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Chumakov, A. I.

Publications and source records attributed to Chumakov, A. I..

Magnetic State of Quasiordered Fe–Al Alloys Doped with Ga and B: Magnetic Phase Separation and Spin Order

Results of structural, magnetic, and Mössbauer studies of quasi ordered alloys Fe{sub 65}Al{sub 35−} {sub x}M{sub x} (M{sub x} = Ga, B; x = 0, 5 at %) are presented. The magnetic state of examined structurally–single-phase alloys at low temperatures is interpreted from the viewpoint of magnetic phase separation. An explanation is proposed for the observed behavior of magnetic characteristics of Fe{sub 65}Al{sub 35} and Fe{sub 65}Al{sub 30}Ga{sub 5} in the framework of the model of two magnetic phases, a ferromagnetic-type one and a spin density wave. The boron-doped alloy Fe{sub 65}Al{sub 30}B{sub 5} is shown to demonstrate behavior that is typical of materials with the ferromagnetic type of ordering.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Ionisation response in semiconductor structures exposed to the X-ray radiation of a femtosecond laser-plasma source

The possibilities of applying a femtosecond laser-plasma source of X-ray radiation for modelling the effect of single nuclear particles based on the principle of equivalent charge generation are analysed. The parameters of femtosecond X-ray radiation for the experimental modelling of individual radiation effects are validated. The experimental setup forming the X-ray radiation is described. The results of comparative ionisation response modelling in simple electronic devices using the FLUKA and FEANT codes are presented. (paper)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Rocking curve imaging of high quality sapphire crystals in backscattering geometry

Here, we report on the characterization of high quality sapphire single crystals suitable for high-resolution X-ray optics at high energy. Investigations using rocking curve imaging reveal the crystals to be of uniformly good quality at the level of ~10 -4 in lattice parameter variations, deltad/d. But, investigations using backscattering rocking curve imaging with lattice spacing resolution of deltad/d ~ 5.10 -8 shows very diverse quality maps for all crystals. Our results highlight nearly ideal areas with edge length of 0.2-0.5 mm in most crystals, but a comparison of the back re ection peak positions shows that even neighboring ideal areas exhibit a relative difference in the lattice parameters on the order of deltad/d = 10-20.10 -8 ; this is several times larger than the rocking curve width. Furthermore, the stress-strain analysis suggests that an extremely stringent limit on the strain at a level of ~100 kPa in the growth process is required in order to produce crystals with large areas of the quality required for X-ray optics at high energy.

36 MATERIALS SCIENCE↗

Peculiarities of FeSi phonon spectrum induced by a change of atomic volume

We analyze in detail the results of experimental investigations of the evolution of the thermal vibration spectra for iron atoms in iron monosilicide FeSi depending on two external parameters, viz., temperature T (in the range 46–297 K at pressure P = 0.1 MPa) and pressure P (in the range 0.1 MPa–43 GPa at temperature T = 297 K), obtained by nuclear inelastic scattering of synchrotron radiation. The decrease of the atomic volume is accompanied by a rearrangement of the phonon spectrum, which is manifested, in particular, in the splitting of the low-energy peak in the spectrum and in an increase of the energy for all phonons. The changes of the average energy of the iron atom vibrational spectrum and of the Debye energy with decreasing atomic volume are analyzed. Different versions of FeSi electron spectrum variation, which can be used to explain the observed phonon anomalies, are considered.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Structural complexity of simple Fe 2 O 3 at high pressures and temperatures

Although chemically very simple, Fe 2 O 3 is known to undergo a series of enigmatic structural, electronic and magnetic transformations at high pressures and high temperatures. So far, these transformations have neither been correctly described nor understood because of the lack of structural data. Here we report a systematic investigation of the behaviour of Fe 2 O 3 at pressures over 100 GPa and temperatures above 2,500 K employing single crystal X-ray diffraction and synchrotron Mössbauer source spectroscopy. Crystal chemical analysis of structures presented here and known Fe(II, III) oxides shows their fundamental relationships and that they can be described by the homologous series nFeO·mFe 2 O 3 . Decomposition of Fe 2 O 3 and Fe 3 O 4 observed at pressures above 60 GPa and temperatures of 2,000 K leads to crystallization of unusual Fe 5 O 7 and Fe 25 O 32 phases with release of oxygen. Lastly, our findings suggest that mixed-valence iron oxides may play a significant role in oxygen cycling between earth reservoirs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Time differentiated nuclear resonance spectroscopy coupled with pulsed laser heating in diamond anvil cells

