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Chen, J. H.

Publications and source records attributed to Chen, J. H..

51 records · Page 3

A study of the topology of dissipating motions in direct numerical simulations of time-developing compressible and incompressible mixing layers

A preliminary investigation of the geometry of flow patterns in numerically simulated compressible and incompressible mixing layers was carried out using 3-D critical point methodology. Motions characterized by high rates of kinetic energy dissipation and/or high enstrophy were of particular interest. In the approach the partial derivatives of the velocity field are determined at every point in the flow. These are used to construct the invariants of the velocity gradient tensor and the rate-of-strain tensor (P, Q, R, and P(sub s), Q(sub s), R(sub s) respectively). For incompressible flow the first invariant is zero. For the conditions of the compressible simulation, the first invariant is found to be everywhere small, relative to the second and third invariants, and so in both cases the local topology at a point is mainly determined by the second and third invariants. The data at every grid point is used to construct scatter plots of Q versus R and Q(sub s) versus R(sub s). Most points map to a cluster near the origin in Q-R space. However, fine scale motions, that is motions which are characterized by velocity derivatives which scale with the square root of R(sub delta), tend to map to regions which lie far from the origin. Definite trends are observed for motions characterized by high enstrophy and/or high dissipation. The observed trends suggest that, for these motions, the second and third invariants of the velocity gradient and rate-of-strain tensors are strongly correlated. The second and third invariants of the rate-of-strain tensor are related by K(-Q(sub s))(exp 3/2), which is consistent with the above scaling of velocity derivatives. The quantity K appears to depend on Reynolds number with an upper limit K = 2(the square root of 3)/9 corresponding to locally axisymmetric flow. For both the compressible and incompressible mixing layer, regions corresponding to high rates of dissipation are found to be characterized by comparable magnitudes of R(sub ij)R(sub ij) and S(sub ij)S(sub ij). For the incompressible mixing layer, regions characterized by the highest values of enstrophy are found to have relatively low strain rates.

Chen, J. H.↗

The isotopic composition of Ag in meteorites and the presence of Pd-107 in protoplanets

Results are presented on the isotopic composition of Ag and the concentrations of Pd and Ag in metal and sulfide phases in iron meteorites Gibeon, Derrick Peak, and Mundrabilla and in schereibersite in Derrick Peak. It was found that almost all iron meteorite samples with a ratio of Pd-108/Ag-109 greater than about 400 had an excess of Ag-107. The results, in conjunction with the data of Chen and Wasserburg (1983) on IIIA-IIIB meteorites, demonstrate the widespread occurrence of excess Ag-107 in diverse types of small early planetary bodies. The excess Ag-107 is believed to be produced by the decay of Pd-107.

Chen, J. H.↗

U, Th, and Pb isotopes in hot springs on the Juan de Fuca Ridge

Concentrations and isotopic compositions of U, Th, and Pb in three hydrothermal fluids from the Juan de Fuca Ridge were determined from samples obtained by the Alvin submersible. The samples were enriched in Pb and Th relative to deep-sea water, and were deficient in U. No clear relationship with Mg was found, suggesting nonideal mixing between the hot hydrothermal fluids and the cold ambient seawater. Values for U-234/U-238 have a seawater signature, and show a U-234 enrichment relative to the equilibrium value. The Pb isotopic composition has a uniform midocean ridge basalt signature, and it is suggested that Pb in these fluids may represent the best average value of the local oceanic crust.

Chen, J. H.↗

Precise timing of the last interglacial period from mass spectrometric determination of thorium-230 in corals

The development of mass spectrometric techniques for determination of Th-230 abundance has made it possible to reduce analytical errors in (U-238)-(U-234)-(Th-230) dating of corals even with very small samples. Samples of 6 x 10 to the 8th atoms of Th-230 can be measured to an accuracy of + or - 3 percent (2sigma), and 3 x 10 to the 10th atoms of Th-230 can be measured to an accuracy of + or - 0.2 percent. The time range over which useful age data on corals can be obtained now ranges from about 50 to about 500,000 years. For young corals, this approach may be preferable to C-14 dating. The precision with which the age of a coral can now be determined should make it possible to critically test the Milankovitch hypothesis concerning Pleistocene climate fluctuations. Analyses of a number of corals that grew during the last interglacial period yield ages of 122,000 to 130,000 years. The ages coincide with, or slightly post-date, the summer solar insolation high at 65 deg N latitude which occurred 128,000 years ago. This supports the idea that changes in Pleistocene climate can be the result of variations in the distribution of solar insolation caused by changes in the geometry of the earth's orbit and rotation axis.

