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Bockelee-Morvan, D.

Publications and source records attributed to Bockelee-Morvan, D..

ALMA Mapping of Rapid Gas and Dust Variations in Comet C/2012 S1 (ISON): New Insights into the Origin of Cometary HNC

Observations of the sungrazing comet C/2012 S1 (ISON) were carried out using the Atacama Large Millimeter/submillimeter Array at a heliocentric distance of 0.58-0.54 AU (Astronomical Units) (pre-perihelion) on 2013 November 16-17. Temporally resolved measurements of the coma distributions of HNC, CH3OH, H2CO, and dust were obtained over the course of about an hour on each day. During the period UT 10:10-11:00 on November 16, the comet displayed a remarkable drop in activity, manifested as a greater than 42 percent decline in the molecular line and continuum fluxes. The H2CO observations are consistent with an abrupt, approximately 50 percent reduction in the cometary gas production rate soon after the start of our observations. On November 17, the total observed fluxes remained relatively constant during a similar period, but strong variations in the morphology of the HNC distribution were detected as a function of time, indicative of a clumpy, intermittent outflow for this species. Our observations suggest that at least part of the detected HNC originated from degradation of nitrogen-rich organic refractory material, released intermittently from confined regions of the nucleus. By contrast, the distributions of CH3OH and H2CO during the November 17 observations were relatively uniform, consistent with isotropic outflow and stable activity levels for these species. These results highlight a large degree of variability in the production of gas and dust from comet ISON during its pre-perihelion outburst, consistent with repeated disruption of the nucleus interspersed with periods of relative quiescence.

techniques: interferometric↗

Isotopic Ratios of H, C, N, O, and S in Comets C2012 F6 (lemmon) and C2014 Q2 (lovejoy) * ** ***

The apparition of bright comets C/2012 F6 (Lemmon) and C/2014 Q2 (Lovejoy) in March-April 2013 and January 2015, combined with the improved observational capabilities of submillimeter facilities, offered an opportunity to carry out sensitive compositional and isotopic studies of the volatiles in their coma. We observed comet Lovejoy with the IRAM 30 meter telescope between 13 and 26 January 2015, and with the Odin submillimeter space observatory on 29 January - 3 February 2015. We detected 22 molecules and several isotopologues. The H2 O-16 and H2 O-18 production rates measured with Odin follow a periodic pattern with a period of 0.94 days and an amplitude of approximately 25 percent. The inferred isotope ratios in comet Lovejoy are O-16/O-18 = 499 +/- 24 and D/H equals 1.4 +/- 0.4 x 10(exp -4) in water, S-32/S-34 = equals 24.7 +/- 3.5 in CS, all compatible with terrestrial values. The ratio C-12/C-13 equals 109 +/- 14 in HCN is marginally higher than terrestrial and 14 N/ 15/N equals 145 +/- 12 in HCN is half the Earth ratio. Several upper limits for D/H or C-12/ C-13 in other molecules are reported. From our observation of HDO in comet C/2014 Q2 (Lovejoy), we report the first D/H ratio in an Oort Cloud comet that is not larger than the terrestrial value. On the other hand, the observation of the same HDO line in the other Oort-cloud comet, C/2012 F6 (Lemmon), suggests a D/H value four times higher. Given the previous measurements of D/H in cometary water, this illustrates that a diversity in the D/H ratio and in the chemical composition, is present even within the same dynamical group of comets, suggesting that current dynamical groups contain comets formed at very different places or times in the early solar system.

Biver, N.↗

Submillimetric Spectroscopic Observations of Volatiles in Comet C-2004 Q2 (Machholz)

