Direct Numerical Simulations of Supercritical Mixing Layers: Heptane-Nitrogen Mixing
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Engineering topics
Publications and source records attributed to Bellan, J..
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Despite the fact that supercritical fluids occur both in nature and in industrial situations, the fundamentals of their behavior is poorly understood because supercritical fluids combine the characteristics of both liquids and gases, and therefore their behavior is not intuitive.
This model predicts the unfiltered variables at droplet locations better than simply interpolating the filtered variables.
The differences between subcritical liquid drop and supercritical fluid drop behavior are shown to be a direct consequence of the length scales near the fluid drop boundary.
Direct numerical simulations of a temporally developing, droplet laden mixing layer undergoing transition to mixing turbulence are conducted. The formulation includes complete two-way couplings of mass, momentum, and energy.
The differences between subcritical liquid drop and supercritical fluid drop behavior are discussed. Under subcritical, evaporative high emission rate conditions, a film layer is present in the inner part of the drop surface which contributes to the unique determination of the boundary conditions; it is this film layer which contributes to the solution's convective-diffusive character. In contrast, under supercritical condition as the boundary conditions contain a degree of arbitrariness due to the absence of a surface, and the solution has then a purely diffusive character. Results from simulations of a free fluid drop under no-gravity conditions are compared to microgravity experimental data from suspended, large drop experiments at high, low and intermediary temperatures and in a range of pressures encompassing the sub-and supercritical regime. Despite the difference between the conditions of the simulations and experiments (suspension vs. free floating), the time rate of variation of the drop diameter square is remarkably well predicted in the linear curve regime. The drop diameter is determined in the simulations from the location of the maximum density gradient, and agrees well with the data. It is also shown that the classical calculation of the Lewis number gives qualitatively erroneous results at supercritical conditions, but that an effective Lewis number previously defined gives qualitatively correct estimates of the length scales for heat and mass transfer at all pressures.
The idea that low soot propensity of high-energy-density (HED) liquid sooting fuels and cost reduction of a multicomponent energetic fuel can be achieved by doping a less expensive, less sooting liquid fuel with HED is tested through numerical simulations.
Direct numerical simulations are performed of a confined three-dimentional, temporally developing, initially isothermal gas mixing layer with one stream laden with as many as 7.3 x 10***sup5*** evaporating hydrocarbon droplets, at moderate gas temperature and subsonic Mach number.
The high-energy-density (HED) fuels developed under U.S. Navy sponsorship as a replacement for conventional liquid fuels, in its missile propulsion systems have the drawback of high soot propensity: this makes misiles visible and thus strategically unacceptabel.
A model is presented for the behavior of a polydisperse cluster of spherical evaporating drops in a cylindrical, axisymmetric inviscid vortex. The formulation accounts for drop interactions and for complete dynamic and thermodynamic coupling between drops and gas.
An Investigation of the statistical description of binary mixing and/or reaction between a carrier gas and an evaporated vapor species in two-phase gas-liquid turbulent flows is perfomed through both theroetical analysis and comparisons with results from direct numerical simulations (DNS) of a two-phase mixing layer.
Soot propensity is studied numerically for an initially binary size, axisymmetric cluster of evaporating drops by defining it as the propensity for nucleation reations to occur; the study does not address physical or chemical processes ensuing after soot nucleation.
A variety of liquid droplet evaporation models, including both classical equilibrium and non-equilibrium Langmuir-Knudsen formulations, are evaluated through comparisons with experiments with particular emphasis on computationally efficient procedures for many-droplet gas-liquid flow simulations.
A numerical study is performed in order to evaluate the performance and optimal operating conditions of vortex pyrolysis reactors used for condensable tar production from biomass.
A model has been developed for the behavior of an isolated fluid drop of a single compound immersed into another compound in finite, quiescent surroundings at supercritical conditions. The model is based upon fluctuation theory which accounts for both Soret and Dufour effects in the calculation of the transport matrix relating molar and heat fluxes to the transport properties and the thermodynamic variables.
A model of fluid drop behavior in clusters has been developed including the interactions induced by the drop proximity. The model is based upon the global conservation equations for the cluster coupled to isolated fluid drop equations previously developed.
A model has been developed for the behavior of an isolated fluid drop of a single componet species immersed into another single component species in finite, quiescent surroundings at supercritical condidionts
Concern over the future availability of high quality liquid fuels or use in furnaces and boilers prompted the U. S. Department of Energy (DOE) to consider alternate fuels as replacements for the high grade liquid fuels used in the 1970's and 1980's. Alternate fuels were defined to be combinations of a large percentage of viscous, low volatility fuels resulting from the low end of distillation mixed with a small percentage of relatively low viscosity, high volatility fuels yielded by the high end of distillation. The addition of high volatility fuels was meant to promote desirable characteristics to a fuel that would otherwise be difficult to atomize and burn and whose combustion would yield a high amount of pollutants. Several questions thus needed to be answered before alternate fuels became commercially viable. These questions were related to fuel atomization, evaporation, ignition, combustion and pollutant formation. This final report describes the results of the most significant studies on ignition and combustion of alternative fuels.