Engineering topics

Bezard, Bruno

Publications and source records attributed to Bezard, Bruno.

15 records

NASA NTRS2019

Detection of Propadiene on Titan

The atmosphere of Titan, the largest moon of Saturn, is rich in organic molecules, and it has been suggested that the moon may serve as an analog for the pre-biotic Earth due to its highly reducing chemistry and existence of global hazes. Photochemical models of Titan have predicted the presence of propadiene (historically referred to as allene), CH2CCH2, an isomer of the well-measured propyne (also called methylacetylene) CH3CCH, but its detection has remained elusive due to insufficient spectroscopic knowledge of the molecule. This has recently been remedied with an updated spectral line list. Here we present the first unambiguous detection of the molecule in any astronomical object, observed with the Texas Echelle Cross Echelle Spectrograph on the NASA Infrared Telescope Facility in 2017 July. We model its emission line near 12 μm and measure a volume mixing ratio of (6.9 ± 0.8) × 10(exp −10) at 175 km, assuming a vertically increasing abundance profile as predicted in photochemical models. Cassini measurements of propyne made during 2017 April indicate that the abundance ratio of propyne to propadiene is 8.2 ± 1.1 at the same altitude. This initial measurement of the molecule in Titan's stratosphere paves the way toward constraining the amount of atomic hydrogen available on Titan, as well as future mapping of propadiene on Titan from 8 m and larger ground-based observatories, and future detection on other planetary bodies.

Propadiene or allene↗

NASA NTRS2016

Titan Science with the James Webb Space Telescope

The James Webb Space Telescope (JWST), scheduled for launch in 2018, is the successor to the Hubble Space Telescope (HST) but with a signicantly larger aperture (6.5 m) and advanced instrumentation focusing on infrared science (0.6-28.0 microns). In this paper, we examine the potential for scientic investigation of Titan using JWST, primarily with three of the four instruments: NIRSpec, NIRCam, and MIRI, noting that science with NIRISS will be complementary. Five core scientic themes are identied: (1) surface (2) tropospheric clouds (3) tropospheric gases (4) stratospheric composition, and (5) stratospheric hazes. We discuss each theme in depth, including the scientic purpose, capabilities, and limitations of the instrument suite and suggested observing schemes. We pay particular attention to saturation, which is a problem for all three instruments, but may be alleviated for NIRCam through use of selecting small sub-arrays of the detectorssufcient to encompass Titan, but with signicantly faster readout times. We nd that JWST has very signicant potential for advancing Titan science, with a spectral resolution exceeding the Cassini instrument suite at near-infrared wavelengths and a spatial resolution exceeding HST at the same wavelengths. In particular, JWST will be valuable for time-domain monitoring of Titan, given a ve- to ten-year expected lifetime for the observatory, for example, monitoring the seasonal appearance of clouds. JWST observations in the post-Cassini period will complement those of other large facilities such as HST, ALMA, SOFIA, and next-generation ground-based telescopes (TMT, GMT, EELT).

Nixon, Conor A.↗

NASA NTRS2010

Meridional Distribution of CH3C2H and C4H2 in Saturn's Stratosphere from CIRS/Cassini Limb and Nadir Observations

Limb and nadir spectra acquired by Cassini/CIRS (Composite InfraRed Spectrometer) are analyzed in order to derive, for the first time, the meridional variations of diacetylene (C4H2) and methylacetylene (CH3C2H) mixing ratios in Saturn's stratosphere, from 5 hPa up to 0.05 hPa and 80 deg S to 45 deg N. We find that the C4H2 and CH3C2H meridional distributions mimic that of acetylene (C2H2), exhibiting small-scale variations that are not present in photochemical model predictions. The most striking feature of the meridional distribution of both molecules is an asymmetry between mid-southern and mid-northern latitudes. The mid-southern latitudes are found depleted in hydrocarbons relative to their northern counterparts. In contrast, photochemical models predict similar abundances at north and south mid-latitudes. We favor a dynamical explanation for this asymmetry, with upwelling in the south and downwelling in the north, the latter coinciding with the region undergoing ring shadowing. The depletion in hydrocarbons at mid-southern latitudes could also result from chemical reactions with oxygen-bearing molecules. Poleward of 60 deg S, at 0.1 and 0.05 hPa, we find that the CH3C2H and C4H2 abundances increase dramatically. This behavior is in sharp contradiction with photochemical model predictions, which exhibit a strong decrease towards the south pole. Several processes could explain our observations, such as subsidence, a large vertical eddy diffusion coefficient at high altitudes, auroral chemistry that enhances CH3C2H and C4H2 production, or shielding from photolysis by aerosols or molecules produced from auroral chemistry. However, problems remain with all these hypotheses, including the lack of similar behavior at lower altitudes. Our derived mean mixing ratios at 0.5 hPa of (2.4 +/- 0.3) 10(exp -10) for C4H2 and of (1.1 +/- 0.3) 10(exp -9) for CH3C2H are compatible with the analysis of global-average ISO observations performed by Moses et al. Finally, we provide values for the ratios [CH3C2H]/[C2H2] and [C4H2]/[C2H2] that can constrain the coupled chemistry of these hydrocarbons.