Submillimeter spectroscopic observations of comets provide an important tool for understanding their chemical composition and enable a taxonomic classification. Aims. We aim to determine the production rates of several parent- and product volatiles and the C-12/C-13 isotopic carbon ratio in the long-period comet C/2004 Q2 (Machholz), which is likely to originate from the Oort Cloud. Methods. The line emission from several molecules in the coma was measured with high signal-to-noise ratio in January 2005 at heliocentric distance of 1.2 AU by means of high-resolution spectroscopic observations using the Submillimeter Telescope (SMT) at the Arizona Radio Observatory (ARO). Results. We have obtained production rates of several volatiles (CH3OH, HCN, H(sup 13)CN, HNC, H2CO, CO, and CS) by comparing the observed and simulated line-integrated intensities. We calculated the synthetic profiles using a radiative transfer code that includes collisions between neutrals and electrons, and the effects of radiative pumping of the fundamental vibrational levels by solar infrared radiation. Furthermore, multiline observations of the CH3OH J = 7-6 series allow us to estimate the rotational temperature using the rotation diagram technique. We find that the CH3OH population distribution of the levels sampled by these lines can be described by a rotational temperature of 40 +/- 3 K. Derived mixing ratios relative to hydrogen cyanide are CO/CH3OH/H2CO/CS/HNC/HC-13N/HCN= 30.9/24.6/4.8/0.57/0.031/0.013/1 assuming a pointing offset of 8" due to the uncertain ephemeris at the time of the observations and the telescope pointing error. Conclusions. The measured relative molecular abundances in C/2004 Q2 (Machholz) are between low- to typical values of those obtained in Oort Cloud comets, suggesting that it has visited the inner solar system previously and undergone thermal processing. The HNC/HCN abundance ratio of approx 3.1% is comparable to that found in other comets, accounting for the dependence on the heliocentric distance, and could possibly be explained by ion-molecule chemical processes in the low-temperature atmosphere. From a tentative HC-13N detection, the measured value of 97 +/- 30 for the HC-12N/HC-13N isotopologue pair is consistent with a telluric value. The outgassing variability observed in the HCN production rates over a period of two hours is consistent with the rotation of the nucleus derived using different observational techniques.

chemical composition↗

New Molecular Species In Comet C/1995 (Hale-Bopp) Observed with the Caltech Submillimeter Observatory

We present millimeter-wave observations of HNCO, HC3N, SO, NH2CHO, H(13)CN, and H3O(+) in comet C/1995 O1 (Hale-Bopp) obtained in February-April, 1997 with the Caltech Submillimeter Observatory (CSO). HNCO, first detected at the CSO in comet C/1996 B2 (Hyakutake), is securely confirmed in comet Hale-Bopp via observations of three rotational transitions. The derived abundance with respect to H2O is (4-13) x 10(exp -4). HC3N, SO, and NH2CHO are detected for the first time in a comet. The fractional abundance of HC3N based on observations of three rotational lines is (1.9 +/- 0.2) x 10(exp -4). Four transitions of SO are detected and the derived fractional abundance, (2-8) x 10(exp -3), is higher than the upper limits derived from UV observations of previous comets. Observations of NH2CHO imply a fractional abundance of (1-8) x 10(exp -4). H3O(+) is detected for the first time from the ground. The H(13)CN (3-2) transition is also detected and the derived HCN/H(13)CN abundance ratio is 90 +/- 15, consistent with the terrestrial C-13/C-12 ratio. in addition, a number of other molecular species are detected, including HNC, OCS, HCO(+), CO(+), and CN (the last two are first detections in a comet at radio wavelengths).

Lis, D. C.↗

A determination of the HDO/H2O ratio in comet C/1995 O1 (Hale-Bopp)

Deuterated water (HDO) was detected in comet C/1995 O1 (Hale-Bopp) with the use of the James Clerk Maxwell Telescope on Mauna Kea, Hawaii. The inferred D/H ratio in Hale-Bopp's water is (3.3 +/- 0.8) x 10(-4). This result is consistent with in situ measurements of comet P/Halley and the value found in C/1996 B2 (Hyakutake). This D/H ratio, higher than that in terrestrial water and more than 10 times the value for protosolar H2, implies that comets cannot be the only source for the oceans on Earth.

NASA Discipline Exobiology↗

Deuterated Water in Comet C/1996 B2 (Hyakutake) and its Implications for the Origin of Comets

