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Chen, Bo

Publications and source records attributed to Chen, Bo.

At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Evoking ordered vacancies in metallic nanostructures toward a vacated Barlow packing for high-performance hydrogen evolution

Metallic nanostructures are commonly densely packed into a few packing variants with slightly different atomic packing factors. The structural aspects and physicochemical properties related with the vacancies in such nanostructures are rarely explored because of lack of an effective way to control the introduction of vacancy sites. Highly voided metallic nanostructures with ordered vacancies are however energetically high lying and very difficult to synthesize. Here, we report a chemical method for synthesis of hierarchical Rh nanostructures (Rh NSs) composed of ultrathin nanosheets, composed of hexagonal close-packed structure embedded with nanodomains that adopt a vacated Barlow packing with ordered vacancies. The obtained Rh NSs exhibit remarkably enhanced electrocatalytic activity and stability toward the hydrogen evolution reaction (HER) in alkaline media. Theoretical calculations reveal that the exceptional electrocatalytic performance of Rh NSs originates from their unique vacancy structures, which facilitate the adsorption and dissociation of H 2 O in the HER.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Crystallization in one-step solution deposition of perovskite films: Upward or downward?

Despite the fast progress of perovskite photovoltaic performances, understanding the crystallization and growth of perovskite films is still lagging. One unanswered fundamental question is whether the perovskite films are grown from top (air side) to bottom (substrate side) or from bottom to top despite 10 years of development. Here, by using grazing incidence x-ray diffraction and morphology characterizations, we unveil that the perovskite films prepared by one-step solution processes, including antisolvent-assisted spin coating and blade coating, follow the downward growth from intermediate phase during thermal annealing. Such a top-to-bottom downward growth is initialized by the evaporation of residual solvent from the top surface of “wet” films and is less sensitive to perovskite compositions and the wettability of underlying substrates. Addressing this fundamental question is important to understand the heterogeneity of perovskite films along the vertical direction, which markedly affects the efficiency and stability of perovskite solar cells.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Sequential Perturbation-based FDIA Detection using DERs for Unbalanced Distribution System

The power distribution system with its reliance on automated monitoring and control infrastructure makes it a complicated cyber-physical system and vulnerable to various cyber-attacks. This paper proposes a moving target defense inspired false data injection attack (FDIA) detection mechanism for an unbalanced distribution system. In the proposed grid diagnosis service framework, the distribution system operator judiciously manipulates power outputs of a subset of inverter-based distribution energy resources (DERs) to create secret low magnitude voltage perturbations which are inconsequential to the normal operation of the grid. A mixed-integer-linear-programming algorithm is developed to select the optimal set of DERs that can create a voltage perturbation signal of the required magnitude at each sensor location at a minimum cost. Then, a sequential detector is applied that detects for the FDIA as measurements are received from individual sensors. The performance of the proposed perturbation-based FDIA detection framework is demonstrated via simulation of the IEEE 123 bus test system.

Attack Detection↗
DOE OSTI2021

Cybersecurity of Wide Area Monitoring, Protection and Control Systems for HVDC Applications

The flexibility provided by High Voltage Direct Current (HVDC) systems can be further extended by Wide Area Monitoring, Protection, and Control (WAMAPC) systems. WAMPAC systems enable many HVDC applications and, on the other hand, inevitably introduce cybersecurity concerns that need to be addressed. In this work, a security domain layer and decision framework is reported to detect and mitigate the impact of false data injection (FDI) attacks targeting HVDC stations. Specifically, a rule-based cyber-attack detection method is introduced and implemented on Raspberry Pi and tested on the real-time HVDC simulation facility on the real-time digital simulator (RTDS) platform at ABB U.S. Corporate Research Center.

cybersecurity↗
DOE OSTI2020

Power System Resilience Enhancement in Typhoons Using a Three-Stage Day-Ahead Unit Commitment

