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Blau, Peter J.

Publications and source records attributed to Blau, Peter J..

The characterization of wear-causing particles and silica sand in particular

Erodants and abradants are two types of wear-causing particles (WCP). Despite their effects on the severity and rate of wear, WCP are inadequately characterized in a surprising number of publications, especially those involving impingement erosion and three-body abrasion. That shortfall makes it difficult to correlate features of WCP with the details of worn surfaces, or to develop wear models that account for those features. It is argued that the documentation of WCP should go beyond simply reporting their composition and mean particle size. In late 1985, ASTM Committee G2 on Wear and Erosion established a task group on the characterization of WCP. At that time, image analysis was slower and less sophisticated than it is today. While that ASTM task group failed to produce a consensus standard, computerized particle characterization methods were developing in fields other than tribology, fields like geoscience, heavy sand mining, materials processing, and pharmaceuticals. A notable exception to this is ferrography, which is a widely-used diagnostic for lubricated tribosystems. In the context of dry wear, it is useful to identify which features of WCP would be beneficial to document, and to identify some techniques and scales of detail appropriate to particular tribosystems. In this paper, examples are presented for the morphological and mechanical characterization of silica sand grains, as prompted by a triboanalysis of the abrasive and erosive wear of biomass pre-processing equipment. The authors propose a minimum level of documentation for WCP, one that can enrich tribosystem analysis both in laboratory tests and field studies.

36 MATERIALS SCIENCE↗

Investigating grid-to-rod fretting wear of nuclear fuel claddings using a unique autoclave fretting rig

Fuel rods in a pressurized water nuclear reactor (PWR) experience coolant flow-induced relative motion against the grid support features, a phenomenon called grid-to-rod fretting (GTRF), which may cause progressive fretting wear damage. Wear-through of the cladding on fuel rods will leak the radioactive fuel into the coolant loop to significantly increase the radiation level in PWR primary loop and often trigger expensive Post Irradiation Examination. In this work, a unique autoclave fretting test rig was designed and fabricated to allow studying GTRF using actual cladding and grid materials. Water temperature was up to 220 °C, which was designed to mimic the environment in an industry full-assembly reactor core simulator. The contact load (0.1–1 N), oscillation frequency (20–30 Hz) and stroke (50–150 µm), and work rate (1–3 mW) were defined based on simulations of GTRF in an actual reactor. Using this autoclave GTRF rig, tests were conducted to learn the effect of water temperature and to investigate the wear behavior of different cladding-grid material combinations currently used in actual PWRs, including Zr alloy claddings without and with pre-oxidation against Zr alloy and Inconel grids. Higher water temperature evidently increased the cladding wear, and pre-oxidation of the Zr alloy and/or using the Inconel grid effectively reduced the wear rate. In conclusion, results were correlated with the data of a full-size industry reactor core simulator in terms of both wear rate and wear scar morphology.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Summary report describing CASL accomplishments in support of the GTRF Challenge Problem

Coolant flow-induced relative motions between structural components in the cores of lightwater nuclear reactor cores, a phenomenon called Grid-To-Rod Fretting (GTRF), can result in progressive wear damage. Wear-through of the cladding on fuel rods can introduce radioactive species into the coolant loop. Such an event is termed a “leaker” and may cause premature and expensive reactor shut-down. GTRF results in wear scars of various sizes, shapes, and depths on the sides of the fuel rod cladding. Fretting damage may also occur on the springs and dimples that hold the fuel rods in place, resulting in the formation of gaps. Due to variability in the operating conditions of the reactor (burn-up rates and operating campaigns) and the associated variable cladding surface oxide film growth and removal rates, the wear coefficient is unlikely to remain constant over time. Therefore, constant wear rate models do not accurately account for transients in the operating conditions.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

GTRF Cladding Wear Modeling and Experimental Validation

Coolant flow-induced relative motions between certain structural components in the cores of lightwater nuclear reactor cores, a phenomenon called Grid-To-Rod Fretting (GTRF), can result in progressive wear damage. Wear-through of the cladding on fuel rods can introduce radioactive species into the coolant loop. Such an event is termed a “leaker” and may cause premature and expensive reactor shut-down. GTRF results in wear scars of various sizes, shapes, and depths on the sides of the fuel rod cladding. Fretting damage may also occur on the springs and dimples that hold the fuel rods in place, resulting in the formation of gaps. Due to variability in the operating conditions of the reactor (burn-up rates and operating campaigns) and the associated variable cladding surface oxide film growth and removal rates, the wear coefficient is unlikely to remain constant over time. Therefore, constant wear rate models do not accurately account for transients in the operating conditions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Friction behavior of a multi-interface system and improved performance by AlMgB 14 –TiB 2 –C and diamond-like-carbon coatings

