Mn-induced ferromagnetism and enhanced thermoelectric properties in Ru 1- x Mn x Sb 2+ δ
We report the experimental investigation of Mn doping effect on the electrical, magnetic, and thermal properties of Ru 1-x Mn x Sb 2+δ single crystals. While RuSb 2+δ is a diamagnetic semiconductor, partial replacement of Ru by Mn results in ferromagnetism with the Curie temperature 536 K and 540 K for x = 0.04 and 0.08, respectively. Correspondingly, the electrical resistivity decreases dramatically and shows metallic character due to the increased electron concentration. Surprisingly, the magnitude of the thermopower increases upon Mn doping, reaching -250 μV K -1 at 300 K for x = 0.08, while the thermal conductivity remains unchanged above 100 K. These indicate a strong modification of electronic structure by doped Mn, leading to enhanced thermoelectric properties. The carriers induced by Mn not only decrease the resistivity, but also mediate the long-range ferromagnetic ordering in Ru 1-x Mn x Sb 2+δ .