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Collins, L.

Publications and source records attributed to Collins, L..

DOE-STD-1112-2019 Review for the 2020 DOELAP Radiobioassy Program Assessment

In compliance with DOE-STD-1112-2019 section 4.6(i) and in preparation for a 2020 DOELAP assessment of Radiobioassay Program, the QA officer, WBC/SLAB Group Leader, BLAB/RML Group Leader, and WBC/SLAB Health Physicists reviewed the program’s performance in accordance with the criteria found in DOE-STD-1112-2019 and in the accompanying checklist provided to the DOELAP assessor community in January 2020.

61 RADIATION PROTECTION AND DOSIMETRY↗

Thickness and strain dependence of piezoelectric coefficient in BaTiO 3 thin films

We explore the thickness dependence of the converse piezoelectric coefficient (d 33 ) in epitaxial thin films of BaTiO 3 (BTO) grown on (001) SrTiO 3 substrates. Piezoresponse force microscope was performed using an atomic force microscope equipped with an interferometric displacement sensor allowing direct quantification of electromechanical coupling coefficients in BTO free from unwanted background contributions. We find that 80-nm-thick films exhibit a d 33 of ~20.5pm/V, but as the thickness is reduced, the d 33 reduces to less than 2 pm/V for a 10 nm film. To explain the atomistic origin of the effect, we performed molecular dynamics simulations with a recently developed ab initio-derived reactive force field, constructed using the ReaxFF framework. Simulations predict that under applied electric fields thin films of BaTiO 3 show an increasing thickness, with compressive strain, of the region screening the depolarization-field. This study confirms quantitatively the drop in piezoelectric performance in BTO ultrathin films and again highlights the importance of the screening mechanisms when films approach the ultrathin limits in dictating the functional behaviors.

36 MATERIALS SCIENCE↗

Effect of melittin on water diffusion and membrane structure in DMPC lipid bilayers

Quasielastic neutron scattering (QENS) is well suited for studying the dynamics of water in proximity to supported membranes whose structure can be characterized by atomic force microscopy (AFM). Here we use QENS to investigate the effect of an adsorbed peptide (melittin) on water diffusion near a single-supported zwitterionic membrane (DMPC). Measurements of the incoherent elastic neutron intensity as a function of temperature provide evidence of bulk-like water freezing onto the melittin, which AFM images indicate coalesces into peptide-lipid domains as the peptide concentration increases. Analysis of the QENS spectra indicates that, at sufficiently high melittin concentrations, a water component diffusing more slowly than bulk-like water first freezes onto the bound melittin.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Characterization of martensite-austenite constituents and micro-hardness in intercritical reheated and coarse-grained heat affected zones of API X70 HSLA steel

Highlights: • The influence of cold wire addition to the tandem submerged arc welding process on the ICRCGHAZ is investigated. • Comprehensive characterization of the microstructure and micro-hardness in the ICRCGHAZ of a HSLA steel is performed. • A lower fraction of finely distributed M-A formed in the ICRCGHAZ of TSAW + cold wire steel, leading to lower micro-hardness. • The aspect ratio and inter-particle spacing of M-A constituents decreased in the ICRCGHAZ through cold wire addition. - Abstract: The thermal cycles that high strength low alloy (HSLA) low carbon steels experience during welding inevitably affect the microstructure and mechanical properties of the weld joints. It is generally agreed that the coarse-grained heat affected zone (CGHAZ) and the intercritical reheated coarse-grained heat affected zone (ICRCGHAZ) in one-pass and multi-pass welding, respectively, have the poorest microstructure and mechanical properties relative to the rest of the steel joint. The martensite-austenite (M-A) constituents formed in the HAZ regions predominantly govern property deterioration in the CGHAZ and the ICRCGHAZ by promoting the initiation and propagation of micro-cracks. However, the characteristics of the M-A constituents, i.e., fraction, size, shape and aspect ratio, are strongly affected by the welding heat input. Accordingly, in this study, the aim was to evaluate the influence of a cold wire addition in conventional tandem submerged arc welding (TSAW + cold-wire) on the microstructure and micro-hardness in the CGHAZ and ICRCGHAZ. Microstructural characterization showed that a lower fraction of finely distributed M-A constituents associated with smaller prior austenite grains (PAGs) formed in the CGHAZ of the steel welded by the TSAW + cold-wire process (CW-OD weld) relative to that welded by the conventional TSAW process (TW-OD weld). Furthermore, the fraction of M-A constituents in the ICRCGHAZ of the CW-OD weld was decreased. A higher fraction of slender shaped M-A constituents in the ICRCGHAZ of the TW-OD weld resulted in an increase in the micro-hardness. The microstructure and micro-hardness changes associated with cold wire addition were attributed to the lower welding heat input and, consequently, the faster cooling rate with a corresponding reduction in the retention time in the austenitic region and ferrite/austenite region in the CGHAZ and ICRCGHAZ regions, respectively.

