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Carter, J. L.

Publications and source records attributed to Carter, J. L..

Lunar regolith fines - A source of hydrogen

The theoretical evaluation of the lunar regolith fines as a primary source of hydrogen reveals that a minimum order of magnitude increase in hydrogen content is possible in beneficiated fines because both particle size and particle shape play a significant role in the relationship of volume percent of surface coating to grain size. The lunar regolith fines meet the basic requirement for beneficiation because a major portion (minimum two-thirds) of the hydrogen occurs in the less than 20-micron-size fraction, a relatively small part of the fines. Beneficiation should be accomplished by a combination of vibratory screening followed by cyclone and/or possibly electrostatic separation. Early exploitation of the lunar regolith fines for hydrogen probably will be limited to hydrogen obtained as a by-product or co-product from the mining and processing for other elements or materials because a minimum of about 13,600 tons to about 19,600 tons of 100 ppm hydrogen-bearing lunar regolith fines will have to be processed with about 3,100 tons to about 4,500 tons, respectively, of concentrate heated to supply 1 ton of hydrogen, yielding a recovery of about 74 percent to about 51 percent respectively, of the hydrogen.

Carter, J. L.↗

Surface morphology and chemistry of rusty particle 60002,108

Scanning electron microscope, energy dispersive X-ray, and microprobe analyses of the surface of rusty colored particle 60002,108 from deep core 60002 reveal the particle to be basically metallic Ni-Fe that probably grew in contact with silicate minerals, principally plagioclase and pyroxene, and was later partially oxidized and hydrated. A yellowish wrinkled and 'shatter cone' like granular material that is either iron oxide or oxyhydrate may have formed while the particle was in the lunar environment. Ruby-red mounds of lawrencite formed, and the reaction of lawrencite, metallic Ni-Fe, and water vapor resulted in aprons of iron oxyhydrate that surrounds these mounds and flows out over the preexisting yellowish granular substrate. The observations do not allow one to distinguish unequivocally between the initiation of hydration of the ruby-red lawrencite mounds in the lunar environment followed by reaction in the terrestrial and/or spacecraft environment or only reaction in the terrestrial and/or spacecraft environment. The relationship of the lawrencite-rich mounds to the yellowish granular substrate favors the first possibility.

Carter, J. L.↗

Morphology and composition of chalcopyrite, chromite, Cu, Ni-Fe, pentlandite, and troilite in vugs of 76015 and 76215

Vugs from 76015 and 76215 are lined with euhedral crystals of plagioclase, pyroxene, ilmenite, Ni-Fe, and troilite. Smaller crystals of chromite, pentlandite, and chalcopyrite occur on the surface of the troilite in 76015. Wire Cu and dendritic-metallic Cu occurs with metallic Ni-Fe and troilite in some vugs of 76215. Troilite in both samples may have crystallized from an immiscible sulfide liquid. With falling temperature, chalcopyrite, and pentlandite may have exsolved from the troilite in 76015. By contrast, metallic Cu may have formed in 76215 by thermal breakdown of a bornite, troilite, and Ni-Fe assemblage which originally crystallized from a low-Ni immiscible sulfide liquid.

Carter, J. L.↗

VLS /vapor-liquid-solid/ - Newly discovered growth mechanism on the lunar surface.

A probable vapor-liquid-solid (VLS) type of growth has been discovered for the first time in nature on the surface of lunar rock 15015. Scanning electron microprobe and energy dispersive x-ray data indicate that the growth occurs as metallic iron stalks from about 0.015 to 0.15 micrometer in diameter, with bulbous tips consisting of a mixture of iron and sulfur and measuring from about 0.03 to 0.2 micrometer in diameter. The stalk length is two to ten times the bulb diameter.

Carter, J. L.↗

Studies related to the evolution of the lunar soil materials

Studies of the chemistry and morphology of the lunar samples are reported. The presence of fragments of plagoclase in the centers of the impact craters indicate that the glass spheres were derived by meteoritic impact from high velocity particles, while the glass was at high temperatures. From the study of the Apollo 16 samples, it is suggested that this material was formed in a hot impact ejecta blanket, or in an igneous environment, and later exposed to meteoritic impact. It is suggested that particles from Apollo 17 were formed in a cloud of siliceous vapors.

Carter, J. L.↗

Chemistry and surface morphology of soil particles from Luna 20 LRL sample 22003.

Optical and scanning electron microscopy, scanning electron microprobes and energy dispersion techniques were applied in an analysis of six siliceous glass spheres, five siliceous glass-bonded agglutinates and one breccia fragment from Luna 20 sample 22003. It is theorized that local meteor impact processes might have been responsible for the formation of most of the glass spheres and that the impacts of relatively high velocity particles might have been responsible for the craters observed on the surfaces of the spheres. The concentrations of iron spherules on the surfaces of the glass spheres were generally lower than in similar Apollo 11 and 12 glass spheres.

Carter, J. L.↗

Scanning electron microscopy, non-dispersive X-ray analysis and electron microprobe studies of lunar soil, rocks and microbreccia

Silicate glass of composition similar to brown lunar glass was reduced with carbon and hydrogen. The typical complex iron sulfide and metallic iron mound formed by reduction with carbon is zoned. Its interior is metallic iron or a mixture of iron sulfide and metallic iron. The outer layer is pure metallic iron which is generally discontinuous, but the surface of the mound next to the silicate host is iron sulfide. This type of mound commonly has a waist of metallic iron and a void beneath it. The silicate surface of the void is covered with droplets or stringers of iron sulfide. The complex iron sulfide and metallic iron mounds formed by reduction with hydrogen generally are zoned. The outer layer is iron sulfide or a mixture of iron sulfide and metallic iron but the interior is metallic iron and iron sulfide, and the mound material next to the silicate host is iron sulfide. On the surface of some complex mounds, globules of silicate material are present. In one example, the globules consist of particles of aluminum oxide surrounded by silicate material. In turn, the margin of the globules is surrounded by iron sulfide. Dimples are present and surface of the dimples is covered by dendritic sheaths of iron sulfide and isolated metallic iron globules.

Carter, J. L.↗