Engineering topics

Bourret, E. D.

Publications and source records attributed to Bourret, E. D..

4 records

NASA NTRS1985

Dynamics of Bridgman-Stockbarger growth of non-dilute binary alloys

The coupling between heat and mass transfer in the Bridgman-Stockbarger growth of nondilute crystals induces growth rate transients that are longer than those caused by heat transfer alone. The dynamics of the diffusion-controlled growth for thermophysical properties representative of Pb(1-x)Sn(x)Te and Hg(1-x)Cd(x)Te are computed from a one-dimensional solidification model which includes melt-crystal phase behavior. Results show that the growth rate response to a step change in pull rate for both systems differs from the exponential decay observed for dilute alloys and that growth rates cannot be inferred from axial segregation data in nondilute systems due to the dependence of the segregation coefficient on composition.

Bourret, E. D.↗

NASA NTRS1983

Seeded crystal growth of pseudobinary systems with large liquidus-solidus separation

The design and execution of seeded melt growth involving concentrated alloys is strongly dependent on the crystal-melt interface temperature and its change during seeding and growth. Thermodynamic instabilities during the seeding process can be controlled by the choice of the seed and melt composition and by the axial temperature gradient of the growth apparatus. These basic factors controlling seeded melt growth of concentrated alloys are of major importance for planning space experiments.

Bourret, E. D.↗

NASA NTRS1982

Segregation effects during growth of pseudo-binary system with large liquidus-solidus separation

Results are reported for an experimental study of the seeded growth, of PbSnTe single crystals in a vertical Bridgman-Stockbarger (B-S) furnace. Profiles of axial and radial segregation of Sn are presented for crystal growth from melts with aspect ratios of 15 and 6.8; the profiles indicate intense convective mixing. A one-dimensional model of heat and mass transfer in an idealized B-S furnace with diffusion control is used to examine the importance of liquidus-solidus separation in determining growth-rate and composition transients in a pseudobinary system. It is shown that the coupling of heat and mass transfer in a pseudobinary system with a large liquidus-solidus separation causes the transient behavior in a nondilute system to differ markedly from such behavior in a dilute system and that PbSnTe crystals with a reasonable diameter can be grown under nearly convectionless conditions in a microgravity environment.

Bourret, E. D.↗

NASA NTRS1982

Segregation during directional melting and its implications on seeded crystal growth: A theoretical analysis

Directional melting of binary systems, as encountered during seeding in melt growth, is analyzed for concurrent compositional changes at the crystal-melt interface. It is shown that steady state conditions cannot normally be reached during seeding and that the growth interface temperature at the initial stages of seeded growth is a function of backmelt conditions. The theoretical treatment is numerically applied to Hg1-xCdXTe and Ga-doped Ge.

Bourret, E. D.↗