The close approach to the Earth of comet C/1996 B2 (Hyakutake) in March 1996 allowed searches for minor volatile species outgassing from the nucleus. We report the detection of deuterated water (HDO) through its 1(sub 01)-0(sub 00) rotational transition at 464.925 GHz using the Caltech Submillimeter Observatory. We also present negative results of a sensitive research for the J(5-4) line of deuterated hydrogen cyanide (DCN) at 362.046 GHz. Simultaneous observations of two rotational lines of methanol together with HDO in the same spectrum allow us to determine the average gas temperature within the telescope beam to be 69 +/- 10 K. We are thus able to constrain the excitation conditions in the inner coma and determine reliably the HDO production rate as (1.20 +/- 0.28) x 10(exp 26)/s on March 23-24, 1996. Available IR, UV and radio measurements lead to a water production rate of (2.1 +/- 0.5) x 10(exp 29)/s at the time of our HDO observations. The resulting D/H ratio in cometary water is thus (29 +/- 10) x 10(exp -5) in good agreement with the values of (30.8(sub - 5.3, sup +3.8) (Balsiger et al. 1995) and (31.6 +/- 3.4) x 10(exp -5) (Eberhardt et al. 1995) determined in comet P/Halley from in situ ion mass spectra. The inferred 3 a upper limit for the D/H ratio in HCN is 1%. Deuterium abundance is a key parameter for studying the origin and the early evolution of the Solar System and of its individual bodies. Our HDO measurement confirms that, in cometary water, deuterium is enriched by a factor of at least 10 relative to the protosolar ratio, namely the D/H ratio in H2 in the primitive Solar Nebula which formed from the collapse of the protosolar cloud. This indicates that cometary water has preserved a major part of the high D/H ratio acquired in this protosolar cloud through ion-molecule isotopic exchanges or grain-surface reactions and was not re-equilibrated with H2 in the Solar Nebula. Scenarios of formation of comets consistent with these results are discussed.

Bockelee-Morvan, D.↗

The infrared spectrum of comet Hale-Bopp

The infrared spectroscopic observations of the comet C/1995 O1 (Hale-Bopp), in April and September-October 1996, are summarized. High resolution spectra were obtained with the long and short wavelength spectrometers of the Infrared Space Observatory (ISO). The results showed that the dust in this comet contains crystalline silicates. The dust of Hale-Bopp is rather similar to that observed in the circumstellar disks of Vega-type stars.

Crovisier, J.↗

Detection of acetylene in the infrared spectrum of comet Hyakutake

Comets are rich in volatile materials, of which roughly 80% (by number) are water molecules. Considerable progress is being made in identifying the other volatile species, the abundances of which should enable us to determine whether comets formed primarily from ice-covered interstellar grains, or from material that was chemically processed in the early solar nebula. Here we report the detection of acetylene (C2H2) in the infrared spectrum of comet C/1996 B2 (Hyakutake). The estimated abundance is 0.3-0.9%, relative to water, which is comparable to the predicted solid-phase abundance in cold interstellar clouds. This suggests that the volatiles in comet Hyakotake may have come from ice-covered interstellar grains, rather than material processed in the accretion disk out of which the Solar System formed.

Acetylene/analysis↗

Spectroscopic evidence for interstellar ices in comet Hyakutake

Volatile compounds in comets are the most pristine materials surviving from the time of formation of the Solar System, and thus potentially provide information about conditions that prevailed in the primitive solar nebula. Moreover, comets may have supplied a substantial fraction of the volatiles on the terrestrial planets, perhaps including organic compounds that played a role in the origin of life on Earth. Here we report the detection of hydrogen isocyanide (HNC) in comet Hyakutake. The abundance of HNC relative to hydrogen cyanide (HCN) is very similar to that observed in quiescent interstellar molecular clouds, and quite different from the equilibrium ratio expected in the outermost solar nebula, where comets are thought to form. Such a departure from equilibrium has long been considered a hallmark of gas-phase chemical processing in the interstellar medium, suggesting that interstellar gases have been incorporated into the comet's nucleus, perhaps as ices frozen onto interstellar grains. If this interpretation is correct, our results should provide constraints on the temperature of the solar nebula, and the subsequent chemical processes that occurred in the region where comets formed.