In this work, we propose a three-stage resilient unit commitment model which considers uncertain typhoon paths and line outages to improve the power system resilience against typhoon events. The proposed solution coordinates resources in response to the worst-case scenario for each possible typhoon path. The optimal decision is based on the characterization of the power system schedule into three stages of preventive control, emergency control, and restoration. Preventive control is performed before the typhoon occurs by quickly adjusting the three-stage resilient unit commitment schedule; emergency control is conducted during the typhoon by shedding local loads to meet the power balance, while other control strategies are assumed to be unavailable due to possible interruptions in the communication system; restoration is realized after the typhoon, when resources are optimally dispatched to repair the outages of critical devices and recover the normal operation state of the power system quickly. Considering the typhoon path uncertainty, we have introduced a stochastic model for possible typhoon paths where all possible affected lines along each typhoon path are assumed to be on outage during the typhoon. Accordingly, we explore the strategy for co-optimizing the three stages in unit commitment. The proposed model is tested on the IEEE 118-bus system and the real-world provincial system to verify its effectiveness.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2020

Coastal Community Resiliency Enhancement Using Marine Hydrokinetic (MHK) Resources and Networked Microgrids

Enormous challenges are inherent in the operation of modern distribution grids. In particular, distribution feeders can be severely compromised under extreme conditions such as large-scale weather events (e.g., hurricanes, floods, and other types of natural disasters). To combat this problem, they turn to local energy support from distributed energy resources, such as solar and wind, marine hydrolinetic (MHK), and other types of energy. In this report, we investigate the actual characteristics of MHK resources to enhance coastal community resiliency. Two typical types of MHK resources (i.e., wave and tidal resources) illustrate the coastal resilience enhancement framework. By identifying their operational characteristics, such as target time-scales and potential power generation variations, we detail a holistic coastal community resiliency enhancement framework that integrates both optimization and control efforts. The optimization problem is formulated to significantly minimize the power outage time at the critical infrastructures in coastal communities by implementing multiple autonomous and dynamic microgrids around MHK resources. Therefore, during severe power outages caused by natural disasters (e.g., floods, hurricanes), the coastal community load profiles can be satisfied using local MHK resources in each microgrid with limited or no power support from upstream power grids.

16 TIDAL AND WAVE POWER↗
DOE OSTI2020

DC Microgrids Under Denial of Service Attacks: Feasibility and Stability Issues

Distributed control has been extensively studied for a DC microgrid to coordinate multiple grid assets where each asset can generate its own control decisions based on communications within its neighborhood. Nevertheless, such a control strategy usually has a strong dependence on active information exchange and needs to always maintain a pre-determined communication graph. This makes it vulnerable to cyber attacks, especially denial of service (DoS) attacks that block communication channels that effectively change the communication graph. In this paper, we study two potential impacts of DoS attacks: the inability to maintain steady-state and dynamical generation-demand balance, i.e. the feasibility and stability issues. We develop a mathematical model to describe the cyber-induced system steady-state and dynamical performance. The model reveals the impacts of DoS attacks and enables formal analysis. Case studies are shown to verify the proposed work.

41 EE - Solar Energy Technologies Office (EE-4S)↗
DOE OSTI2020

Region-Based Stability Analysis of Resilient Distribution Systems with Hybrid Grid-Forming and Grid-Following Inverters

In this paper, distribution system stability considering mixed grid-forming (GFM) and grid-following (GFL) inverters is discussed. A holistic small-signal model of the distribution feeder accommodating both GFM and GFL inverters is derived. In contrast to conventional point-by-point stability analysis, a region-based stability assessment approach is proposed and implemented to evaluate small-signal system stability with both GFM and GFL controls. Furthermore, to enhance the computational efficiency, an Artificial Intelligence (AI) assisted Kernel Ridge Regression (KRR) approach is developed to obtain the stability region boundary. Therefore, with the derived stability region, the impact of critical parameters on system stability is intuitively shown, and more importantly, the relationship between the maximum penetration level and the corresponding feasible range of the selected control parameters can be quantified. The proposed approach has been validated using MATLAB/Simulink.

grid-following↗
DOE OSTI2020

Ethanol Conversion over La 0.7 Sr 0.3 MnO 3–x (100): Autocatalysis, Adjacent O-Vacancies, Disproportionation, and Dehydrogenation

