The Viability of Glycine Fermentation in Titan’s Subsurface Ocean
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Antonin Affholder↗
Engineering topics
Conor A. Nixon
Publications and source records attributed to Conor A. Nixon.
Chapter 6: Titan’s Atmospheric Structure, Composition, Haze, and Dynamics
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Veronique Vuitton↗
New Constraints on Titan's Stratospheric n-Butane Abundance
Curiously, n-butane has yet to be detected at Titan, though it is predicted to be present in a wide range of abundances that span over 2.5 orders of magnitude. We have searched infrared spectroscopic observations of Titan for signals from n-butane (n-C4H10) in Titan's stratosphere. Three sets of Cassini Composite Infrared Spectrometer Focal Plane 4 (1050–1500 cm−1) observations were selected for modeling, having been collected from different flybys and pointing latitudes. We modeled the observations with the Nonlinear Optimal Estimator for MultivariatE Spectral AnalySIS radiative transfer tool. Temperature profiles were retrieved for each of the data sets by modeling the ν4 emission from methane near 1305 cm−1. Then, incorporating the temperature profiles, we retrieved abundances of all of Titan's known trace gases that are active in this spectral region, reliably reproducing the observations. We then systematically tested a set of models with varying abundances of n-butane, investigating how the addition of this gas affected the fits. We did this for several different photochemically predicted abundance profiles from the literature, as well as for a constant-with-altitude profile. Ultimately, though we did not produce any firm detection of n-butane, we derived new upper limits on its abundance specific to the use of each profile and to multiple different ranges of stratospheric altitudes. These results will tightly constrain the C4 chemistry of future photochemical modeling of Titan's atmosphere and also motivate the continued search for n-butane and its isomer, isobutane.
Brendan L. Steffens↗
Titan’s Global Radiant Energy Budget During the Cassini Epoch (2004-2017)
Radiant energies of planets and moons are of wide interest in the fields of geoscience and planetary science. Based on long-term multiinstrument observations from the Cassini spacecraft, we provide here the first observational study of Titan's global radiant energy budget and its seasonal variations. Our results show that Titan's radiant energy budget is not balanced over the Cassini era (2004–2017) with the absorbed solar energy (1.208 ± 0.008) × 10^(23) J larger than the emitted thermal energy (1.174 ± 0.005) × 10^(23) J. The energy imbalance is 2.9 ± 0.8% of the emitted thermal energy. Titan's global radiant energy budget is not balanced either at the timescales of Earth's years and Titan's seasons. In particular, the energy imbalance can be beyond 10% of the emitted thermal energy at the timescale of an Earth year. The energy imbalance revealed in this study has important impacts on Titan, which should be examined further by theories and models.
Ellen C. Creecy↗
Spatial and Seasonal Variations in C3Hx Hydrocarbon Abundance in Titan’s Stratosphere from Cassini CIRS Observations
Of the C3Hx hydrocarbons, propane (C3H8) and propyne (methylacetylene, CH3C2H) were first detected in Titan’s atmosphere during the Voyager 1 flyby in 1980. Propene (propylene, C3H6) was first detected in 2013 with data from the Composite InfraRed Spectrometer (CIRS) instrument on Cassini. We present the first measured abundance profiles of propene on Titan from radiative transfer modeling, and compare our measurements to predictions derived from several photochemical models. Near the equator, propene is observed to have a peak abundance of 10 ppbv at a pressure of 0.2 mbar. Several photochemical models predict the amount at this pressure to be in the range 0.3 - 1 ppbv and also show a local minimum near 0.2 mbar which we do not see in our measurements. We also see that propene follows a different latitudinal trend than the other C3 molecules. While propane and propyne concentrate near the winter pole, transported via a global convective cell, propene is most abundant above the equator. We retrieve vertical abundances profiles between 125 km and 375 km for these gases for latitude averages between 60◦S to 20◦S, 20◦S to 20◦N, and 20◦N to 60◦N over two time periods, 2004 through 2009 representing Titan’s atmosphere before the 2009 equinox, and 2012 through 2015 representing time after the equinox. Additionally, using newly corrected line data, we determined an updated upper limit for allene (propadiene, CH2CCH2), the isomer of propyne). The measurements we present will further constrain photochemical models, by refining reaction rates and the transport of these gases throughout Titan’s atmosphere.
