Hydrogen Adsorption and Isotope Mixing on Copper-Functionalized Activated Carbons
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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Engineering topics
Boyd, David A.
Publications and source records attributed to Boyd, David A..
Enhanced Bulk Transport in Copper Vanadate Photoanodes Identified by Combinatorial Alloying
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14 SOLAR ENERGY↗
The CHANDRA X-Ray Observatory: Thermal Design, Verification, and Early Orbit Experience
The CHANDRA X-ray Observatory (formerly AXAF), one of NASA's "Great Observatories" was launched aboard the Shuttle in July 1999. CHANDRA comprises a grazing-incidence X-ray telescope of unprecedented focal-length, collecting area and angular resolution -- better than two orders of magnitude improvement in imaging performance over any previous soft X-ray (0.1-10 keV) mission. Two focal-plane instruments, one with a 150 K passively-cooled detector, provide celestial X-ray images and spectra. Thermal control of CHANDRA includes active systems for the telescope mirror and environment and the optical bench, and largely passive systems for the focal plans instruments. Performance testing of these thermal control systems required 1-1/2 years at increasing levels of integration, culminating in thermal-balance testing of the fully-configured observatory during the summer of 1998. This paper outlines details of thermal design tradeoffs and methods for both the Observatory and the two focal-plane instruments, the thermal verification philosophy of the Chandra program (what to test and at what level), and summarizes the results of the instrument, optical system and observatory testing.
Boyd, David A.↗
The Submillimeter-Wave Astronomy Satellite: On-Orbit Thermal Performance and Design Retrospective
A large telescope aperture, stringent thermal stability and temperature range requirements, and a passively-cooled 1500K module presented major challenges in thermal design and hardware fabrication of this Small Explorer satellite. This paper reviews briefly the thermal design of the SWAS science instrument, and examines the first three months of on-orbit thermal history. Measured temperatures for both the science payload and the spacecraft module and solar arrays are compared with those predicted by the correlated analytical model. Similarities and differences are interpreted in terms of the major uncertainties remaining after thermal-balance testing, especially those of MLI performance and telescope aperture properties. Review of the thermal model adequacy and thermal design verification are included to suggest improvements in the thermal design process for future missions.
Boyd, David A.↗
The Submillimeter-Wave Astronomy Satellite: On-Orbit Thermal Performance and Design Retrospective
A large telescope aperture, stringent thermal stability and temperature range requirements, and a passively-cooled 150 K module presented major challenges in thermal design and hardware fabrication of this Small Explorer satellite. This paper reviews briefly the thermal design of the SWAS science instrument, and examines the first three months of on-orbit thermal history. Measured temperatures for both the science payload and the spacecraft module and solar arrays are compared with those predicted by the correlated analytical model. Similarities and differences are interpreted in terms of the major uncertainties remaining after thermal-balance testing, especially those of MLI performance and telescope aperture properties. Review of the thermal model adequacy and thermal design verification are included to suggest improvements in the thermal design process for future missions.
Boyd, David A.↗
Ion Bombardment Experiments Suggesting an Origin for Organic Particles in Pre-Cometary and Cometary Ices
Simple molecules frozen as mantles of interstellar and circumstellar grains and incorporated into comets are subjected to ion bombardment in the form of cosmic rays, stellar flares, stellar winds, and ions accelerated in stellar wind shocks. The total expected dosage for the variety of situations range from 10 eV/molecule for interplanetary dust subjected to solar flares to 10(exp 6) eV/molecule for material in the T Tauri environment. Utilizing a Van de Graaff accelerator and a target chamber having cryogenic and mass spectrometer capabilities, we have bombarded frozen gases in the temperature range of 10 K to 30 K with 175 keV protons. After irradiation, removal of the ice by sublimation at an elevated temperature in vacuum reveals a fluffy residue. These experiments suggest that processes resulting in the formation of organic particles found in the coma of Comet Halley, "CHON", may have included ion bombardment. Also, the moderate energy (100 keV to 500 keV) shock accelerated ion environment of bipolar outflow of stars in the planetary nebula stage such as the Red Rectangle, could produce complex molecular species which emit the observed unidentified infrared bands at 3.3 micro-m, 6.2 micro-m, 7.7 micro-m, 8.6 micro-m, and 11.3 micro-m.
Wdowiak, Thomas J.↗
PAH in the laboratory and interstellar space
The theory that polycyclic aromatic hydrocarbons (PAHs) are a constituent of the interstellar medium, and a source of the IR emission bands at 3.3, 6.2, 7.7, 8.6, and 11.3 microns is being studied using PAH containing acid insoluble residue of the Orgueil CI meteorite and coal tar. FTIR spectra of Orgueil PAH material that has undergone thermal treatment, and a solvent insoluble fraction of coal tar that has been exposed to hydrogen plasma are presented. The UV excided luminescence spectrum of a solvent soluble coal tar film is also shown. Comparison of the lab measurements with observations appears to support the interstellar PAH theory, and shows the process of dehydrogenation expected to take place in the interstellar medium.
Wdowiak, Thomas J.↗
Ion bombardment experiments suggesting an origin for organic particles in pre-cometary and cometary ices
During the Giotto and Vega encounters with Comet Halley both organic particles called CHON and energetic ions were detected. The acceleration of ions to hundreds of keV in the vicinity of the bow shock and near the nucleus may be a demonstration of a situation occurring in the early solar system (perhaps during the T Tauri stage) that led to the formation of organic particles only now released. Utilizing a Van de Graaff accelerator and a target chamber having cryogenic and mass spectrometer capabilities, frozen gases were bombarded at 10 K with 175 keV protons with the result that fluffy solid material remains after sublimation of the ice. Initial experiments were carried out with a gas mixture in parts of 170 carbon monoxide, 170 argon, 25 water, 20 nitrogen, and 15 methane formulated to reflect an interstellar composition in experiments involving the freezing out of the products of a plasma. The plasma experiments resulted in a varnish-like film residue that exhibited luminescence when excited with ultraviolet radiation, while the ion bombardment created particulate material that was not luminescent.
Wdowiak, Thomas J.↗