Guerlet, Sandrine↗

NASA NTRS2000

Photochemistry of Saturn's Atmosphere: Hydrocarbon Chemistry and Comparisons with ISO Observations - 1

To investigate the details of hydrocarbon photochemistry on Saturn, we have developed a one-dimensional diurnally averaged model that couples hydrocarbon and oxygen photochemistry, molecular and eddy diffusion, radiative transfer, and condensation. The model results are compared with observations from the Infrared Space Observatory (ISO) to place tighter constraints on molecular abundances, to better define Saturn's eddy diffusion coefficient profile, and to identify important chemical schemes that control the abundances of the observable hydrocarbons in Saturn's upper atmosphere. From the ISO observations, we determine that the column 12 densities of CH3, CH3C2H, and C4H2 above 10 mbar are 4 (sup +2) (sub -1.5) x 10 (exp 13) cm (sup -2), (1.1 plus or minus 0.3) x 10 (exp 15) cm (exp -2), and (1.2 plus or minus 0.3) x 10 (exp 14) cm (sup -2), respectively. The observed ISO emission features also indicate C2H2 mixing ratios of 1.2 (sup +0.9) (sub -0.6) x 10 (exp -6) at 0.3 mbar and (2.7 plus or minus 0.8) x 10 (exp -7) at 1.4 mbar, and a C2H6 mixing ratio of (9 plus or minus 2.5) x 10 (exp -6) at 0.5 mbar. Upper limits are provided for C2H4, CH2CCH2, C3H8, and C6H2 sensitivity of the model results to variations in the eddy diffusion coefficient profile, the solar flux, the CH4 photolysis branching ratios, the atomic hydrogen influx, and key reaction rates are discussed in detail. We find that C4H2 and CH3C2H are particularly good tracers of important chemical processes and physical conditions in Saturn's upper atmosphere, and C2H6 is a good tracer of the eddy diffusion coefficient in Saturn's lower stratosphere. The eddy diffusion coefficient must be smaller than approximately 3 x 10 (exp 4) sq cm s (sup -1) at pressures greater than 1 mbar in order to reproduce the C2H6 abundance inferred from ISO observations. The eddy diffusion coefficients in the upper stratosphere could be constrained by observations of CH3 radicals if the low-temperature chemistry of CH3 were better understood. We also discuss the implications of our modeling for aerosol formation in Saturn's lower stratosphere-diacetylene, butane, and water condense between approximately 1 and 300 mbar in our model and will dominate stratospheric haze formation at nonauroral latitudes. Our photochemical models will be useful for planning observational sequences and for analyzing data from the upcoming Cassini mission.

Moses, Julianne I.↗

NASA NTRS2000

Photochemistry Saturn's Atmosphere: Effects of an Influx of External Oxygen - 2

We use a one-dimensional diurnally averaged model of photochemistry and diffusion in Saturn's stratosphere to investigate the influence of extraplanetary debris on atmospheric chemistry. In particular, we consider the effects of an influx of oxygen from micrometeoroid ablation or from ring-particle diffusion; the contribution from cometary impacts, satellite debris, or ring vapor is deemed to be less important. The photochemical model results are compared directly with Infrared Space Observatory (ISO) observations to constrain the influx of extraplanetary oxygen to Saturn. From the ISO observations, we determine that the column densities of CO2 and H2O above 10 mbar in Saturn's atmosphere are (6.3 +/- 1) x 10(exp 14) and (1.4 +/- 0.4) x 10(exp 15)/ square cm, respectively; our models indicate that a globally averaged oxygen influx of (4+/-2) x 10(exp 6) O atoms /sq cm/s is required to explain these observations. Models with a locally enhanced influx of H20 operating over a small fraction of the projected area do not provide as good a fit to the ISO H2O observations. If volatile oxygen compounds comprise one-third to one-half of the exogenic source by mass, then Saturn is currently being bombarded with (3 +/- 2) x 10(exp -16) g/square cm/s of extraplanetary material. To reproduce the observed CO2/H2O ratio in Saturn's stratosphere, some of the exogenic oxygen must arrive in the form of a carbon-oxygen bonded species such as CO or CO2. An influx consistent with the composition of cometary ices fails to reproduce the high observed CO2/H2O ratio, suggesting that (i) the material has ices that are slightly more carbon-rich than is typical for comets, (ii) a contribution from an organic-rich component is required, or (iii) some of the hydrogen-oxygen bonded material is converted to carbon-oxygen bonded material without photochemistry (e.g., during the ablation process). We have also reanalyzed the 5-micron CO observations of Noll and Larson and determine that the CO lines are most sensitive to the 100- to 400-mbar column density for which we derive a range of (0.7-1.5) x 10(exp 17)/square cm; the CO observations do not allow us to distinguish between an external or internal source of CO on Saturn. If we assume that all the extraplanetary oxygen derives from a micrometeoroid source, then the unfocused dust flux at 9.5 AU must be (i) (1 +/- 0.7) x 10(exp -16) g/square cm/s if interstellar grains are the source of the external oxygen on Saturn, (ii) (4 +/- 3) x 10 (exp -17) g/ sq. cm./s if IDPs on randomly inclined, highly eccentric orbits (e.g., Halley-type comet grains) are the source of the external oxygen, or (iii) (2+/- 1.4) x 10(exp -18)/g/sq cm/s if IDPs on low inclination, low eccentricity orbits (e.g., Kuiper-belt grains) are the source of the external oxygen. These estimates can be used in combination with future Cassini dust detection data to determine the ultimate source of the dust at Saturn's distance from the Sun.

