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Champion, R. L.

Publications and source records attributed to Champion, R. L..

Electron detachment from negative ions - The effects of isotopic substitution

Absolute total electron-detachment cross sections and relative elastic-scattering cross sections are presented for collisions of H(-) or D(-) with He, Ne, Ar, and N2 for collision energies ranging from about 2 eV up to 100 eV. Special emphasis has been given to the effect of isotopic substitution. It was found that, with the exception of the helium target, the results cannot be in accord with a model using a localized complex potential. On the other hand, the results for H(-) or D(-) with He are in excellent agreement with predictions based on previous (local complex potential) analysis of differential elastic-scattering measurements.

Champion, R. L.

Electron detachment in low-energy collisions of H/-/ and D/-/ with He

The applicability of the complex-potential theory to H(-)-He collisions is investigated. Measurements are conducted of the elastic differential cross section for H(-)-He collisions, taking into account energies in the range from 5 to 120 eV. A preliminary determination is made of the energy spectrum of detached electrons. The results are interpreted in terms of the complex-potential theory. The crossing point is determined together with the general shape of the HeH(-) potential curve.

Lam, S. K.

Low-energy elastic differential scattering of He/++/ by He.

Experimental results are developed for the relative elastic differential scattering of He(++) by He for collision energies in the range 4 equal to or less than E equal to or less than 75 eV. In the analysis of the data, semiclassical considerations are utilized, assuming that the dynamics of the scattering is governed solely by the B and E states of He2(++). It is shown that existing ab initio calculations for the intermolecular potentials predict differential cross sections which are not in particularly good agreement with the experimental data.

Lam, S. K.

Curve crossing for low-energy elastic scattering of He/+/ by Ne.

The perturbation seen in the experimental differential elastic-scattering cross section for the 40-eV He/+/ + Ne system has been attributed to a single crossing of two intermolecular potential-energy curves. A new theoretical treatment of the curve-crossing problem, namely, that of Delos and Thorson, is employed to obtain the crossing probabilities and phases associated with the crossing. These are determined by utilizing ab initio potentials involved in the crossing and are further used in a partial-wave calculation of the cross section, which is compared with our experiment. The origin of the oscillatory structure observed in the differential cross section is discussed in semiclassical terms by defining the problem in terms of two pseudo-deflection-functions. A rainbow effect is shown to be related to a particular feature (a maximum rather than a minimum) of these deflection functions.

Bobbio, S. M.

Curve crossing for low energy elastic scattering of He (plus) by Ne

The perturbation seen in the experimental differential elastic scattering cross section for the 40 eV He(+) + Ne system was attributed to a single crossing of two intermolecular potential energy curves. A new theoretical treatment of the curve crossing problem, that of Delos and Thorson, is employed to obtain the crossing probabilities and phases associated with the crossing. These are determined by utilizing ab initio potentials involved in the crossing and are further used in a partial wave calculation of the cross section, which is compared with our experiment. The origin of the oscillatory structure observed in the differential cross section is discussed in semiclassical terms by defining the problem in terms of two pseudo-deflection functions. A rainbow effect is shown to be related to a particular feature (a maximum rather than a minimum) of these deflection functions.

Bobbio, S. M.

Inversion problem for ion-atom differential elastic scattering.

The paper describes a practical application of Remler's (1971) method by which one constructs a set of phase shifts from high resolution measurements of the differential elastic scattering of protons by rare-gas atoms. These JWKB phase shifts are then formally inverted to determine the corresponding intermolecular potentials. The validity of the method is demonstrated by comparing an intermolecular potential obtained by direct inversion of experimental data with a fairly accurate calculation by Wolniewicz (1965).

Rich, W. G.

Interpretation of experimental differential elastic scattering cross section for H/+/ + Ne.

The interatomic V(r) found by potential-model calculations is compared to an ab initio calculation of the intermolecular potential for NeH+ due to Peyerimhoff (1965). The reason for a rather significant difference in the two results is discussed, and a new method due to Remler (1971) involving Regge poles is applied. The method can be used to calculate the differential cross section, where the starting point for such calculations is based on intuition in light of the classical deflection function.

Bobbio, S. M.