Non-NASA Center↗

(abstract) Microwave Instrument for Rosetta Orbiter (MIRO)

MIRO is a scientific instrument designed for the orbiter of the Rosetta International Mission. It will address the nature of the cometary nucleus, outgassing, and the development of the coma as strongly interrelated aspects of cometary physics. Detailed parameters of the MIRO instrument and the scientific objectives to be met will be discussed. Simulated observations with the MIRO instrument will be shown.

comet microwaves MIRO Microwave Instrument for Ros↗

Spectroscopic Evidence for Interstellar Ice in Comet Hyakutake

Volatile compounds in comets are the most pristine materials surviving from the time of formation of the Solar System, and thus potentially provide information about conditions that prevailed in the primitive solar material. Moreover, comets may have supplied a substantial fraction of the volatiles on the terrestrial planets, perhaps including organic compounds that played a role in the origin of life on Earth. Here we report the detection of hydrogen isocyanide (HNC) in comet Hyakutake. The abundance of HNC relative to hydrogen cyanide (HCN) is very similar to that observed in quiescent interstellar molecular clouds, and quite different from the equilibrium ratio expected in the outermost solar nebula, where comets are thought to form. Such a departure from equilibrium has long been considered a hallmark of gas-phase chemical processing in the interstellar medium, suggesting that interstellar gases have been incorporated into the comet's nucleus, perhaps as ices frozen onto interstellar grains. If this interpretation is correct, our results should provide constraints on the temperature of the solar nebula, and the subsequent chemical processes that occurred in the region where comets formed.

Irvine, W. M.↗

Observations of cometary parent molecules with the IRAM radio telescope

Several rotational transitions of HCN, H2S, H2CO, and CH3OH were detected in comets P/Brorsen-Metcalf 1989 X, Austin (1989c1) and Levy (1990c) with the Institute for Millimeter Radioastronomy (IRAM) 30-m radio telescope. This allows us to determine the production rates of these molecules and to probe the physical conditions of the coma.

Colom, P.↗

OH radio observations of comets P/Brorsen-Metcalf (1989o), Okazaki-Levy-Rudenko (1989r), Aarseth-Brewington (1989a1), and Austin (1989c1) at the Nancay radio telescope

The 1667 MHz and 1665 MHz transitions of the OH radical were recently monitored in several comets with the Nancay radio telescope: P/Brorsen-Metcalf (1989o) (August 4 to October 31, 1989), Okazaki-Levy-Rudenko (1989r) (October 3 to December 2, 1989), Aarseth-Brewington (1989a1) (December 8 to 30, 1989), and Austin (1989c1) (February 15 to June 14, 1990). Present gas expansion measurements obtained from the analysis of the line shapes are presented and the long term variations of the water production rate, as measured from the OH radio lines. On October 13, 1989, the occultation of a background source by comet Okazaki-Levy-Rudenko (1989r) was fortuitously observed. A preliminary report of this observation is given. Further analysis of the data is continuing.

Bockelee-Morvan, D.↗

Millimetre observations of comets P/Brorsen-Metcalf (1989o) and Austin (1989c1) with the IRAM 30-m radio telescope

Millimeter observations with the IRAM 30 m telescope were conducted in comet P/Brorsen-Metcalf (1989o) on September 1989 and Austin (1989c1) on April and May 1990. The HCN J(1-0) and J(3-2) lines were detected in both comets. The HCN production rate relative to water in P/Brorsen-Metcalf is comparable to that previously measured in comet P/Halley, while that inferred in comet Austin might be smaller by a factor of two. The H2CO(3 sub 12 - 2 sub 11) transition, marginally observed in comet P/Brorsen-Metcalf, was firmly detected in May 1990 in comet Austin. Observations performed at offset positions suggest that the source of H2CO might be distributed. The H2CO abundance is on the order of 0.5 percent that of water for both comets, assuming a scalelength of 10(exp 4) km at 1 AU from the Sun for the distributed source. During the May observing period of comet Austin, two new species were detected for the first time in a comet: hydrogen sulfide (H2S) through its 1(sub 10) - 1(sub 01) ortho line at 169 GHz, and methanol (CH3OH) through J(3-2) delta K = 0 transitions at 145 GHz. Preliminary estimates of their abundances are 1.5 x 10(exp -3) for H2S and 8 x 10(exp -3) for CH3OH.