The mechanism for catalytic conversion of ethanol over La 0.7 Sr 0.3 MnO 3– x (100) surface to acetaldehyde and ethene was investigated. Pre-exposure temperature-programmed reaction (PE-TPR) experiments were performed in which ethanol was introduced to oxidized or reduced surfaces followed by heating. In particular, sequential PE-TPR experiments were conducted to incrementally and gradually reduce the surface. The products and their ratios were investigated as a function of surface reduction. The data show that acetaldehyde and ethene production is catalyzed with hydrogen abstraction and oxygen abstraction reactions occurring by intermediates in vacancies at various temperatures >400 K. Adsorption of acetaldehyde followed by a temperature-programmed reaction does not produce ethene, indicating that acetaldehyde is not an intermediate to ethene and that the hydrogen and oxygen abstraction from ethanol to ethene are decoupled steps. Further evidence for this mechanistic nuance was obtained using isotopically labeled ethanol (CD 3 CH 2 OH), which produces CD 3 CHO and CD 2 CH 2 . Additionally, the ratio of aldehyde production to alkene production increases with reduction, suggesting that aldehyde is produced from a disproportionation reaction between ethoxy species in adjacent O-vacancies, while ethene is produced from a dehydrogenation reaction with ethoxy species in vacancies without requiring adjacent O-vacancies. Counterintuitively, this finding indicates that the more oxygenated product (aldehyde vs ethene) is favored with more vacancies and that the net alcohol conversion is autocatalytic. Density functional theory calculations were able to find the previously unknown disproportionation pathway between ethoxies in adjacent O-vacancies, and kinetic Monte Carlo simulations support this interpretation by reproducing experimental selectivities. The activation energies for these pathways are estimated as 132 ± 10 kJ/mol for the disproportionation reaction (when occurring between ethoxies in adjacent vacancies) and as 148 ± 11 kJ/mol for the direct dehydrogenation reaction of an ethoxy in a vacancy. Based on these results, a mechanism with operative pathways based on elementary steps in O-vacancies is reported.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Phase-Selective Epitaxial Growth of Heterophase Nanostructures on Unconventional 2H-Pd Nanoparticles

Heterostructured, including heterophase, noble-metal nanomaterials have attracted much interest due to their promising applications in diverse fields. However, great challenges still remain in the rational synthesis of well-defined noble-metal heterophase nanostructures. Furthermore, we report the preparation of Pd nanoparticles with an unconventional hexagonal close-packed (2H type) phase, referred to as 2H-Pd nanoparticles, via a controlled phase transformation of amorphous Pd nanoparticles. Impressively, by using the 2H-Pd nanoparticles as seeds, Au nanomaterials with different crystal phases epitaxially grow on the specific exposed facets of the 2H-Pd, i.e., face-centered cubic (fcc) Au (fcc-Au) on the (002)h facets of 2H-Pd while 2H-Au on the other exposed facets, to achieve well-defined fcc-2H-fcc heterophase Pd@Au core–shell nanorods. Moreover, through such unique facet-directed crystal-phase-selective epitaxial growth, a series of unconventional fcc-2H-fcc heterophase core–shell nanostructures, including Pd@Ag, Pd@Pt, Pd@PtNi, and Pd@PtCo, have also been prepared. Impressively, the fcc-2H-fcc heterophase Pd@Au nanorods show excellent performance toward the electrochemical carbon dioxide reduction reaction (CO 2 RR) for production of carbon monoxide with Faradaic efficiencies of over 90% in an exceptionally wide applied potential window from –0.9 to –0.4 V (versus the reversible hydrogen electrode), which is among the best reported CO 2 RR catalysts in H-type electrochemical cells.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

A Flexible Operation of Distributed Generation in Distribution Networks With Dynamic Boundaries

Distributed generators performing black start to form isolated microgrids offer a flexible and resilient solution to service restoration in distribution systems. Employing the dynamic microgrid concept, distributed generators can form isolated microgrids by changing their physical boundaries through smart switches and conventional circuit breakers. However, the flexibility of distributed generators has not been thoroughly investigated and utilised in existing works. To address this issue, this letter presents a new model to the reconfiguration formulation in active distribution networks considering different operation modes of distributed generators. Compared with the existing models, this study provides a new formulation supporting different DGs' operation modes and fully making use of their flexibility. Illustrative results on IEEE 34-test systems verify the effectiveness of the proposed model.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2020