Chen, J. H.↗

U-238-U-234-Th-230-Th-232 systematics and the precise measurement of time over the past 500,000 years

A method is presented for the high-precision measurement of the Th-230 abundance in corals by isotope-dilution mass spectrometry using techniques developed by Chen and Wasserburg (1980, 1981) and Chen et al. (1986). It is shown that 6 x 10 to the 8th atoms of Th-230 can be measured to + or - 30 percent (2 sigma) and 2 x 10 to the 10th atoms of Th-230 to + or - 2 percent. The time over which useful age data on corals can be obtained ranges from a few years to about 500 ky, with the uncertainty in age ranging from 5 y for a 180-y-old coral, to 44 y for a 8294-y-old coral, to 1.1 ky for a 123.1-ky-old coral. Ages were determined with high analytical precision for several corals that grew during high sea-level stands about 120 ky ago, supporting the view that the dominant cause of Pleistocene climate change was Milankovitch forcing.

Edwards, R. Lawrence↗

A comparative petrologic study of iron meteorites with radiogenic Ag-107 anomalies

The characteristics of the sulfide and metal phases of Derrick Peak, Cape York, Grant, Gibeon, and Santa Clara iron meteorite samples are examined. The textures and mineralogies of the samples are described. The effects of thermal and shock events on the distribution of Ag, and the relationship between Ag-107 and Pd are investigated. The correlation between the thermal histories and metal and sulfide nodules of the Gibeon and Santa Clara specimens is analyzed. It is noted that the Pd-107-Ag107 systematics involve the isotopic chemistry and cooling history of iron meteorites, the intensity of late extraterrestrial shock occurrences, and thermal processing.

Teshima, J.↗

Formation ages and evolution of Shergotty and its parent planet from U-Th-Pb systematics

The isotopic composition of Pb from Shergotty, Zagami, and EETA 79001 meteorites was determined for different phases. Using phases with low U-238/Pb-204 ratio, the initial leads of these meteorites were defined. Samples from all three meteorites were shown to have distinct initial leads, and, thus to have evolved from different reservoirs over most of solar system history in a low U-238/Pb-204 environment. It follows that the parent planet of the shergottites has a high Pb-204 concentration relative to U and must also be high in other volatiles. The possibility of the Martian origin of the SNC-type meteorites is discussed.

Chen, J. H.↗

The isotopic composition of silver and lead in two iron meteorites - Cape York and Grant

Anomalies in silver isotope composition in the metal phases of the Cape York (IIIA) and Grant (IIIB) iron meteorites are studied together with the lead isotopic composition of both the metal and sulfide phases of Cape York. Following extensive surface cleaning, the Ag-107/Ag-109 ratio in the metal phases of the meteorites is found to be in excess of the terrestrial ratio, and of that found in the sulfide phases. A definite correlation between the Ag-107/Ag-109 and Pd-108/Ag-109 ratios is observed for these meteorites, indicating the in situ decay of Pd-107 and supporting the widespread presence of Pd in the early universe. Lead, determined after cleaning and with chemical separations using low blank levels, is found to exist in variable proportions in the metal and sulfide phases. The sulfides appear to be dominated by radiogenic modern lead, which may be explained by terrestrial contamination or by late metamorphism in the meteorite parent body.

Chen, J. H.↗

Lead isotopic studies of the Samail ophiolite, Oman

The isotopic composition of Pb and the concentrations of U, Th, and Pb are determined for samples from massive sulfides and lithologic units of the Samail ophiolite. It is shown that the magma that formed the ophiolite was probably derived from a depleted mantle, similar in Pb isotopic composition to the source area of mid-ocean ridge basalt. The gross geochemical characteristics of the mantle sources have remained almost unchanged for the last 100 million years. It is also shown that the U-Th-Pb systematics of the Samail formation indicate that local vertical heterogeneity in the oceanic crust can result from crystal fractionation and metasomatism at, and near, an oceanic spreading center.

