Engineering topics

Chen, Zhiqiang

Publications and source records attributed to Chen, Zhiqiang.

3 records

DOE OSTI2022

Phase Transitions in Amorphous Germanium under Non-Hydrostatic Compression

As the pioneer semiconductor in transistor, germanium (Ge) has been widely applied in information technology for over half a century. Although many phase transitions in Ge have been reported, the complicated phenomena of the phase structures in amorphous Ge under extreme conditions are still not fully investigated. Here, we report the different routes of phase transition in amorphous Ge under different compression conditions utilizing diamond anvil cell (DAC) combined with synchrotron-based X-ray diffraction (XRD) and Raman spectroscopy techniques. Upon non-hydrostatic compression of amorphous Ge, we observed that shear stress facilitates a reversible pressure-induced phase transformation, in contrast to the pressure-quenchable structure under a hydrostatic compression. These findings afford better understanding of the structural behaviors of Ge under extreme conditions, which contributes to more potential applications in the semiconductor field.

Xu, Jianing (ORCID:0000000325474344)↗

DOE OSTI2021

A strain-driven thermotropic phase boundary in BaTiO 3 at room temperature by cycling compression

In BaTiO 3 single crystals, we observed a strain-driven phase transition from the tetragonal phase to the tetragonal-orthorhombic phase boundary which can be introduced by slow cycling compressions (a loading of up to 0.5 GPa, strain rate of 10 -4 s -1 , and 100 cycles) at room temperature. Different from the well-known tetragonal to cubic phase transition under stress (~2 GPa), it only takes place locally around bent 90° domain walls. The inhomogeneous local stress and electrical fields as well as the mobile point defect pinning effect contribute to the phase re-entrance. Through comparison experiments by in situ synchrotron x-ray diffraction, Raman scattering, and (scanning) transmission electron microscopy, we explored the phase transition mechanism. Based on that, we developed a mechanical method to obtain well-stabilized high-density thermotropic phase boundary structures (with tetragonal, orthorhombic, and bridging monoclinic phases) in BaTiO 3 for potential applications.

36 MATERIALS SCIENCE↗

NASA NTRS2020

An Integrated Model of Models for Global Flood Alerting

A dramatic increase in frequency of minor to major flooding since 2000 has caused significant damage to infrastructure and economic losses across the world. To mitigate and recover from these losses, actions have been taken to build resilient communities and infrastructures. Situational awareness in near real-time is essential to ensure community resilience and enhance response and recovery efforts. Several hydrologic and hydraulic flood models are available at various spatial and temporal resolutions at regional to global scale. Given the global coverage of two operational flood models - GloFAS (Global Flood Awareness System) and GFMS (Global Flood Monitoring System), the first component of this project first focuses on integrating the outputs from these two models to classify flood severity and send alerts based on potential for impacts similar to the USGS PAGER (used for severity alerting and impact analysis for earthquakes). The second component of the project focuses on using flood outputs derived from earth observation data to validate, update and add additional exposure and impact products to flood alerts. The flood impacts and severity information will be disseminated as alerts and maps through the DisasterAWARE platform, operated by the Pacific Disaster Center (PDC), that provides global multi-hazard alerting and Situational Awareness information to the emergency management community and public. In this presentation, the following objectives will be covered: (i) the effective integration of the flood models, (ii) accuracy of the flood model outputs (flood extent and depth) for specific flood events both in the United States and globally in comparison with each other and earth observation data.

Glasscoe, Margaret↗