Search NASA⌕ Search

Engineering topics

Blake, D. R.

Publications and source records attributed to Blake, D. R..

39 records · Page 3

Global atmospheric concentrations and source strength of ethane

A study of the variation in ethane (C2H6) concentration between northern and southern latitudes over three years is presented together with a new estimate of its source strength. Ethane concentrations vary from 0.07 to 2 p.p.b.v. (parts per billion by volume) in air samples collected in remote surface locations in the Pacific (latitude 71 N-47 S) in all four seasons between September 1984 and June 1985. The variations are consistent with southerly transport from sources located chiefly in the Northern Hemisphere, further modified by seasonal variations in the strength of the reaction of C2H6 with OH radicals. These global data can be combined with concurrent data for CH4 and the laboratory reaction rates of each with OH to provide an estimate of three months as the average atmospheric lifetime for C2H6 and 13 + or - 3 Mtons for its annual atmospheric release.

Blake, D. R.↗

World-wide increase in tropospheric methane, 1978-1983

Techniques used to assess methane concentration in the troposphere are described, and data obtained during the period from 1978 to 1983 are presented in detail. Tropospheric methane concentrations in remote locations averaged a yearly world-wide increase of 0.018 + or - 0.002 parts per million by volume (ppmv). Average world-wide tropospheric concentration of methane in dry air was 1.625 ppmv at the end of 1983 measured against an NBS standard certified as 0.97 ppmv. Contributing to this steady increase in methane concentration are increases in the source strengths from cattle and rice fields, which in turn result from CO, CH4 and HO coupling. Among the physical and chemical effects is an increase in greenhouse warming of about 0.04 C per decade.

Blake, D. R.↗

Methane concentrations and source strengths in urban locations

The results of a six year measurement of trace gases in 18 different urban and remote areas throughout the Northern and Southern Hemispheres are reported. It is found that the measurements are consistent with a yearly atmospheric release of 30 to 60 megatons of CH4 in urban environments. Concentrations of CCl3F, CCl2F2, and CH3CCl3 were also found to be higher in the same urban samples than in corresponding samples from remote areas. The 'urban excess' (urban concentration minus remote concentration) was generally 1000 to 2000 times larger on a molar basis for CH4 than for CCl3F. The fraction of world-wide methane release occurring in the urban environment is estimated from the concentration ratios for CH4 vs CCl3F. It is shown that about 8 to 15 percent of atmospheric methane release occurs in urban areas.

Blake, D. R.↗