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Considine, D. B.

Publications and source records attributed to Considine, D. B..

Simulating Observed Ozone Loss in the Northern Hemisphere Winter

Ozone amounts observed at high Northern latitudes in late winter and early spring have been relatively very low in four of the last six years. On the face of it, this decline appears similar to that observed in the Antarctic in the mid-1980s in spite of the fact that the abundance of stratospheric chlorine is currently steady or decreasing. In order to predict the extent to which this change represents a trend, and to understand what combination of factors produces the low ozone, we need to accurately simulate these observations with models. In this presentation, we focus on the winter of 1999-2000, which exhibited some of the lowest ozone ever recorded in the Northern hemisphere. It also contained the largest-ever assembled set of atmospheric measurements and modeling activities in the SAGE III Ozone Loss and Validation Experiment/Third European Stratospheric Experiment on Ozone (SOLVE/THESEO). We use SOLVE/THESEO observations in comparison with the Goddard 3-D global model of stratospheric chemistry and transport to explore the model's capability to simulate the evolution of ozone and other species through the winter. We will discuss advective transport and mixing, chlorine activation, and denitrification, which are key processes to accurately simulating wintertime ozone. Preliminary results show that, although the model tracer transport and chlorine activation compare relatively well with observations, the magnitude of observed ozone loss is difficult to achieve in the model. Calculated ozone loss is sensitive to denitrification, which presents a major challenge to parameterization in a global model. Simulation requirements and uncertainties will be evaluated.

Kawa, S. R.↗

A Monte Carlo Uncertainty Analysis of Ozone Trend Predictions in a Two Dimensional Model

We use Monte Carlo analysis to estimate the uncertainty in predictions of total O3 trends between 1979 and 1995 made by the Goddard Space Flight Center (GSFC) two-dimensional (2D) model of stratospheric photochemistry and dynamics. The uncertainty is caused by gas-phase chemical reaction rates, photolysis coefficients, and heterogeneous reaction parameters which are model inputs. The uncertainty represents a lower bound to the total model uncertainty assuming the input parameter uncertainties are characterized correctly. Each of the Monte Carlo runs was initialized in 1970 and integrated for 26 model years through the end of 1995. This was repeated 419 times using input parameter sets generated by Latin Hypercube Sampling. The standard deviation (a) of the Monte Carlo ensemble of total 03 trend predictions is used to quantify the model uncertainty. The 34% difference between the model trend in globally and annually averaged total O3 using nominal inputs and atmospheric trends calculated from Nimbus 7 and Meteor 3 total ozone mapping spectrometer (TOMS) version 7 data is less than the 46% calculated 1 (sigma), model uncertainty, so there is no significant difference between the modeled and observed trends. In the northern hemisphere midlatitude spring the modeled and observed total 03 trends differ by more than 1(sigma) but less than 2(sigma), which we refer to as marginal significance. We perform a multiple linear regression analysis of the runs which suggests that only a few of the model reactions contribute significantly to the variance in the model predictions. The lack of significance in these comparisons suggests that they are of questionable use as guides for continuing model development. Large model/measurement differences which are many multiples of the input parameter uncertainty are seen in the meridional gradients of the trend and the peak-to-peak variations in the trends over an annual cycle. These discrepancies unambiguously indicate model formulation problems and provide a measure of model performance which can be used in attempts to improve such models.

Considine, D. B.↗

Simulation of Long Lived Tracers Using an Improved Empirically Based Two-Dimensional Model Transport Algorithm

We have developed a new empirically-based transport algorithm for use in our GSFC two-dimensional transport and chemistry model. The new algorithm contains planetary wave statistics, and parameterizations to account for the effects due to gravity waves and equatorial Kelvin waves. As such, this scheme utilizes significantly more information compared to our previous algorithm which was based only on zonal mean temperatures and heating rates. The new model transport captures much of the qualitative structure and seasonal variability observed in long lived tracers, such as: isolation of the tropics and the southern hemisphere winter polar vortex; the well mixed surf-zone region of the winter sub-tropics and mid-latitudes; the latitudinal and seasonal variations of total ozone; and the seasonal variations of mesospheric H2O. The model also indicates a double peaked structure in methane associated with the semiannual oscillation in the tropical upper stratosphere. This feature is similar in phase but is significantly weaker in amplitude compared to the observations. The model simulations of carbon-14 and strontium-90 are in good agreement with observations, both in simulating the peak in mixing ratio at 20-25 km, and the decrease with altitude in mixing ratio above 25 km. We also find mostly good agreement between modeled and observed age of air determined from SF6 outside of the northern hemisphere polar vortex. However, observations inside the vortex reveal significantly older air compared to the model. This is consistent with the model deficiencies in simulating CH4 in the northern hemisphere winter high latitudes and illustrates the limitations of the current climatological zonal mean model formulation. The propagation of seasonal signals in water vapor and CO2 in the lower stratosphere showed general agreement in phase, and the model qualitatively captured the observed amplitude decrease in CO2 from the tropics to midlatitudes. However, the simulated seasonal amplitudes were attenuated too rapidly with altitude in the tropics. Overall, the simulations with the new transport formulation are in substantially better agreement with observations compared with our previous model transport.

Fleming, E. L.↗