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Burns, Jonathan

Publications and source records attributed to Burns, Jonathan.

Effects of annealing on fission fragment release from electrodeposited Cf-252 thin-films

In this work, samarium thin-films doped with a 252 Cf radiotracer were used to study the effects of annealing on the release of fission fragments from electrodeposited films. An ammonium acetate molecular plating technique was utilized to perform the depositions. The fission fragment yields were measured using a unique technique involving the exposure of aluminum foils to the deposited material for a fixed time followed by gamma-ray spectroscopy to determine the rate at which the fission fragments implanted into the foils. Annealing of the electrodeposited films was found to have no effect on the release of fission fragments.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Algorithm for Establishing Safeguards Termination Concentration Limits

This paper presents an algorithm for estimating the maximum concentration limits for terminating safeguards on nuclear materials. These limits are important because such material is no longer subject to accounting, reporting or inspections after the International Atomic Energy Agency (IAEA) has approved the termination of safeguards on nuclear material declared by a State to be waste.Maximum concentration limits for different waste forms generated within nuclear fuel cycle facilities must be sufficiently conservative such that termination of safeguards does not become a weak link in the safeguards system. The concentration limits must also remain practical in order to ensure IAEA resources are used effectively and efficiently to implement safeguards in the State. These termination limits should be technically-based while remaining objective and reasonable to implement by the State. In support of the original IAEA guidance on concentration limits for termination of safeguards prepared in the early 1990s, the U.S. developed an algorithm to estimate concentrations that would make recovery of nuclear material from waste on which safeguards had been terminated at least as unattractive as undeclared production from uranium ore or diversion of similar nuclear material. In 2016, the IAEA sought technical advice from a meeting of experts from selected member States to support updating its internal guidance on termination of safeguards. Their recommendations included extending the guidance to consider additional waste forms. The experts in the 2016 meeting recommended that the IAEA limits should more clearly reflect the technical difficulty and level of effort required to recover nuclear material from the various waste forms. This paper identifies and assesses the most likely techniques a State might use to recover nuclear material from the waste forms identified by the experts and determines how the safeguards termination algorithm could be revised to more accurately reflect the difficulty of recovering one significant quantity of nuclear material from these waste forms.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Samarium electrodeposited acetate and oxide thin films on stainless steel substrate characterized by XPS

Characterization of a samarium thin film deposited on a stainless steel substrate using molecular electrodeposition was carried out using a Thermo Scientific K-Alpha X-ray photoelectron spectrometer. We studied two types of samarium electrodeposition samples, one as-deposited and one heated to 700 °C in an air flow. Survey scans include peaks coming from the stainless steel substrate, such as Fe and Cr. An X-ray photoelectron spectroscopy (XPS) survey spectrum, Sm 3d, C 1s, and O 1s narrow scans are shown. It was determined that the heating process decomposed the deposited Sm acetate to Sm 2 O 3 using XPS.

36 MATERIALS SCIENCE↗