Photochemical hydrogen evolution from cobalt microperoxidase-11
Not provided.
Biochemistry & Molecular Biology↗
Engineering topics
Chakraborty, Saikat
Publications and source records attributed to Chakraborty, Saikat.
Light-driven hydrogen production with CdSe quantum dots and a cobalt glutathione catalyst
A photocatalytic hydrogen (H 2 ) production system is reported using glutathione (GSH)-capped CdSe QDs with a cobalt precatalyst, yielding 130 000 mol H 2 per mol cobalt over 48 hours. Analysis of the reaction mixtures after catalysis indicates that the active catalyst is a labile complex of cobalt and GSH formed in situ.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Enhancing the activity of photocatalytic hydrogen evolution from CdSe quantum dots with a polyoxovanadate cluster
Here, we report the improvement of photocatalytic proton reduction using molecular polyoxovanadate-alkoxide clusters as hole scavengers for CdSe quantum dots. The increased hydrogen production is explained by favorable charge interactions between reduced forms of the cluster and the charge on the quantum dots arising from the capping ligands.
08 HYDROGEN↗