Networked Microgrids for Grid Resilience, Robustness, and Efficiency: A Review

Networked microgrids (NMGs) are clusters of microgrids that are physically connected and functionally interoperable. The massive and unprecedented deployment of smart grid technologies, new business models, and involvement of new stakeholders enable NMGs to be a conceptual operation paradigm for future distribution systems. Much work needs to be done, however, to enable NMGs to achieve seamless coordination, including physical, communication, and functional integration. In this paper, we review and summarize the state-of-the-art methodologies for operation and control of NMGs. Furthermore, we also specifically discuss the notion of dynamic boundaries for advanced microgrid applications. In addition, we introduce the opportunities, challenges, and possible solutions regarding NMGs for improving grid resilience, robustness, and efficiency.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2020

Simplified interconnection structure based on C 60 /SnO 2-x for all-perovskite tandem solar cells

The efficiencies of all-perovskite tandem devices are improving quickly. However, their complex interconnection layer (ICL) structures – with typically four or more layers deposited by different processes – limit their prospects for applications. Here, we report an ICL in all-perovskite tandem cells consisting merely of a fullerene layer and a SnO 2-x (0 60 layer is unintentionally n-doped by iodine ions from the perovskite and thus acts as an effective electron collecting layer. The SnO 2-x layer, formed by the incomplete oxidization of tin (x=1.76), has ambipolar carrier transport property enabled by the presence of a large density of Sn 2+ . The C 60 /SnO 1.76 ICL forms Ohmic contacts with both wide and narrow bandgap perovskite subcells with low contact resistivity. The ICL boosts the efficiencies of small-area tandem cells (5.9 mm 2 ) and large-area tandem cells (1.15 cm 2 ) to 24.4% and 22.2%, respectively. Lastly, the tandem cells remain 94% of its initial efficiency after continues 1-sun illumination for 1,000 hours.

14 SOLAR ENERGY↗
DOE OSTI2020

Dynamic Modeling of Sequential Service Restoration in Islanded Single Master Microgrids

This paper presents a methodology for generating restoration sequences in distribution systems and microgrids with emphasis on deriving optimal switching times for remote control switches (RCS). Microgrid architecture considered are assumed to be operating in islanded single master mode. Control methods for handling the unbalance inherent in distribution systems using single-phase controlled PQ inverters were developed and incorporated in the proposed method. The problem of considering simultaneously both energy optimization and dynamic stability of the system, which is lacking in existing methods, was addressed by studying the transient behavior of microgrids based on extended EMTP simulations and then approximate and incorporate these behaviors into the optimization formulation for restoration. The approach is based on multi-objective optimization of final restored load and total restoration time. The methodology was studied on a modified IEEE 123 node test feeder. An EMTP simulation in PSCAD of the formed microgrids was used to validate the accuracy of the dynamic and steady-state characteristics of the resulting systems. By considering the transient behavior of DGs during restoration, a better restoration sequence that does not trigger protection relays could be realized.

42 ENGINEERING↗
NASA NTRS2016

Determination of the Earth's Plasmapause Location from the CE-3 EUVC Images

The Moon-based Extreme Ultraviolet Camera (EUVC) aboard China's Chang'e-3 (CE-3) mission has successfully imaged the entire Earth's plasmasphere for the first time from the side views on lunar surface. An EUVC image on 21 April 2014 is used in this study to demonstrate the characteristics and configurations of the Moon-based EUV imaging and to illustrate the determination algorithm of the plasmapause locations on the magnetic equator. The plasmapause locations determined from all the available EUVC images with the Minimum L Algorithm are quantitatively compared with those extracted from insitu observations (Defense Meteorological Satellite Program, Time History of Events and Macroscale Interactions during Substorms, and Radiation Belt Storm Probes). Excellent agreement between the determined plasmapauses seen by EUVC and the extracted ones from other satellites indicates the reliability of the Moon-based EUVC images as well as the determination algorithm. This preliminary study provides an important basis for future investigation of the dynamics of the plasmasphere with the Moon-based EUVC imaging.

He, Fei↗