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Engineering topics

Bernius, Mark T.

Publications and source records attributed to Bernius, Mark T..

14 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Two-step sulfonation process for the conversion of polymer fibers to carbon fibers

Disclosed herein are processes for preparing carbon fibers, comprising: sulfonating a polymer fiber with a sulfonating agent that is fuming sulfuric acid, sulfuric acid, chlorosulfonic acid, or a combination thereof; treating the sulfonated polymer with a heated solvent, wherein the temperature of the heated solvent is at least 95.degree. C.; and carbonizing the resulting product by heating it to a temperature of 501-3000.degree. C. Carbon fibers prepared according to these methods are also disclosed herein.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Processes for preparing carbon fibers using gaseous sulfur trioxide

Disclosed herein are processes for preparing carbonized polymers, such as carbon fibers, comprising: sulfonating a polymer with a sulfonating agent that comprises SO.sub.3 gas to form a sulfonated polymer; treating the sulfonated polymer with a heated solvent, wherein the temperature of said solvent is at least 95.degree. C.; and carbonizing the resulting product by heating it to a temperature of 500-3000.degree. C.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Processes for preparing carbon fibers using sulfur trioxide in a halogenated solvent

Disclosed here are processes for preparing carbonized polymers (preferably carbon fibers), comprising sulfonating a polymer with a sulfonating agent that comprises SO.sub.3 dissolved in a solvent to form a sulfonated polymer; treating the sulfonated polymer with a heated solvent, wherein the temperature of the solvent is at least 95.degree. C.; and carbonizing the resulting product by heating it to a temperature of 500-3000.degree. C. Carbon fibers made according to these methods are also disclosed herein.

36 MATERIALS SCIENCE↗
NASA NTRS1992

Combined Velocity/Charge-To-Mass-Ratio Analyzer

Instrument analyzes ions according to velocity and ratio of mass to electric charge. State-of-the-art combination of two instruments: time-of-flight analyzer and electrostatic analyzer functioning as mass spectrometer. Features include compactness, light weight, and low power. Terrestrial versions useful in chemical analysis, chromatography, and analysis of plasmas.

Chutjian, Ara↗
NASA NTRS1990

High-Voltage Square-Wave Generator

Fast switching circuit puts out rectangular pulses of order of kilovolt or greater at typical repetition frequencies as high as hundreds of kilohertz and with rise times as short as 50 ns. Designed around power metal oxide/semiconductor field-effect transistors (MOSFET's). Optically isolated power MOSFET's in series rapidly switch output between high voltages V(sub 1) and V(sub 2). Used to supply power to pulsed laser or to modulate beam of charged particles in laboratory experiment or industrial process.

Bernius, Mark T.↗
NASA NTRS1990

Reversal electron attachment ionizer for detection of trace species

An in-line reversal electron, high-current ionizer capable of focusing a beam of electrons to a reversal region and executing a reversal of said electrons, such that the electrons possess zero kinetic energy at the point of reversal, may be used to produce both negative and positive ions. A sample gas is introduced at the point of electron reversal for low energy electron-(sample gas) molecule attachment with high efficiency. The attachment process produces negative ions from the sample gas, which includes species present in trace (minute) amounts. These ions are extracted efficiently and directed to a mass analyzer where they may be detected and identified. The generation and detection of positive ions is accomplished in a similar fashion with minimal adjustment to potentials applied to the apparatus.

Bernius, Mark T.↗
NASA NTRS1990

High-Sensitivity Ionization Trace-Species Detector

Features include high ion-extraction efficiency, compactness, and light weight. Improved version of previous ionization detector features in-line geometry that enables extraction of almost every ion from region of formation. Focusing electrodes arranged and shaped into compact system of space-charge-limited reversal electron optics and ion-extraction optics. Provides controllability of ionizing electron energies, greater efficiency of ionization, and nearly 100 percent ion-collection efficiency.

