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Brauer, D. P.

Publications and source records attributed to Brauer, D. P..

10 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Concentration-time data in toxicity tests and resulting relationships

Periodic analyses for carbon monoxide and methane in the animal exposure chamber during pyrolysis of polyethylene at 800 C without forced air flow showed that the concentrations of these compounds increased with exposure time. These observations, and similar observations for polyurethane flexible foam, permitted the calculation of carbon monoxide toxicity in terms of a DP (Death Product Concentration) value, in addition to flammability in terms of HC (Hydro Carbon) value. Observed DP values exceeding the critical DP(CO) value of 47,200 ppm-min for carbon monoxide may indicate that lethal exposures were reached earlier but not immediately manifested because of the time delay involved in physiological processes. On the basis of this DP(CO) value, carbon monoxide could have been the sole toxicant in the case of polyethylene, polypropylene, polyoxymethylene, polystyrene, polycarbonate, ethylene propylene diene rubber, and wood.

Hilado, C. J.↗
NASA NTRS1979

Toxicity of pyrolysis gases from polyoxymethylene

A sample of polyoxymethylene was evaluated for toxicity of pyrolysis gases, using the toxicity screening test method developed at the University of San Francisco. Under several test conditions, this material gave shorter times to death than many other synthetic polymers. Carbon monoxide appeared to be the principal toxicant in the pyrolysis gases.

Hilado, C. J.↗
NASA NTRS1978

An apparatus and procedure for evaluating the toxic hazards of smoldering seating and bedding materials

An apparatus and procedure are described for evaluating the toxicity of the gases evolved from the smoldering combustion of seating and bedding materials. The method combines initiation of smoldering combustion in fabric/cushion combinations by a lighted cigarette and exposure of laboratory animals to the gases evolved. The ratio of the surface available for smoldering to the compartment volume in this apparatus is approximately five times the ratio expected in a California living room, and 100 times the ratio expected in a wide-body aircraft passenger cabin. Based on fabric/cushion combinations tested, the toxicity of gases from smoldering combustion does not appear to be a significant hazard in aircraft passenger cabins, but seems to be a basis for careful selection of materials for residential environments.

Hilado, C. J.↗
NASA NTRS1978

Effect of pyrolysis temperature and air flow on toxicity of gases from a polycarbonate polymer

A polycarbonate polymer was evaluated for toxicity of pyrolysis gases generated at various temperatures without forced air flow and with 1 L/min air flow, using the toxicity screening test method developed at the University of San Francisco. Time to various animal responses decreased with increasing pyrolysis temperature over the range from 500 C to 800 C. There appeared to be no significant toxic effects at 400 C and lower temperatures.

Hilado, C. J.↗
NASA NTRS1978

The effect of fire retardants on the fire response characteristics of cellulosic materials

The resistance to ignition of fire retardant-treated wood, cotton, and cellulose insulation was studied. The proprietary composition used to treat wood was found to increase resistance to ignition and to reduce smoke toxicity. Cotton treated with boric acid (added by padding on or by vapor phase process) was found to have increased resistance to ignition and decreased smoke toxicity. Boric acid increased the resistance of cellulose insulation to ignition but also slightly increased the smoke toxicity.

Hilado, C. J.↗