dielectric model to represent the constitutive behavior of the liquid phases. The results follow from the general solutions in bispherical coordinates to the Laplace equation for the electric potential and the Stokes equations for the velocity field. For drops of similar composition, the electrical interactions induced between the drops by the imposition of the electric field are always attractive, meaning they favor coalescence of the drop pair. The hydrodynamic interactions, however, are not always favorable and, indeed, are shown in certain circumstances to drive the drops apart.

Erker, J. A.↗

Electrophoresis of small particles and fluid globules in weak electrolytes

An examination is conducted of the influence of partial ionization on the electrophoresis of small particles and fluid globules, with a view to the nature of conditions under which dissociation-association (D-A) alters electrokinetics. It is found that, since D-A processes are important in cases where double-layer polarization and relaxation would otherwise prevail, the predicted effect on electrophoretic mobility is greatest for the drops and bubbles whose surfaces are fluid and convection within the interface is significant. While the computation scheme used applies only to situations where forcing-field magnitude is small, the results obtained indicate that D-A processes involving ionogenic solutes may be significant in apolar liquids where electrokinetic phenomena are driven by strong forcing fields.

Baygents, J. C.↗

Electrohydrodynamic effects in continuous flow electrophoresis

We demonstrate experimentally and theoretically the importance of electrohydrodynamic (EHD) flows in continuous-flow electrophoresis (CFE) separations. These flows are associated with variations in the conductivity or dielectric constant, and are quadratic in the field strength. They appear to be the main cause of extraneous and undesired flows in CFE which have degraded separation performance and have until now not been explained. We discuss the importance of EHD flows relative to other effects. We also describe possible techniques for reducing the associated degradation of CFE separations.

Electrophoresis/instrumentation/methods↗