Engineering topics

Cherchneff, Isabelle

Publications and source records attributed to Cherchneff, Isabelle.

5 records

NASA NTRS2010

The Origin of Dust in the Early Universe: Probing the Star Formation History of Galaxies by Their Dust Content

Two distinct scenarios for the origin of the approximately 4 x 10(exp 8) Solar Mass of dust observed in the high-redshift (z = 6.4) quasar J1148+5251 have been proposed. The first assumes that this galaxy is much younger than the age of the universe at that epoch so that only supernovae, could have produced this dust. The second scenario assumes a significantly older galactic age, so that the dust could have formed in lower-mass AGB stars. Presenting new integral solutions for the chemical evolution of metals and dust in galaxies, we offer a critical evaluation of these two scenarios. ^N;"(,, show that the AGB scenario is sensitive to the details of the galaxy's star formation history (SFH), which must consist of an early intense starburst followed by a period of low stellar activity. The presence or absence of massive amounts of dust in high-redshift galaxies can therefore be used to infer their SFH. However, a problem with the AGB scenario is that it produces a stellar mass that is significantly larger than the inferred dynamical mass of J1148+5251, an yet unresolved discrepancy. If this problem persists, then additional sites for the growth or formation of dust, such as molecular clouds or dense clouds around active galactic nuclei, must be considered.

Dwek, Eli↗

NASA NTRS1993

The formation of cyanopolyyne molecules in IRC + 10216

Molecule formation in the outer envelope of the carbon-rich star IRC + 10216 is investigated, with special emphasis on the chemistry of the cyanopolyynes HC(i)N (i = 3, 5, 7). Basic elements of the photochemical model of Glassgold et al. (1986) are revised. A dust model suitable to IRC + 10216 is used for which the extinction properties in the far-UV are those of 500 A amorphous carbon particles. A new chemical route to the formation of large cyanopolyynes is proposed, based on reactions of the radicals C3N and C5N with acetylene, and shown to be efficient. Our results agree qualitatively with observations of the spatial distributions of HCN, CN, HC3N, and C3N, but the calculated column densities of the higher-order cyanopolyynes appear to be too small. The amount of the allenic radical HC2N produced by molecular ion reactions with atomic N agrees with recent observations.

Cherchneff, Isabelle↗

NASA NTRS1992

Polycyclic aromatic hydrocarbon formation in carbon-rich stellar envelopes

A detailed chemical kinetic scheme is applied to stellar envelope profiles of gas density and temperature profiles in order to study the formation of PAH molecules in carbon-rich stellar outflows. Chemical concentration profiles are calculated for several envelope models by integrating the coupled continuity equations that include spherically expanding flows from an inner boundary at the shock formation radius. The influence of the 'inverse greenhouse' effect experienced by small PAHs is investigated and shown to increase the PAH yield by many orders of magnitude. It is shown that the route through propargyl radicals could be an important channel to produce benzene. PAH formation yields are found to be extremely sensitive to gas density and temperature and are much smaller than values inferred from the observed dust content of late-type carbon-rich stellar envelopes. It is therefore unlikely that aromatic molecules are generated in the stellar outflow itself.

Cherchneff, Isabelle↗

NASA NTRS1991

Polycyclic aromatic hydrocarbon optical properties and contribution to the acceleration of stellar outflows

The optical constants of four polycyclic aromatic hydrocarbon (PAH) molecules (benzene, pyrene, pentacene, and coronene) are determined from their measured laboratory absorption spectra. The Planck mean of the radiation pressure cross section is computed for each molecule and for amorphous carbon (AC) grains, and semiempirically estimated for large PAH molecules up to 400 carbon atoms. Assuming that PAHs are present in carbon-rich stellar outflows, the radiation pressure forces acting on them are calculated and compared with the radiation forces on AC particles. The results show that PAHs possess very different optical properties from AC grains. Small PAHs may experience an 'inverse greenhouse' effect in the inner part of the envelope, as they decouple from the gas close to the photosphere. The radiation pressure force on PAHs is always much less than the force at work on AC grains, and PAH molecules do not affect significantly the dynamics of the outflow.

Cherchneff, Isabelle↗

NASA NTRS1989

Infrared fluorescence from PAHs in the laboratory

Several celestial objects, including UV rich regions of planetary and reflection nebulae, stars, H II regions, and extragalactic sources, are characterized by the unidentified infrared emission bands (UIR bands). A few years ago, it was proposed that polycyclic aromatic hydrocarbon species (PAHs) are responsible for most of the UIR bands. This hypothesis is based on a spectrum analysis of the observed features. Comparisons of observed IR spectra with lab absorption spectra of PAHs support the PAH hypothesis. An example spectrum is represented, where the Orion Bar 3.3 micron spectrum is compared with the absorption frequencies of the PAHs Chrysene, Pyrene, and Coronene. The laser excited 3.3 micron emission spectrum is presented from a gas phase PAH (azulen). The infrared fluorescence theory (IRF) is briefly explained, followed by a description of the experimental apparatus, a report of the results, and discussion.

Cherchneff, Isabelle↗