Chen, J. H.↗

The isotopic composition of uranium and lead in Allende inclusions and meteoritic phosphates

The isotopic compositions of uranium and lead in Ca-Al-rich inclusions from the Allende chondrite and in whitlockite from the St. Severin chondrite and the Angra dos Reis achondrite are reported. Isoptopic analysis of acid soluble fractions of the Allende inclusions and the meteoritic whitlockite, which show isotopic anomalies in other elements, reveals U-235/U-238 ratios from 1/137.6 to 1/138.3, within 20 per mil of normal terrestrial U abundances. The Pb isotopic compositions of five coarse-grained Allende inclusions give a mean Pb-207/Pb-206 model age of 4.559 + or - 0.015 AE, in agreement with the U results. Pb isotope ratios of two fine-grained inclusions and a coarse-grained inclusion with strong mass fractionation and some nonlinear isotopic anomalies indicate that the U-Pb systems of these inclusions have evolved differently from the rest of Allende. Th/U abundance ratios in the Allende inclusions and meteoritic phosphate are found to range from 3.8 to 96, presumably indicating an optimal case for Cm/U fractionation, although the normal U concentrations do not support claims of abundant live Cm-247 or Cm-247/U-238 fractionation at the time of meteorite formation, in contrast to previous results. A limiting Cm-247/U-235 ratio of 0.004 at the time of meteorite formation is calculated which implies that the last major r process contribution at the protosolar nebula was approximately 100 million years prior to Al-26 formation and injection.

Chen, J. H.↗

A search for isotopic anomalies in uranium

The U-238/U-235 ratios for nine bulk chondritic meteorites and a terrestrial basalt were measured. The total range in U-238/U-235 determined for both total meteorites and for acid leaches was from 137.2 terrestrial U. The typical errors in a single determination are plus or minus 6 per thousand (2 sigma m) for a 2 ng U sample from a chondrite. Taking the extreme values of delta U-235 for each measurement the maximum amount of excess U-235 that can be allowed to be present ranges from 200 million to 2 billion atoms per gram of bulk meteorite. These results do not support the claims of variations in U-238/U-235 at the percentage levels or number of excess U-235 atoms in some of the same meteorites as reported by several other previous workers.

Chen, J. H.↗

Lead isotope systematics of three Apollo 17 mare basalts

The paper deals with new and more accurate determinations of uranium, thorium, and isotopic lead data for five bulk samples and separate pyroxene, ilmenite, and plagioclase from basalt 71055. In a concordia diagram, the samples suggest a postcrystallization disturbance of the U-Pb systems of the rock. There is no compelling reason, from U-Pb data, to believe that the moon is younger than 4.55 AE.

Tilton, G. R.↗

Lead isotope systematics of mare basalt 75075

Uranium, thorium and isotopic lead data are reported for two bulk samples and separated pyroxene, ilmenite and plagioclase from basalt 75075. In a concordia diagram the whole rock, ilmenite and four pyroxene samples define a chord intersecting the concordia curve at approximately 4.25 and 2.8 AE. Three plagioclase samples plot distinctly off the chord. The crystallization age of 75075 is accurately determined at 3.74 AE by Rb-Sr, Sm-Nd and K-Ar measurements from other laboratories. It is not possible to adjust the isotopic composition of initial lead so as to reconcile the U-Pb data with a crystallization age of 3.74 AE. The data therefore indicate some type of post-crystallization disturbance of the U-Pb system that is not detected by the other systems. The 75075 data are one of the few examples of this type of age pattern found on the moon. If the disturbance was a single event, it probably occurred around 2.8 AE ago, the time indicated by the pyroxene, whole rock and ilmenite data.

Chen, J. H.↗

Lead isotope studies of mare basalt 70017

Uranium, thorium, and isotopic lead data for components of basalt 70017 are reported, and it is found that the whole rock, pyroxene, and ilmenite points in a concordia diagram plot along a chord intersecting the curve at 3.7 and 4.33 eons. The plagioclase data do not seem to lie on this line. The data for 70017 appear to plot along a distinctly different chord in a concordia diagram than do the data for 75055 and 75035, two other Apollo 17 mare basalts. The lead data are in accord with Sm-Nd results. A 3.7 eon crystallization age for 70017 would be consistent with the same kind of parentless lead that is indicated by previous studies of soils and soil breccias from stations at Taurus-Littrow. The Th/U ratio in ilmenite is 2.2, and the concentrations of these two elements are approximately twice those in pyroxene.

Mattinson, J. M.↗

Lead isotopic studies of lunar soils - Their bearing on the time scale of agglutinate formation

Fines (smaller than 75 microns) and bulk soil were studied to analyze loss of volatile lead; losses of the order of 10% to 30% radiogenic lead during the production of agglutinates are assessed. Lead isotope data from fine-agglutinate pairs are analyzed for information on the time scale of micrometeorite bombardment, from the chords generated by the data in concordia diagrams. Resulting mean lead loss ages were compared to spallogenic gas exposure ages for all samples. Labile parentless radiogenic Pb residing preferentially on or in the fines is viewed as possibly responsible for aberrant lead loss ages. Bulk soils plot above the concordia curve (in a field of excess radiogenic Pb) for all samples with anomalous ages.

Church, S. E.↗