Nicholas A. Lombardo↗
Mapping the seasonal variability of Titan’s upper atmospheric gases using ALMA
We present a study of the impact of seasonal effects on the spatial distribution of Titan’s atmospheric gases HNC, CH3CN, and HC3N over a timescale of less than a Titan month (9 Earth months). These molecules are synthesized primarily in the upper and middle atmosphere as a result of CH4 and N2 photochemistry, and are redistributed around Titan’s globe as a result of diffusion and zonal and meridional circulation. With observations from the Atacama Large Millimeter/submillimeter Array (ALMA) obtained in August 2016 [1] and May 2017 [2], we produced high-resolution, spectrally and spatially resolved maps of the emission from these gases. These observations are contemporaneous with the end of the Cassini mission (around the time of the northern summer solstice), allowing for studies of seasonal variations in Titan’s organic chemistry through analysis of the production, destruction, and transport of complex molecules. We observed a strong reduction of 41% ± 4% in the HC3N flux coming from the north pole, while CH3CN and HNC remained relatively stable (within errors) over the 9 month period of our observations. In the south pole, CH3CN presented a 31% ± 10% increase, while HNC saw a reduction of 20% ± 8%, and HC3N remained fairly stable (within errors). The HNC emission comes primarily from the highest (thermospheric) altitudes, and is distributed more uniformly about Titan’s limb than HC3N and CH3CN; the latter two molecules show strong polar enhancements due to meridional circulation. The steep decline in the HC3N north polar concentration is consistent its short photochemical lifetime (compared to HNC and CH3CN), combined with a reduction in meridional transport of gases produced at lower latitudes, towards the northern (summer) pole. The loss of emission of HC3N in the northern hemisphere is also consistent with the breakdown of Titan’s northern polar vortex during the onset of the northern summer, leading to a loss of confinement of these species [3].
Titan↗
Photonic Integrated Circuit TUned for Reconnaissance and Exploration (PICTURE)
The mid-infrared (MIR) spectral range (3-5 μm) is of particular interest for remotely sensing gaseous molecules such as H2O, CO2, CH4, N2O, CO, NH3, and other compounds. The infrared spectra of planets, moons, comets, and asteroids are rich in information, including gas composition and surface mineralogy. Significant advances in technology have emerged for ground-based telescopes, including the higher spectral resolution permitted by cross-dispersed instruments and heterodyne techniques. New technologies offer the opportunity to break this barrier, by using solid-state photonics. In the past three years, under the NASA ROSES PICASSO program, we have been developing key components for a revolutionary MIR spectrometer: Photonic Integrated Circuit TUned for Reconnaissance and Exploration (PICTURE), which is based on integrated photonics technology that offers ultra-small size, weight, and power (SWaP) with non-moving parts and low cost for future planetary missions. In this paper, we will describe our science and technology development progress leading to demonstrating the concept and functionalities of the PICTURE instrument. The photonic integrated circuit spectrometer (PICS) of the PICTURE instrument uses an integrated heterodyne detection scheme to significantly reduce SWaP and improve sensitivity. Our program goals are to advance the building blocks needed for the PICS, which include arrayed waveguide gratings (AWGs), quantum cascade lasers (QCLs) as local oscillators, and quantum cascade detectors (QCDs) as heterodyne detectors. In addition, we are leveraging a NASA SBIR program to develop the toolsets needed to fabricate MIR photonics lanterns (PL). The PL is a critical component that enables PICTURE to bring a signal from the collecting telescope to the PICS, which requires single optical mode inputs. PICTURE focuses on the CO spectral band at 4.6-4.8 μm that is of key importance to cometary science. We also continue to explore future instrument concepts that exploit the broad wavelength potential of the PICS design to perform spectroscopy spanning the full MIR and longwave IR (LWIR) bands. This will have wide applicability in planetary science, for example, to probe the strongest CO2, H2O, and CH4 transitions that are difficult (CH4) or impossible (CO2, H2O) to detect using Earth-based telescopes due to atmospheric opacity. Each integrated-photonics-spectrometer chip will feature a single heterodyne room-temperature laser with a wide wavelength tuning range, or multiple local-oscillator lasers for much broader spectral coverage. The fully developed PICTURE instrument will provide a cost-effective, high-resolution spectrometer for future space applications.
Anthony W. Yu↗