Engineering topics

Chameides, William L.

Publications and source records attributed to Chameides, William L..

8 records

NASA NTRS2002

China as an Evolving Metro-Agro-Plex (China-MAP)

The one-year NASA-funded project was implemented to complete the analyses and model-simulations undertaken under the auspices of the 3-year research effort supported by NASA as an Interdisciplinary Earth System Science Investigation (IDS) entitled: China As An Evolving Metro-Agro-Plex (China-MAP). The primary goal of China-MAP was to assess the effects of economic development and the regional environmental changes it engenders upon agriculture in China. The project was carried out as part of the Sino-U.S. Science and Technology Protocol in the Atmospheric Sciences, an official government-to-government agreement that establishes the parameters for joint research projects between the two nations in the atmospheric sciences. The NASA-funded portion of the project focused on the development and application of a regional coupled climate/chemical transport model for East Asia (i.e., RegChem-CM). The funds provided under the subject 1-year project were used to: (1) complete specific investigations undertaken by the China-MAP Science Team using the Reg-Chem-CM expended; and (2) document the results of these and other China-MAP investigations in the peer-reviewed literature. A summary of these specific investigations in provided.

Chameides, William L.↗

NASA NTRS1990

Model simulations of rainout and washout from a warm stratiform cloud

A one-dimensional, time-dependent cloud model with parameterized microphysics is used to investigate the processes which control the rainout and washout of soluble gases from warm, precipitating stratiform clouds. Calculations are presented simulating the distributions of soluble species within and below the cloud layer and in the precipitating raindrops as a function of time and species' solubility. Calculations indicate that for species with low solubility, wet removal processes are relatively slow and thus do not significantly affect the species' gas-phase abundance. As a result, the removal of low-solubility species by rainout and washout is controlled by thermodynamic processes with the concentration of the species in cloud and rainwater largely determined by the species' solubility. For highly soluble species on the other hand, dissolution into cloud droplets and removal in rain is quite rapid and the abundance of highly soluble species within and below the cloud falls rapidly as soon as the precipitation begins.

Xing, Lin↗

NASA NTRS1990

Model simulations of rainout and washout from a warm stratiform cloud

Calculations utilizing a one-dimensional, time-dependent stratiform cloud model with parameterized microphysics to study the washout and rainout of soluble trace gases are presented. It is shown that the in-cloud concentrations of relatively insoluble species remain essentially unaffected by the presence of cloudwater and rainwater, while the concentrations of highly soluble species are rapidly depleted within the cloud. Due to this depletion it is shown that for highly soluble species the below-cloud scavenging via washout can dominate over in-cloud scavenging via rainout; in-cloud, aqueous-phase cloudwater and rainwater concentrations can differ considerably and, near the cloudbase, cloudwater concentrations can exceed rainwater concentrations by factors of two to ten.

Xing, Lin↗

NASA NTRS1989

Trace gases in the atmosphere of Mars - An indicator of microbial life

The detection of certain trace gases in the atmosphere of Mars would indicate the presence of microbial life on the surface. Candidate biogenic gases include CH4, NH3, N2O, and several reduced sulfur species. Chemical thermodynamic equilibrium and photochemical calculations preclude the presence of these gases in any measurable concentrations in the atmosphere of Mars in the absence of biogenic production. A search for these gases utilizing either high-resolution (spectral and spatial) spectroscopy from a Mars orbiter, such as the Mars Observer orbiter, and/or in situ measurements from a Mars lander or rover is proposed.

Levine, Joel S.↗

NASA NTRS1988

High-ozone events in Atlanta, Georgia, in 1983 and 1984

Measurements of ozone levels and meterological parameters were analyzed to determine the relative importance of transport-related processes and photochemical production in causing high-ozone events in and around the Atlanta metropolitan area. Back-trajectories calculated by the Branching Air Trajectory Model indicate that the air associated with high-ozone events had often traveled a significant distance within the previous 3 days: for days with ozone levels above 100 ppbv, half of the calculated trajectories showed that the air had traveled over 600 km, with half of those coming from the northwest quadrant. Six-hour vector-averaged winds were used to find that the concentrations of ozone in the air leaving the metropolitan area averaged 20-40 ppbv more than that entering the area.

Lindsay, Ronald W.↗

NASA NTRS1988

Diagnostic studies of the HxOy-NzOy-O3 photochemical system using data from NASA GTE field expeditions

Spring 1084 GTE CITE-1 flight data from the field exercise was obtained from a GTE Data Archive Tape. Chemical and supporting meteorological data taken over the Pacific Ocean was statistically and diagnostically analyzed to identify the key processes affecting the concentrations of ozone and its chemical precursors in the region. The analysis was completed. The analysis of the GTE CITE-2 data is being performed in collaboration with Dr. D.D. Davis and other GTE scientists. Initial results of the analysis were presented and work begun on the paper describing the results.

Chameides, William L.↗

NASA NTRS1987

Acid dew and the role of chemistry in the dry deposition of reactive gases to wetted surfaces

A formalism is developed to describe the dry deposition of soluble reactive gases to wetted surfaces in terms of the relevant meteorological conditions, the surface roughness, the total amount of liquid water present on the surface, the rate of accumulation of this water, and the species' solubility and reactivity in the surface water. This formulation is then incorporated into a model designed to simulate the generation of acidic dew from the deposition of HNO3, SO2, S(IV) oxidants, H2O2, and O3. Similar to the observations of dew in the continental U.S., the model generates a dewdrop pH of about 4 by the end of the night; the pH can rapidly fall to toxic levels due to rapid evaporation after sunrise. Relatively low deposition velocities are predicted for the SO2 and O3 because of their lower solubilities and hence larger surface resistances than those of the other oxidants. Because the chemical lifetime of the SO2 in the dew is influenced by the atmospheric levels of H2O2, O3, and SO2, the SO2 deposition velocity is a strong function of these species' atmospheric abundances.

Chameides, William L.↗

NASA NTRS1986

Rainout lifetimes of highly soluble aerosols and gases as inferred from simulations with a general circulation model

The rainout-determined lifetimes of highly soluble particulate and gaseous atmospheric compounds are investigated using general circulation model simulations in which removal is explicitly calculated in terms of the local, model-produced precipitation rates. The calculations indicate that because of the episodic and asymmetric nature of rainout, species' lifetimes depend not only on the amount of precipitation but also on the characteristics of the precipitation regime (such as duration and frequency of the precipitation events) and on the direction of the tracer main flow (determined by the species' average mixing ratio gradient). For this reason, averaged rainout lifetimes of tracers flowing downstream from the stratosphere are found to differ substantially from those of tracers of surface origin flowing upward or tracers of a more ubiquitous tropospheric source. These results imply that the use of a first-order parameterization to simulate rainout in a photochemical model that does not explicitly calculate precipitation can be inadequate in representing this process. A computationally efficient parameterization that includes the effects of intermittence and asymmetry of rainout is proposed, and it is shown how this parameterization can be used to estimate rainout-determined tropospheric residence times from observational data sets. A review of published estimates of submicron aerosol tropospheric residence times based on observations shows that these are consistent with the model results.

Giorgi, Filippo↗