Developments in pulsed laser heating applied to nuclear resonance techniques are presented together with their applications to studies of geophysically relevant materials. Continuous laser heating in diamond anvil cells is a widely used method to generate extreme temperatures at static high pressure conditions in order to study the structure and properties of materials found in deep planetary interiors. The pulsed laser heating technique has advantages over continuous heating, including prevention of the spreading of heated sample and/or the pressure medium and, thus, a better stability of the heating process. Time differentiated data acquisition coupled with pulsed laser heating in diamond anvil cells was successfully tested at the Nuclear Resonance beamline (ID18) of the European Synchrotron Radiation Facility. We show examples applying the method to investigation of an assemblage containing ε-Fe, FeO, and Fe{sub 3}C using synchrotron Mössbauer source spectroscopy, FeCO{sub 3} using nuclear inelastic scattering, and Fe{sub 2}O{sub 3} using nuclear forward scattering. These examples demonstrate the applicability of pulsed laser heating in diamond anvil cells to spectroscopic techniques with long data acquisition times, because it enables stable pulsed heating with data collection at specific time intervals that are synchronized with laser pulses.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Quenching rattling modes in skutterudites with pressure

In this paper, a high-pressure study of the lattice dynamics in the filled skutterudite Eu 0.84 Fe 4 Sb 12 was carried out by means of x-ray powder diffraction and nuclear inelastic scattering. The anharmonicity of particular phonon modes was characterized by mode and element specific Grüneisen parameters. The large anharmonicity of the rattling optical mode that is hybridized with the acoustical phonons at ambient pressure is reduced at high pressure as the phonon modes decouple. Finally, this result suggests that anharmonic coupling between acoustic and optical phonon modes plays a central role in the reduced thermal conductivity.

36 MATERIALS SCIENCE↗

Nuclear forward scattering of synchrotron radiation by 99 Ru

In this study, we measured nuclear forward scattering spectra utilizing the 99 Ru transition, 89.571(3) keV, with a notably mixed E2/M1 multipolarity. The extension of the standard evaluation routines to include mixed multipolarity allows us to extract electric and magnetic hyperfine interactions from 99 Ru-containing compounds. This paves the way for several other high-energy Mössbauer transitions, E~90 keV. Lastly, the high energy of such transitions allows for operando nuclear forward scattering studies in real devices.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Multispace quantum interference in a {sup 57}Fe synchrotron Moessbauer source

A physical picture for coherent emission of {gamma} rays by a nuclear array excited with synchrotron radiation is given. The particular case of a pure nuclear Bragg reflection from the {sup 57}FeBO{sub 3} crystal is analyzed. During free de-excitation of the nuclei, a nuclear exciton polariton is developing inside the crystal and generates at the exit of the crystal a coherent {gamma}-ray beam. In the crystal the nuclear levels of {sup 57}Fe are split because of a combined magnetic and electric interaction. The rich picture of {gamma}-ray interference is described, which involves geometrical space, energy, and spin domains. In the vicinity of the Neel temperature of the crystal the magnetic splitting of nuclear levels nearly collapses. These conditions lead to drastic changes in the angular, energy, and temporal properties of the emitted radiation. The emission angular function, which in the approximation of a plane incident wave represents the emission intensity for different angular settings of the crystal near Bragg angle, strongly broadens and transforms to a double-hump structure with a central dip between the peaks. The energy and temporal distributions of the emitted radiation crucially depend upon the crystal angular setting. Beyond the central dip, the energy distribution of nuclear scattering acquires a complicated form with several satellites at various energies. In contrast, at the exact angular position of the central dip, the energy spectrum exhibits a single line shape with the line width close to the natural width of the nuclear resonance. The obtained results constitute the theoretical basis for the understanding and for the further elaboration of the {sup 57}Fe synchrotron Moessbauer source--the device that provides a collimated beam of intense and polarized {gamma} radiation in an energy bandwidth of nanoelectronvolts, the nuclear resonance natural level width.

74 ATOMIC AND MOLECULAR PHYSICS↗