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Burns, David M.

Publications and source records attributed to Burns, David M..

Chapter 13: A Simple Estimation of UV Irradiance Under Clear-Sky Conditions

Accelerated aging tests are designed to estimate the useful life of products in their end-use environment. There is currently no simple way to answer the age-old question: “How long should I run my weathering test to reproduce 1 year of outdoor aging?” At the very least, there is need to (1) evaluate the acceleration rate associated with each stress factor and (2) estimate the intensity of the stress factors that the products under scrutiny are exposed to in natural aging. In this chapter, a model is introduced to calculate the ratio between ultraviolet (UV) irradiance and global horizontal irradiance (GHI). This method was empirically derived from measured or simulated irradiance data and validated against outdoor observations. This ratio provides a simple way to estimate the UV dose that samples are exposed to at any outdoor location.

ENERGY PLANNING, POLICY, AND ECONOMY,OTHER INSTRUM↗

Degradation in photovoltaic encapsulation strength of attachment: Results of the first PVQAT TG5 artificial weathering study

Delamination of the encapsulant in photovoltaic (PV) module technology results in immediate optical loss and may enable subsequent corrosion or mechanical damage. The effects of artificial weathering were not previously known; therefore, an empirical study was performed to survey the factors most affecting adhesion, including the ultraviolet (UV) source (ie, Xe or fluorescent lamp[s]), the optical filters for the lamp, the chamber temperature, and the relative humidity. Natural weathering was also performed at locations, including the following: Golden, Colorado; Miami, Florida; Phoenix, Arizona; QiongHai, China; Riyadh, Saudi Arabia; and Turpan, China. Specimens were constructed using a laminated glass/poly (ethylene-co-vinyl acetate)/glass geometry. The compressive shear test (CST) was used to quantify the mechanical strength of attachment, taken as a proxy for adhesion. The fractography of select specimens (including cross-sectional optical microscopy) was used to verify the failure mode (delamination or decohesion). Additional analysis of the local solar spectrum as well as the specimen temperature was performed to interpret the results of natural weathering. The goals of this study include to identify the most significant stressors, clarify where strong coupling may occur between stressors, and validate accelerated test results relative to natural weathering. The importance of specimen conditioning (for moisture) and hygrometric degradation as well as the effects of UV degradation are identified in this paper.

14 SOLAR ENERGY↗

Helical Engine

A new concept for in-space propulsion is proposed in which propellant is not ejected from the engine, but instead is captured to create a nearly infinite specific impulse. The engine accelerates ions confined in a closed loop to relativistic speeds, and slightly varies their velocity to change their momentum. The engine then moves the ions back and forth along the direction of travel to produce thrust. This in-space engine is intended to be used for long-term satellite station-keeping without refueling or to propel spacecraft across interstellar distances. The engine has no moving parts other than ions traveling in a closed-loop vacuum line, trapped inside electric and magnetic fields.

Burns, David M.↗

Degradation in photovoltaic encapsulant transmittance: Results of the first PVQAT TG5 artificial weathering study

Reduced optical transmittance of encapsulants resulting from ultraviolet (UV) degradation is frequently identified as a cause of decreased performance through the service life of photovoltaic modules. However, the present module safety and qualification standards apply short UV doses, only capable of examining design robustness and 'infant mortality' failures. Furthermore, essential information remains unknown that might be used to screen encapsulants through product lifetime. We conducted an interlaboratory study to provide the understanding that will be used toward developing a higher-fidelity, more-rigorous UV weathering test. Five representative known formulations of poly (ethylene-co-vinyl acetate) were studied, in addition to one thermoplastic polyurethane material. Replicate laminated silica/polymer/silica specimens were examined at seven institutions using a variety of indoor chambers (including xenon, UVA-340, and metal-halide light sources). Specimens were artificially weathered for 180 cumulative days at steady-state accelerated test conditions, predesignated relative to the default irradiance of 1.0 W m-2 nm-1 at 340 nm, chamber temperature of 60 degrees C, and chamber relative humidity of 30%. The solar-weighted transmittance, yellowness index, and the UV cut-off wavelength - each determined from the measured hemispherical transmittance - are examined to provide understanding and guidance for the UV light source (type lamp and filters), temperature, and humidity used in accelerated UV aging tests. The relative efficacy of xenon-arc and UVA-340 fluorescent sources and the typical range of activation energy for degradation is quantified from the experiments.

14 SOLAR ENERGY↗

Estimating Ultraviolet Radiation From Global Horizontal Irradiance

Terrestrial ultraviolet radiation (UV) radiation is a primary factor contributing to the degradation of photovoltaic (PV) modules' efficiency and reliability over time. Therefore, accurate knowledge of terrestrial UV incident on the surface of the PV materials is essential to understand the degradation of PV modules and provide reliable assessment of their service life. As PV is deployed in various climate zones, it is crucial that terrestrial UV information is available at various locations. However, the availability of terrestrial UV data - measured or modeled - is extremely limited. On the other hand, total solar irradiance (TS) datasets are relatively abundant. In this study, the National Renewable Energy Laboratory, its industry partners, and ASTM's International Subcommittee on Radiometry and Service Life Prediction are developing a simple method to estimate the clear-sky terrestrial UV irradiance (280-400 nm, 295-400 nm, 285-385 nm, or 295-385 nm) from total irradiance data (280-4000 nm). The goal is to provide reliable estimates of the UV received by samples as a function of location, orientation, tilt, and airmass, thus encompassing a variety of conditions. Here, the Simple Model of the Atmospheric Radiative Transfer of Sunshine (SMARTS) model is used to estimate the UV:TS ratio under various scenarios, and examines the influences of atmospheric constituents, such as aerosols, precipitable water vapor or ozone, and of the local surface characteristics (albedo), on the predicted UV.

14 SOLAR ENERGY↗