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Chanin, L. M.

Publications and source records attributed to Chanin, L. M..

Interference with negative particle sampling due to formation of positive ions in a quadrupole mass spectrometer

A quadrupole mass spectrometer has been utilized to study active discharges containing Cs vapor. Production of positive ions by electron impact within the mass spectrometer and subsequent secondary electron emission from cesiated surfaces produced spurious or pseudonegative ion signals which interfered with attempts to sample negative ions from the plasma. These effects may also occur in other gas discharge systems.

Kuehn, D. G.↗

Negative and positive cesium ion studies

Mass spectrometric analyses have been performed on the positive and negative species from discharges in Cs, He-Cs, and He-H2-Cs mixtures. Sampling was conducted through the electrodes of normal glow discharges and from close-spaced heated-cathode conditions, which approximate a cesium thermionic converter. No negative Cs ions were observed for Cs pressures less than .01 torr. Identified species included Cs(+), Cs2(+), Cs(-), and what appeared to be multiply charged ions. Low-mass negative and positive ions attributed to H2 were observed when an He-H2 mixture was also present in the discharge region.

Kuehn, D. G.↗

Investigations of negative and positive cesium ion species

A direct test is provided of the hypothesis of negative ion creation at the anode or collector of a diode operating under conditions simulating a cesium thermionic converter. The experimental technique involves using direct ion sampling through the collector electrode with mass analysis using a quadrupole mass analyzer. Similar measurements are undertaken on positive ions extracted through the emitter electrode. Measurements were made on a variety of gases including pure cesium, helium-cesium mixtures and cesium-hydrogen as well as cesium-xenon mixtures. The gas additive was used primarily to aid in understanding the negative ion formation processes. Measurements were conducted using emitter (cathode) temperatures up to about 1000 F. The major negative ion identified through the collector was Cs(-) with minor negative ion peaks tentatively identified as H(-), H2(-), H3(-), He(-) and a mass 66. Positive ions detected were believed to be Cs(+), Cs2(+) and Cs3(+).

Chanin, L. M.↗