Colom, P.↗

The 2.5-12 micrometers spectrum of comet Halley from the IKS-VEGA experiment

The infrared instrument IKS flown on board the VEGA space probes was designed for the detection of emission bands of parent molecules, and for a measurement of the size and temperature of the thermal emitting nuclear region. The instrument had three channels with cooled detectors: an "imaging channel" designed to modulate the signal of the nucleus and two spectroscopic channels operating at 2.5-5 and 6-12 micrometers, respectively, equipped with circular variable filters of resolving power approximately 50. This paper presents and discusses the results from the spectral channels. On VEGA 1, usable spectra were obtained at distances D from the comet nucleus ranging from 250,000 to 40,000 km corresponding to fields of view 4000 and 700 km in diameter, respectively. The important internal background signal caused by the instrument itself, which could not be cooled, had to be eliminated. Since no sky chopping was performed, we obtain difference spectra between the current spectrum and a reference spectrum with little or no cometary signal taken at the beginning of the observing sequence (D approximately 200,000 km). Final discrimination between cometary signal and instrumental background is achieved using their different time evolution, since the instrumental background is proportional to the slow temperature drift of the instrument, and the cometary signal due to parent molecules or dust grains is expected to vary in first order as D-1. The 2.5-5 micrometers IKS spectra definitely show strong narrow signals at 2.7 and 4.25 micrometers, attributed to the nu 3 vibrational bands of H2O and CO2, respectively, and a broader signal in the region 3.2-3.5 micrometers, which may be attributed to CH-bearing molecules. All these signals present the expected D-1 intensity variation. Weaker emission features at 3.6 and 4.7 micrometers could correspond to the nu 1 and nu 5 bands of H2CO and the (1 - 0) band of CO, respectively. Molecular production rates are derived from the observed emissions, assuming that they are due to resonance fluorescence excited by the Sun's infrared radiation. For the strong bands of H2O and CO2, the rovibrational lines are optically thick, and radiative transfer is taken into account. We derive production rates, at the moment of the VEGA 1 flyby, of approximately 10(30) sec-1 for H2O, approximately 2.7 x 10(28) sec-1 for CO2, approximately 5 x 10(28) sec-1 for CO, and 4 x 10(28) sec-1 for H2CO, if attributions to CO and H2CO are correct. The production rate of carbon atoms in CH-bearing molecules is approximately 9 x 10(29) sec-1 assuming fluorescence of molecules in the gas phase, but could be much less if the 3.2-3.5 micrometers emission is attributed to C-H stretch in polycyclic aromatic hydrocarbons or small organic grains. In addition, marginal features are present at 4.85 and 4.45 micrometers, tentatively attributed to OCS and molecules with the CN group, respectively. Broad absorption at 2.8-3.0 micrometers, as well as a narrow emission at 3.15 micrometers, which follow well the D-1 intensity variation, might be due to water ice. Emission at 2.8 micrometers is also possibly present, and might be due to OH created in vibrationally excited states after water photodissociation. The 6-12 micrometers spectrum does not show any molecular emission, nor emission in the 7.5-micrometers region. The spectrum is dominated by silicate emission showing a double structure with maxima at 9.0 and 11.2 micrometers, which suggests the presence of olivine.

NASA Discipline Number 52-10↗

Hydrogen cyanide in comets - Excitation conditions and radio observations of comet IRAS-Araki-Alcock 1983d

The HCN emission of the pure rotation and rotation/vibration lines in comet IRAS-Araki-Alcock 1983d is examined. The prevailing excitation mechanism for the emissions was the excitation of the nu-2, 2 nu-2, and nu-3 vibrational bands by the solar infrared field. For the description of inner coma, a dynamical excitation model is presented which includes collisions. It is predicted on the basis of the model that HCN molecules in rotation and rotation vibration lines of IRAS-Araki-Alcock 1983d would be detectable with a large-millimeter wave telescope, and that the strongest infrared lines would be observable from space observatories. Subsequent searches for the J = 1-0 HCN radio lines in comet 1983d with the Five College Radio Astronomy Observatory (FCRAO) proved unsuccessful. An extremely low upper limit was found for HCN production which suggests that HCN might not be the only parent of planetary cometary CN.

Bockelee-Morvan, D.↗

Radioastronomical observations of comets IRAS-Araki-Alcock (1983d) and Sugano-Saigusa-Fujikawa (1983e)

Continuum and spectral-line radio observations of the comets IRAS-Araki-Alcock and Sugano-Saigusa-Fujikawa obtained at a number of observatories during May and June, 1983, are compiled in tables and briefly characterized. The species NH3, H2O, CO, and HCN are considered in detail; visible-range observations of CN are compared; and the implications of the results and the experience gained in performing and coordinating the observations for the detection of important species in other comets, especially Halley's Comet, are explored.

Irvine, W. M.↗