36 MATERIALS SCIENCE↗

Full Information Acquisition in Scanning Probe Microscopy

Scanning Probe Microscopy (SPM) has unlocked the nanoworld for exploration and control. While substantial effort has been dedicated towards the development of better instrumental platforms and probes, opportunities related to signal processing and data acquisition in SPMareoftenoverlooked. In this work, we discuss opportunities offered by capturing the full information of thedata stream from the detector, referred to as General Mode (G-Mode) SPM. This approach allows exploration of the complex tip-surface interactions, spatial mapping of multidimensional variability of material properties and their mutual interactions, and imaging at the information channel capacity limit, providing a new paradigm for SPM detection.

47 OTHER INSTRUMENTATION↗

Photorefractivity in a Titanium Doped ZnCdTe Crystal

Single crystals of Zn(.04)Cd(.96)Te was grown by horizontal physical vapor transport (PVT) method and doped by annealing with TiTe2 powder at 600 C for six days. Photorefractive two-beam coupling, along with photoluminescence and absorption spectroscopy, were used to characterize the ZnCdTe:Ti crystal. At 1.32 micrometers, the photorefractive gain has been measured as a function of the grating period. A gain of about 0.16/cm was obtained at an intensity of about 0.1 W/sq cm. The results of this titanium doped ZnCdTe crystal are compared to that of vanadium-doped CdTe crystals reported previously.

Davis, M.↗

Momentum Transfer Studies and Studies of Linear and Nonlinear Optical Properties of Metal Colloids and Semiconductor Quantum Dots

Phase 1 of this work involved design work on a momentum transfer device. The progress on design and testing will be presented. Phase 2 involved the systematic study of the MPD thruster for dual uses. Though it was designed as a thruster for space vehicles, the characteristics of the plasma make it an excellent candidate for industrial applications. This project sought to characterize the system for use in materials processing and characterization. The surface modification on ZnCdTe, CdTe, and ZnTe will be presented. Phase 3 involved metal colloids and semiconductor quantum dots. One aspect of this project involves a collaborative effort with the Solid State Division of ORNL. The thrust behind this research is to develop ion implantation for synthesizing novel materials (quantum dots wires and wells, and metal colloids) for applications in all optical switching devices, up conversion, and the synthesis of novel refractory materials. The ions of interest are Au, Ag, Cd, Se, In, P, Sb, Ga, and As. The specific materials of interest are: CdSe, CdTe, InAs, GaAs, InP, GaP, InSb, GaSb, and InGaAs. A second aspect of this research program involves using porous glass (25-200 A) for fabricating materials of finite size. The results of some of this work will also be reported.

Collins, W. E.↗

PROFILE user's guide

User information for program PROFILE, an aerodynamics design utility for refining, plotting, and tabulating airfoil profiles is provided. The theory and implementation details for two of the more complex options are also presented. These are the REFINE option, for smoothing curvature in selected regions while retaining or seeking some specified thickness ratio, and the OPTIMIZE option, which seeks a specified curvature distribution. REFINE uses linear techniques to manipulate ordinates via the central difference approximation to second derivatives, while OPTIMIZE works directly with curvature using nonlinear least squares techniques. Use of programs QPLOT and BPLOT is also described, since all of the plots provided by PROFILE (airfoil coordinates, curvature distributions) are achieved via the general purpose QPLOT utility. BPLOT illustrates (again, via QPLOT) the shape functions used by two of PROFILE's options. The programs were designed and implemented for the Applied Aerodynamics Branch at NASA Ames Research Center, Moffett Field, California, and written in FORTRAN and run on a VAX-11/780 under VMS.

Collins, L.↗