Moses, Julianne I.↗

NASA NTRS1993

Thermal profiles in the auroral regions of Jupiter

The temperature structure within the northern auroral region of Jupiter is studied by reanalyzing the Voyager 1/infrared interferometer and radiometer spectrometer (IRIS) spectra. The total measured excess infrared auroral zone emission (averaged over the IRIS field of view) in the hydrocarbon bands between 7 and 13 microns is found to be about 208 ergs/cm/s over an area of about 2 x 10(exp 18) sq cm with a resulting power output of 4 x 10(exp 13) W. In comparison, the total energy deposition by magnetospheric charged particles has been estimated on the basis of UV observations to range between 1 x 10(exp 13) and 4 x 10(exp 13) W over a comparable area. The large amount of radiated energy observed in the infrared may imply an additional heat source in the auroral regions (possibly Joule heating). A new set of thermal profiles of Jupiter's high-latitude upper atmosphere has also been derived. These profiles have a large temperature enhancement in the upper stratosphere and are constrained to reproduce the CH4 emission at 7.7 microns. The emission in the other hydrocarbon bands (C2H2 and C2H6) is found to depend on the depth to which the temperature enhancement extends, which further constrains the thermal profiles. This study shows that a large temperature enhancement in the upper stratosphere and lower thermosphere can explain the observed excess hydrocarbon emission bands; thus smaller variations in hydrocarbon abundances (between the high latitudes and the equatorial and middle latitudes) are required than has been assumed in previous models.

Drossart, Pierre↗

NASA NTRS1993

The abundance of sulfur dioxide below the clouds of Venus

We present a new method for determining the abundance of sulfur dioxide below the clouds of Venus. Absorption by the 3nu3 band of SO2 near 2.45 microns has been detected in high-resolution spectra of the night side of Venus recorded at the Canada-France Hawaii telescope in 1989 and 1991. The inferred SO2 abundance is 130 +/- 40 ppm at all observed locations and pertains to the 35-45 km region. These values are comparable to those measured by the Pioneer Venus and Venera 11/12 entry probes in 1978. This stability stands in contrast to the apparent massive decrease in SO2 observed at the cloud tops since these space missions. These results are consistent with laboratory and modeling studies of the SO2 destruction rates in the lower atmosphere of Venus. The new spectroscopic technique presented here allows a remote monitoring of the SO2 abundance below the clouds, a likely tracer of Venusian volcanism.

Bezard, Bruno↗

NASA NTRS1993

Near-infrared light from Venus' nightside - A spectroscopic analysis

The near-IR spectra of the Venus nightside emission are here simulated by means of a radiative transfer code that allows for emission, absorption, and scattering by atmospheric gases and particles. An effort is made to assess the adequacy of current gas data bases in simulating Venus' nightside near-IR spectra and, within these limitations, to derive information on gas abundances below the main clouds and these clouds' optical thickness. It is in this way established that the HITRAN data base for the permitted transitions of CO2 is completely inadequate for simulating the Venus nightside near-IR emissions.

Pollack, James B.↗

NASA NTRS1992

Stratospheric ethane on Neptune - Comparison of groundbased and Voyager IRIS retrievals

Near-simultaneous ground and spacecraft measurements of 12-micron ethane emission spectra during the Voyager encounter with Neptune have furnished bases for the determination of stratospheric ethane abundance and the testing and constraining of Neptune methane-photochemistry models. The ethane retrievals were sensitive to the thermal profile used. Contribution functions for warm thermal profiles peaked at higher altitudes, as expected, with the heterodyne functions covering lower-pressure regions. Both constant- and nonconstant-with-height profiles remain candidate distributions for Neptune's stratospheric ethane.