Bernius, Mark T.↗
NASA NTRS1990

Improved high-voltage, high-frequency square-wave generator

This paper describes the design and operation of a prototype high-voltage full-floating high-frequency square-wave generator which is an improved version of the generator developed by Bernius and Chutjian (1989). The present design overcomes possible momentary simultaneous ON states in the MOSFET configuration and is less susceptible to deleterious effects caused by the component aging and replacements with nonidentical parts. The circuit performs well over a wide voltage and frequency range, until a limit is imposed by the operating characteristics of the active MOSFET elements. Circuit diagrams are presented.

Bernius, Mark T.↗
NASA NTRS1990

Application of reversal electron attachment for ultrasensitive detection of thermal electron-attaching molecules - CCl4 and C6H5O2

A standard gas-dilution method was used to determine the selective response of the reversal electron attachment detector to carbon tetrachloride concentrations in nitrogen. Data are provided that determine the lowest concentration of sample detectable with the present instrumental configuration as being below 1.0 part per trillion by volume. The incorporation of a 90-deg electrostatic deflector with the quadrupole mass spectrometer is shown to be vital, and with it, negative-ion quadrupole mass spectrometry is used to characterize the ionization process. Observations are also made of the reversal electron attachment response to nitrobenzene. The analytical potential of reversal electron capture negative-ion mass spectrometry is examined, and areas for future development are discussed.

Bernius, Mark T.↗
NASA NTRS1989

Pulsed, high-current, in-line reversal electron attachment detector

A new, pulsed, high-current, in-line reversal electron attachment ionizer/detector is described. The ionizer is capable of delivering a beam of electrons into an electrostatic mirror field to form a planar wall of electrons having zero kinetic energy. Electron attachment to a molecular target at the reversal point produces either parent or fragment negative ions through a zero-energy (s-wave) state. The atomic or molecular ion is pulsed out of the attachment region approximately 2 microsec after the electrons are pulsed off, and focused onto the entrance plane of a quadrupole mass analyzer. The sensitivity of the apparatus is preliminarily assessed, and its higher-energy behavior with regard to molecular attachment and ionization is described.

Bernius, Mark T.↗
NASA NTRS1989

Reversal electron attachment ionizer for detection of trace species

An in-line reversal electron, high-current ionizer capable of focusing a beam of electrons to a reversal region and executing a reversal of the electrons, such that the electrons possess zero kinetic energy at the point of reversal, may be used to produce both negative and positive ions. A sample gas is introduced at the point of electron reversal for low energy electron-(sample gas) molecule attachment with high efficiency. The attachment process produces negative ions from the sample gas, which includes species present in trace (minute) amounts. These ions are extracted efficiently and directed to a mass analyzer where they may be detected and identified. The generation and detection of positive ions is accomplished in a similar fashion with minimal adjustment to potentials applied to the apparatus.

Bernius, Mark T.↗
NASA NTRS1989

High-voltage, full-floating 10-MHz square-wave generator with phase control

Wherein a fast (50 ns) rise-time high-frequency square-wave generator capable of switching between arbitrary voltages of high potential difference (1000 V or more) is described utilizing solid-state circuitry of low power consumption. Power field effect transistors are used as the active switching element, which afford compact size and simplified circuit construction. With the addition of monostable multivibrators, high-voltage square-wave pulse trains of controllable phase are produced. The generator should find application in a wide variety of situations where fast switching between high voltages is required, such as in time-of-flight, coincidence, and beams-modulation experiments.

Bernius, Mark T.↗
NASA NTRS1988

An electrostatically and a magnetically confined electron gun lens system

Focal properties, electron trajectory calculations, and geometries are given for two electron 'gun' lens systems that have a variety of applications in, for example, electron-neutral and electron-ion scattering experiments. One nine-lens system utilizes only electrostatic confinement and is capable of focusing electrons onto a fixed target with extremely small divergence angles, over a range of final energies 1-790 eV. The second gun lens system is a simpler three-lens system suitable for use in a uniform, solenoidal magnetic field. While the focusing properties of such a magnetically confined lens systenm are simpler to deal with, the system does illustrate features of electron extraction and Brillouin flow that have not been suitably emphasized in the literature.

Bernius, Mark T.↗