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Brown, L. L.

Publications and source records attributed to Brown, L. L..

A carbon dioxide/methane greenhouse atmosphere on early Mars

One explanation for the formation of fluvial surface features on early Mars is that the global average surface temperature was maintained at or above the freezing point of water by the greenhouse warming of a dense CO2 atmosphere; however, Kasting has shown that CO2 alone is insufficient because the formation of CO2 clouds reduces the magnitude of the greenhouse effect. It is possible that other gases, such as NH3 and CH4, were present in the early atmosphere of Mars and contributed to the greenhouse effect. Kasting et al. investigated the effect of NH3 in a CO2 atmosphere and calculated that an NH3 mixing ratio of approximately 5 x 10 (exp -4) by volume, combined with a CO2 partial pressure of 4-5 bar, could generate a global average surface temperature of 273 K near 3.8 b.y. ago when the fluvial features are believed to have formed. Atmospheric NH3 is photochemically converted to N2 by ultraviolet radiation at wavelengths shortward of 230 nm; maintenance of sufficient NH3 concentrations would therefore require a source of NH3 to balance the photolytic destruction. We have used a one-dimensional photochemical model to estimate the magnitude of the NH3 source required to maintain a given NH3 concentration in a dense CO2 atmosphere. We calculate that an NH3 mixing ratio of 10(exp -4) requires a flux of NH3 on the order of 10(exp 12) molecules /cm-s. This figure is several orders of magnitude greater than estimates of the NH3 flux on early Mars; thus it appears that NH3 with CO2 is not enough to keep early Mars warm.

Brown, L. L.↗

Photochemical model for NH3 in an early Martian atmosphere

A warm and wet climate scenario for early Mars has been explained by invoking a 5-bar CO2 atmosphere; however, Kasting has shown that CO2 will condense in the Martian atmosphere at these pressures. The formation of CO2 clouds will reduce the convection lapse rate and reduce the magnitude of the greenhouse effect. It is possible that additional greenhouse gases such as methane and ammonia were present in the early Mars atmosphere. We are using a one dimensional photochemical model to estimate the magnitude of the ammonia source required to maintain a given ammonia concentration in a dense CO2 atmosphere. Because CO2 is 2.5 times more efficient at Rayleigh scattering than Earth's N2 atmosphere, we anticipate increased scattering opacities and decreased photolytic destruction rates of ammonia on early Mars. The reduced gravity on Mars means that a 1 bar atmosphere will be approximately 3 times as thick as on Earth. It is possible that ammonia could have been shielded from photolysis by hydrocarbon aerosols which form as a product of methane photolysis.

Brown, L. L.↗

Was early Mars warmed by ammonia?

Runoff channels and valley networks present on ancient, heavily cratered Martian terrain suggests that the climate of Mars was originally warm and wet. One explanation for the formation of these channels is that the surface was warmed by the greenhouse effect of a dense, CO2 atmosphere. However, recent work shows that this theory is not consistent for the early period of the solar system. One way to increase the surface temperature predicted is to assume that other greenhouse gases were present in Mars' atmosphere in addition to CO2 and H2O. This possible gas is ammonia, NH3. If ammonia was present in sufficient quantities, it could have raised the surface temperature to 273 K. An adequate source would have been volcanic outgassing if the NH3 produced was shielded from photolysis by an ultraviolet light absorber.

Kasting, J. F.↗

Block rotations in the Rio Grande Rift, New Mexico

Paleomagnetic data from 13 sites of intrusive and extrusive rocks associated with the Oligocene Espinaso Formation around the Ortiz mountains, New Mexico, indicate mean magnetic directions of I = 42.1 deg and D = 337.8 deg, with a corresponding pole position of 67.9 deg N latitude and 142.3 deg E longitude. From comparison with the expected Oligocene direction, 17.8 + or - 11.3 deg of counterclockwise rotation is found, and the similar rotations for Oligocene and Pliocene age rocks suggests that motion has occurred in the past 5 m.y. Data support the previously suggested diamond-shaped crustal block extending from the San Luis basin southward to the Albuquerque basin bounded by well-defined recently active fault zones. The size of the block, the counterclockwise nature of rotation and the timing of motion are supported by geologic and structural data. The counterclockwise rotation of the block has resulted in uplift at the acute ends of the block and subsidence at the obtuse ends, and the driving mechanism may be left slip along the rift.

Brown, L. L.↗

Tectonic rotations within the Rio Grande rift - Evidence from paleomagnetic studies

Paleomagnetic studies on Miocene Pliocene volcanic rocks from the Espanola basin of the Rio Grande rift, New Mexico, reveal directions discordant form the expected mean direction for North America. The Paliza Canyon Formation, Tschicoma Formation, and Lobato Basalt, all sampled in the Jemez Mountains west of the Pajarito fault zone, have mean declinations east of the expected mean. The Cerros del Rio volcanics, lying east of the Pajarito fault zone, have a westerly declination. Combined with published data on the Santa Fe Group sediments east of the fault zone, and the Valles Rhyolite, west of the fault zone, distinct rotations of the two areas are evident. The western block has rotated clockwise 12 deg, while the eastern block shows 16 deg of conter-clockwise motion. Differential rotations of 25-30 deg are calculated between the two blocks; 4 deg/m.y. is the minimum differential rotation for the past 5 m.y. Geologic explanations for these rotations include the opening of the Rio Grande rift in response to clockwise rotation of the Colorado Plateau and significant left slip along the Rio Grande rift.

Brown, L. L.↗