Kostiuk, Theodor↗

NASA NTRS1992

The tropospheric abundances of NH3 and PH3 in Jupiter's Great Red Spot, from Voyager IRIS observations

The tropospheric abundances of NH3 and PH3 in Jupiter's Great Red Spot (GRS) are presently determined on the basis of a group of Voyager IRIS spectra, and compared with those of the surrounding South Tropical Zone (STZ) obtained from another two groups of IRIS spectra, in order to characterize the GRS's chemistry and dynamics. Although the GRS is believed to be a region of strong vertical transport, NH3 depletion is surprisingly found to occur below the tropopause within the GRS. Since one of the STZ's selections has a temperature-pressure profile similar to that of the GRS below the 300 mbar level, condensation cannot explain the low NH3 abundance in the GRS.

Griffith, Caitlin A.↗

NASA NTRS1992

The synthetic infrared spectrum of Titan at high spectral resolution

A systematic study made of the observability of minor species in Titan's atmosphere is reported. This was done by modeling its thermal spectrum at 0.5/cm resolution under the conditions of the Infrared Space Observatory (ISO) and Composite Infrared Radiometer Spectrometer (CIRS), and by exploring the capabilities of the 0.03/cm resolution mode of ISO.

Coustenis, Athena↗

NASA NTRS1991

Hydrocarbons in Neptune's stratosphere from Voyager infrared observations

The ethane and acetylene emissions observed in the Voyager IR spectra of Neptune are analyzed. The mean hydrocarbon abundances are derived from a comparison of the disk-averaged spectral selection with synthetic spectra, using updated temperature information from the Voyager 2 radio occultation data and constraints from the ground-based stellar occultation measurements. The observations are used to test photochemical models generated for various eddy mixing profiles and stratospheric methane mole fractions. Finally, the altitudinal variability of the acetylene emission strength was investigated from a large set of IRIS spectra, and the derived variation is compared with that observed at lower wavenumbers (250 and 350 per cm) where the troposphere and the lower stratosphere are probed.

Bezard, Bruno↗

NASA NTRS1991

Deuterium on Venus - Observations from earth

Absorption lines of HDO and H2O have been detected in a 0.23-wave number resolution spectrum of the dark side of Venus in the interval 2.34 to 2.43 microns, where the atmosphere is sounded in the altitude range from 32 to 42 kilometers (8 to 3 bars). The resulting value of the D/H ratio is 120 + or - 40 times the telluric ratio, providing unequivocal confirmation of in situ Pioneer Venus mass spectrometer measurements that were in apparent conflict with an upper limit set from International UIltraviolet Explorer spectra. The 100-fold enrichment of the D/H ratio on Venus compared to earth is thus a fundamental constraint on models for its atmospheric evolution.

De Bergh, Catherine↗

NASA NTRS1990

The deep atmosphere of Venus revealed by high-resolution nightside spectra

The first high-resolution spectroscopic observations of the night side of Venus obtained in two narrow spectral windows centered at 1.74 and 2.3 microns, where the nightside is anomalously bright, are reported. Absorption features from CO2, CO, H2O, HDO, HCl, HF, and COS are detected, and there are a number of unidentified features. A preliminary analysis indicates that the observed radiation is thermal emission from atmospheric layers in the eight-bar pressure region for the 2.3 micron window and even deeper at 1.7 micron. The derived CO and H2O abundances agree with in situ Pioneer measurements in the deep troposphere and are consistent with the high deuterium enrichment inferred from Pioneer data. The first measurements of HCl and HF below the clouds are reported along with the first firm detection of COS.

Bezard, Bruno↗

NASA NTRS1986

Enhanced acetylene emission near the north pole of Jupiter

The present paper is concerned with observations of acetylene fundamental and hot band vibrational emission lines from the planet Jupiter. It is pointed out that the observation of a polar bright spot in the atmosphere of Jupiter is characterized by an enhancement in the individual lines of C2H2 which can be interpreted as an enhancement in the acetylene abundance. However, a purely thermal effect, on non-LTE phenomena cannot be excluded. The intensity of the observed hot band lines is also consistent with either hypothesis. The reported observations were performed with a cooled Fabry-Perot Grating Spectrometer (FPGS). Observations and instrumentation are considered in detail along with the calculation of synthetic spectra on the basis of a line-by-line computation, and the interpretation of the obtained data.

Drossart, Pierre↗