Engineering topics

Cash, Michele

Publications and source records attributed to Cash, Michele.

2 records

NASA NTRS2002

Hydrogen in rocks: an energy source for deep microbial communities

To survive in deep subsurface environments, lithotrophic microbial communities require a sustainable energy source such as hydrogen. Though H2 can be produced when water reacts with fresh mineral surfaces and oxidizes ferrous iron, this reaction is unreliable since it depends upon the exposure of fresh rock surfaces via the episodic opening of cracks and fissures. A more reliable and potentially more voluminous H2 source exists in nominally anhydrous minerals of igneous and metamorphic rocks. Our experimental results indicate that H2 molecules can be derived from small amounts of H2O dissolved in minerals in the form of hydroxyl, OH- or O3Si-OH, whenever such minerals crystallized in an H2O-laden environment. Two types of experiments were conducted. Single crystal fracture experiments indicated that hydroxyl pairs undergo an in situ redox conversion to H2 molecules plus peroxy links, O3Si/OO\SiO3. While the peroxy links become part of the mineral structure, the H2 molecules diffused out of the freshly fractured mineral surfaces. If such a mechanism occurred in natural settings, the entire rock column would become a volume source of H2. Crushing experiments to facilitate the outdiffusion of H2 were conducted with common crustal igneous rocks such as granite, andesite, and labradorite. At least 70 nmol of H2/g diffused out of coarsely crushed andesite, equivalent at standard pressure and temperature to 5,000 cm3 of H2/m3 of rock. In the water-saturated, biologically relevant upper portion of the rock column, the diffusion of H2 out of the minerals will be buffered by H2 saturation of the intergranular water film.

Hydrogen/analysis↗

NASA NTRS2000

Delivery of Volatiles to Habitable Planets in Extrasolar Planetary Systems

The Earth can support life because: (1) its orbit lies in the Sun's habitable zone', and (2) it contains enough volatile material (e.g. water and organics) for life to flourish. However, it seems likely that the Earth was drier when it formed because it accreted in a part of the Sun's protoplanetary nebula that was too hot for volatiles to condense. If this is correct, water and organics must have been delivered to the habitable zone, after dissipation of the solar nebula, from a 'wet zone' in the asteroid belt or the outer solar system, where the nebula was cool enough for volatiles to condense. Material from the wet zone would have been delivered to the Earth by Jupiter and Saturn. Gravitational perturbations from these giant planets made much of the wet zone unstable, scattering volatile-rich planetesimals and protoplanets across the Solar System. Some of these objects ultimately collided with the inner Planets which themselves lie in a stable part of the Solar System. Giant planets are now being discovered orbiting other sunlike stars. To date, these planets have orbits and masses very different from Jupiter and Saturn, such that few if any of these systems is likely to have terrestrial planets in the star's habitable zone. However, new discoveries are anticipated due to improved detector sensitivity and the increase in the timespan of observations. Here we present numerical experiments examining the range of giant-planet characteristics that: (1) allow stable terrestrial Planets to exist in a star's habitable zone, and (2) make a large part of the star's wet zone weakly unstable, thus delivering volatiles to the terrestrial planets over an extended period of time after the dissipation of the solar nebula.

Chambers, John E.↗