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Clayton, R. N.

Publications and source records attributed to Clayton, R. N..

72 records · Page 4

Characterization of lunar nitrogen components

Rocks of known and disparate cosmic-ray ages are analyzed to find the spallation production rate of N-15. A soil breccia of known formation age was analyzed for its bearing on the antiquity of the isotopically light component. Further stepwise heating analysis of soils shed further light on occurrences of the components. Lunar soil samples were etched slightly by fluorine, revealing significant differences in isotopic ratios between carbon on grain surfaces and bulk carbon; the surface carbon is not retained during agglutinate formation. Etching revealed that about 25% of the total nitrogen resides on the surface of grains; the nitrogen is isotopically heavy. Etching also revealed about 50% of helium in soils residing below the readily etched outermost 1% of soil grain surfaces.

Becker, R. H.↗

Consortium investigation of breccia 67435

The paper presents results of the initial phase of a consortium investigation of lunar rock 67435, a glass coated breccia which contains a unique spinel-troctolite clast. These results include oxygen isotopic data for the host breccia, bulk composition data for the host breccia, glass coating and a large aphanitic clast, and detailed petrographic descriptions of all lithologies encountered.

Warner, R. D.↗

Genetic relations between the moon and meteorites

The moon is shown to have an oxygen isotope distribution similar to that of the earth and the differentiated meteorites (achondrites, mesosiderites, pallasites, irons) but, according to the same criterion, the moon is unrelated to the ordinary chondrites or carbonaceous chondrites. The principal differences between the inferred chemical composition of the moon and that of chondritic meteorites is the depletion of volatile and semivolatile elements, the enrichment of uranium by a factor of 10-15, and the enrichment of the source regions of mare basalts in LIL elements by a factor of 5-10. The reported data support the theory that the moon was formed by the capture of differentiated meteorites. Volatile-element depletion and 'refractory' element enrichment are considered.

Clayton, R. N.↗

Nitrogen abundances and isotopic compositions in lunar samples

Isotopic analyses were carried out on soil separates as well as on bulk samples. Analyses of nitrogen fractions obtained by step-wise heating of the separates were also conducted. It was also attempted to obtain a value for the isotopic composition of indigenous lunar nitrogen from analyses of igneous rock samples. Several breccias were also analyzed for their nitrogen isotope ratios. The significance of the obtained results is discussed. Several lines of evidence point to the conclusion that the isotope ratio of the nitrogen being implanted into the lunar regolith has increased by some 15% over a period of at least 450 million years and possibly as long as 3,700 million years or more. This may be the result of changes in the nitrogen isotope ratio of the solar wind with time, or it may be due to outgassing and subsequent reimplantation of an isotopically light indigenous lunar nitrogen from the lunar interior in the early history of the moon.

Becker, R. H.↗

Oxygen isotopic constraints on the composition of the moon

The mean oxygen isotopic composition of 5 Apollo 17 soils, one Apollo 17 breccia and one Apollo 12 soil is delta O-18 = 5.63 + or - .05 and delta O-17 = 3.8 + or - .2%. These values are within several tenths of a part permil of the composition of a large fraction of the lunar interior. High-temperature condensate aggregates from Allende and other C2 and C3 chondrites are vastly enriched in O-16 compared to this composition. The moon cannot be a mixture of ordinary chondrites and Allende inclusions, nor can it be derived from such a mixture by chemical fractionation processes. The moon's isotopic composition is consistent with a mixture of high- and low-temperature condensates but the refractory fraction would have to be free of the O-16-rich component so prevalent in the meteoritic aggregates, a fact which makes such models less attractive than they once seemed.

Grossman, L.↗

Loss of oxygen, silicon, sulfur, and potassium from the lunar regolith

The processes of formation and maturation of lunar soils lead to enrichments in the heavy stable isotopes of oxygen, silicon, sulfur, and potassium. The isotopic enrichment implies substantial losses of these elements from the moon. Vaporization by micrometeorite impact and by ion sputtering have removed at least 1% of the mass of the regolith. The losses of sulfur and potassium amount to at least 20-30% of their original abundance in the regolith.

Clayton, R. N.↗

A component of primitive nuclear composition in carbonaceous meteorites

Oxygen isotope analysis of anhydrous high-temperature phases from carbonaceous meteorite chondrites indicates a high degree of O(17) and O(18) isotope depletion. The isotope decay is believed to be a result of nuclear rather than chemical processes caused by the admixture of a component consisting of almost pure O(16). It is theorized that this component may predate the solar system and may represent interstellar dust with a separate history of nucleosynthesis.

Clayton, R. N.↗

Oxygen isotopic composition of the Luna 20 soil.

Comparison of the oxygen isotopic composition in the Luna 20 soil sample with the oxygen isotopic abundances of the Apollo 11, 12, 14, and 15 lunar soil samples. The Luna 20 soil is found to have a relatively low delta 0-18 content (0.57%) in comparison to the other lunar soils (0.58 to 0.63%).

Clayton, R. N.↗

Oxygen isotope temperatures of 'equilibrated' ordinary chondrites.

Measurements have been made of O-18/O-16 ratios of coexisting minerals (plagioclase, pyroxene, olivine) from nine ordinary chondrites. The O-18 content of a given mineral increases systematically from H through L to LL group. Isotope fractionations for mineral pairs fall on a concordancy line, suggesting that these minerals were crystallized in oxygen isotope equilibrium. The isotopic temperature is estimated to be 950 (plus or minus 100) C for seven of the type 5 and type 6 chondrites.

Onuma, N.↗

Oxygen isotope cosmothermometer.

Variations in oxygen isotopic abundances of meteoritic minerals, chondrules, whole meteorites, and planets are discussed in terms of a model involving isotopic exchange between primordial dust and a cooling solar nebular gas. From the temperature-dependence of the isotopic fractionation factors, temperatures have been assigned to the processes of initial condensation, chondrule formation, and planetary accretion. Separated phases from carbonaceous chondrites fall into three isotopic groups representing widely differing conditions of formation: (1) low-iron olivine and pyroxene, and calcium-aluminum silicates condensed at temperatures above 1000 K; (2) high-iron olivine and pyroxene melted to form chondrules after prior cooling and exchange to temperatures of 530-620 K; and (3) hydrous silicates condensed at temperatures below 400 K.

Onuma, N.↗

Oxygen isotope composition of the Luna 16 soil.

The results of the 0-18/0-16 analysis of the available 16-mg sample of Luna 16 soil are presented and compared with oxygen-isotope compositions of several Apollo soils. The analytical techniques were the same as those of Onuma et al. (1970) applied to the Apollo samples. It is found that the soil from Mare Fecunditatis is indistinguishable in oxygen isotopic composition from the soils of Mare Tranquillitatis and the Fra Mauro region.

Clayton, R. N.↗