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Crawford, A. J.

Publications and source records attributed to Crawford, A. J..

8 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

Global trends and annual releases of CCl3F and CCl2F2 estimated from ALE/GAGE and other measurements from July 1978 to June 1991

Thirteen years of Atmospheric Lifetime Experiment/Global Atmospheric Gases Experiment CCl3F and CCl2F2 measurements at five remote, surface, globally distributed sites are analyzed. Comparisons are made against shipboard measurements by the Scripps Institution of Oceanography (SIO) group and archived air samples collected at Cape Grim, Tasmania, since 1978. CCl3F in the lower troposphere was increasing at an average rate of 9.2 ppt/yr over the period July 1978 to June 1988. CCl2F2 was increasing at an average 17.3 ppt/yr in the lower troposphere over the same period. However, between July 1988 and June 1991 the increases of CCl3F and CCl2F2 in this region have averaged just 7.0 ppt/yr and 15.7 ppt/yr, respectively. The rate of increase has been decreasing 2.4 ppt/yr(exp 2) and 2.9 ppt/yr(exp 2) over this 3-year period. Based on a recent scenario of the global releases of these compounds and using the new calibration scale SIO 1993, the equilibrium lifetimes are estimated to be 44 +17/-10 and 180 +820/-81 years for CCl3F and CCl2F2, respectively. Using these lifetime estimates and a two-dimensional model, it is estimated that global releases of these two chlorofluorocarbons in 1990 were 249 +/- 28 x 10(exp 6) kg for CCl3F and 366 +/- 30 x 10(exp 6) kg for CCl2F2. It is also estimated that combined releases of these chlorofluorocarbons in 1990 were 21 +/- 5% less than those in 1986.

Cunnold, D. M.↗
NASA NTRS1986

Methane, carbon monoxide and methylchloroform in the Southern Hemisphere

New observational data on CH4, CO and CH3CCl3 in the Southern Hemisphere are reported. The data are analyzed for long term trends and seasonal cycles. CH3CCl3 data are used to scale the OH fields incorporated in a two-dimensional model, which in turn, is used to constrain the magnitude of a global CH4 source function. The possible causes of observed seasonality of CH3CCl3, CH4 and CO are identified, and several other aspects of observed CH4 variability are discussed. Possible future research directions are also given.

Fraser, P. J.↗
NASA NTRS1983

The atmospheric lifetime experiment. I - Introduction, instrumentation, and overview

The Atmospheric Lifetime Experiment is designed to determine accurately the atmospheric concentrations of the four halocarbons CFCl3, CF2Cl2, CCl4, and CH3CCl3, and also of N2O with emphasis on measurement of their long-term trends in the atmosphere. Comparison of these concentrations and trends for the four halocarbons with estimates of their industrial emission rates then enables calculations of their global circulation rates and globally averaged atmospheric lifetimes. The experiment utilizes automated dual-column electron-capture gas chromatographs which sample the background air about 4 times daily at the following globally distributed sites: Adrigole, Ireland, Cape Meares, Oregon; Ragged Point, Barbados; Point Matatula, American Samoa, and Cape Grim, Tasmania. The climatology of these 'clean air' sites and their ability to describe the global air mass are reviewed. The instrumentation and methods for data acquisition and processing are then described. An overview of the data obtained and the trends derived during the 3-year period from July 1978 through June 1981 for each of the five species being measured is presented.

Prinn, R. G.↗
NASA NTRS1983

The atmospheric lifetime experiment. III - Lifetime methodology and application to three years of CFCL3 data

Observations of the chlorofluorocarbon CFCl3 obtained several times daily over the period July 1978 to June 1981 at Adrigole, Ireland; Ragged Point, Barbados; Point Matatula, American Samoa; and Cape Grim, Tasmania are reported. In addition, observations at Cape Meares, Oregon are given for the period January 1980 to June 1981. On January 1, 1980, the average mixing ratio of CFCl3 in the lower troposphere is esimated to have been 168 pptv, and this is calculated to have been increasing 5.7 percent annually. Assuming that the only destruction of CFCl3 occurs in the stratosphere, the lifetime, on January 1, 1980, estimated by a trend technique is 83 + 73, or -27 years; the lifetime estimated from the global inventory of CFCl3 is to + 89 or -25 years. The maximum likelihood current lifetime estimate obtained by combining the estimates from both analysis techniques is 78 years.

Cunnold, D. M.↗
NASA NTRS1983

The Atmospheric Lifetime Experiment. IV - Results for CF2Cl2 based on three years data

Observations of dichlorodifluoromethane obtained several times daily over the period July 1978 to June 1981 at Adrigole, Ireland (52 deg N, 10 deg W), Ragged Point, Barbados (13 deg N, 59 deg W), Point Matatula, American Samoa (14 deg S, 171 deg W), and Cape Grim, Tasmania (41 deg S, 145 deg E), are reported. Observations at Cape Meares, Oregon (45 deg N, 124 deg W), are also given for the period November 1980 to June 1981. On January 1, 1980, the average mixing ratio of dichlorodifluoromethane in the lower troposphere is estimated to have been 285 pptv and to have been increasing at 6.0 percent/year. The atmospheric lifetime of this compound is estimated from this data by adjusting its destruction rate in a two-dimensional model of the atmosphere so as to provide the best fit to the observations. Assuming destruction of CF2Cl2 in the stratosphere only, the lifetime estimate for January 1, 1980, by the inventory technique is 69 + 36 or - 18 years. The trend technique principally provides a lower limit to the lifetime of 81 years. The results suggest a need for further assessment of dichlorodifluoromethane release estimates, particularly those from the USSR and eastern Europe.

Cunnold, D. M.↗
NASA NTRS1982

Natural and anthropogenic trace gases in the southern hemisphere

The complexity of the global environment makes it necessary that many important trace gases in the earth's atmosphere be measured on a global scale before predictions can be made regarding the effects of human activities on the environment. A description is presented of measurements of 14 atmospheric trace gases in the lower atmosphere (0-4 km) of the southern hemisphere. Concentrations are considered of CCl3F, CCl2F2, CHClF2, C2.Cl3.F3, CH3CCl3, CCl4, C2.Cl4, CH3I, CHCl3, CO, CH3Cl, CH4, N2O, and OCS. The obtained data are analyzed and interpreted to statistically quantify the possible differences of concentrations in and above the boundary layer, to model the vertical profile of CH3I, and to use the data in support of previous findings that CH4 is increasing in the atmosphere.

Rasmussen, R. A.↗
NASA NTRS1981

Trends of atmospheric methane in the Southern Hemisphere

Atmospheric observations spanning the past three years show that methane increased at 1.2 (plus or minus 0.3)% per year at Cape Grim in Tasmania (41 deg S). This rate of increase can be compared to the 1.9 (plus or minus 0.4)% per year observed at Cape Meares in Oregon (45 deg N) over the past two years. Over the corresponding period the concentration at Cape Grim increased by 1.4 (plus or minus 0.4)% per year. The Southern Hemisphere data also suggest seasonal variations with minimum concentrations in March and maximum in September. These results are based on 26 large-volume stable air samples collected cryogenically in stainless steel flasks and 75 smaller-volume air samples collected in glass flasks, all analyzed by a gas chromatograph using a flame ionization detector.

Fraser, P. J.↗