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Cariolle, Daniel

Publications and source records attributed to Cariolle, Daniel.

Three-dimensional modelling of trace species in the Arctic lower stratosphere

A three-dimensional radiative-dynamical-chemical model has been developed and used to study some aspects of modeling the polar lower stratosphere. The model includes a comprehensive gas-phase chemistry scheme as well as a treatment of heterogeneous reactions occurring on the surface of polar stratospheric clouds. Tracer transport is treated by an accurate, nondispersive scheme with little diffusion suited to the representation of strong gradients. Results from a model simulation of early February 1990 are presented and used to illustrate the importance of the model transport scheme. The model simulation is also used to examine the potential for Arctic ozone destruction and the relative contributions of the chemical cycles responsible.

Chipperfield, Martyn↗

Odd nitrogen during the MAP/GLOBUS 1983 campaign - Theoretical considerations

The paper reviews the chemical processes involved in the formation and destruction of active nitrogen in the stratosphere and indicates that transport processes play an important role in the behavior of these species. Vertical profiles measured during the MAP/GLOBUS 1983 campaign are compared to distributions calculated by a number of one-dimensional models. An intercomparison between six of these models shows that, if some quantitative differences attributed to different model input are noticeable, the same type of behavior is predicted for NO and NO2 by all models. Although the observed concentration of species belonging to the odd nitrogen family should be highly variable, as a result of dynamical disturbances, most data obtained during the campaign appear to be consistent with the chemical scheme currently used in photochemical models.

Brasseur, Guy↗