We investigated friction behavior of a bearing system with two interfaces involved: a roller component experiencing rolling–sliding interaction against twin cylinders under point contacts while simultaneously undergoing pure sliding interaction against a socket under a conformal contact. Lubrication modeling predicted a strong correlation between the roller's rolling condition and the system's friction behavior. Experimental observations first validated the analytical predictions using steel and iron components. Diamond-like-carbon (DLC) coating and AlMgB 14 –TiB 2 coating with a carbon topcoat (BAMC) were then applied to the roller and twin cylinders, respectively. In conclusion, testing and analysis results suggest that the coatings effectively decreased the slip ratio for the roller–cylinder contact and the sliding friction at both bearing interfaces and, as a result, significantly reduced the system frictional torque.

42 ENGINEERING↗

Assessment of wear coefficients of nuclear zirconium claddings without and with pre-oxidation

In the cores of pressurized water nuclear reactors, water-flow induced vibration is known to cause claddings on the fuel rods to rub against their supporting grids. Such grid-to-rod-fretting (GTRF) may lead to fretting wear-through and the leakage of radioactive species. The surfaces of actual zirconium alloy claddings in a reactor are inevitably oxidized in the high-temperature pressurized water, and some claddings are even pre-oxidized. As a result, the wear process of the surface oxide film is expected to be quite different from the zirconium alloy substrate. In this paper, we attempt to measure the wear coefficients of zirconium claddings without and with pre-oxidation rubbing against grid samples using a bench-scale fretting tribometer. Results suggest that the volumetric wear coefficient of the pre-oxidized cladding is 50 to 200 times lower than that of the untreated cladding. In terms of the linear rate of wear depth, the pre-oxidized alloy wears about 15 times more slowly than the untreated cladding. Finally, fitted with the experimentally-determined wear rates, a stage-wise GTRF engineering wear model demonstrates good agreement with in-reactor experience in predicting the trend of cladding lives.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Titanium aluminide intermetallic alloys with improved wear resistance

The invention is directed to a method for producing a titanium aluminide intermetallic alloy composition having an improved wear resistance, the method comprising heating a titanium aluminide intermetallic alloy material in an oxygen-containing environment at a temperature and for a time sufficient to produce a top oxide layer and underlying oxygen-diffused layer, followed by removal of the top oxide layer such that the oxygen-diffused layer is exposed. The invention is also directed to the resulting oxygen-diffused titanium aluminide intermetallic alloy, as well as mechanical components or devices containing the improved alloy composition.

36 MATERIALS SCIENCE↗

Investigation of Surface Treatments to Improve the Friction and Wear of Titanium Alloys for Diesel Engine Components

This final report summarizes experimental and analytical work performed under an agreement between the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Office of Transportation Technologies, and UT-Battelle LLC. The project was directed by Jerry Gibbs, of the U.S. Department of Energy’s Propulsion Materials Program, with management by D. P. Stinton and J. A. Haynes of ORNL. Participants included Peter J. Blau (Principal Investigator), Kevin M. Cooley (senior technician), Melanie J. Kirkham (materials scientist) of the Materials Science and Technology Division or ORNL, and Dinesh G. Bansal, a post doctoral fellow employed by Oak Ridge Associated Universities (ORAU) and who, at the time of this writing, is an engineer with Cummins, Inc. This report covers a three-year effort that involved two stages. In the first stage, and after a review of the literature and discussions with surface treatment experts, a series of candidate alloys and surface treatments for titanium alloy (Ti-6Al-4V) was selected for initial screening. After pre-screening using an ASTM standard test method, the more promising surface treatments were tested in Phase 2 using a variable loading apparatus that was designed and built to simulate the changing load patterns in a typical connecting rod bearing. Information on load profiles from the literature was supplemented with the help of T.C. Chen and Howard Savage of Cummins, Inc. Considering the dynamic and evolving nature of materials technology, this report presents a snapshot of commercial and experimental bearing surface technologies for titanium alloys that were available during the period of this work. Undoubtedly, further improvements in surface engineering methods for titanium will evolve.

33 ADVANCED PROPULSION SYSTEMS↗

Tribology: Friction, lubrication, and wear technology

The topics are presented in viewgraph form and include the following: introduction and definitions of terms; friction concepts; lubrication technology concepts; wear technology concepts; and tribological transitions. This document is designed for educators who seek to teach these concepts to their students.

Blau, Peter J.↗