Polymorphism in Weberite Na 2 Fe 2 F 7 and its Effects on Electrochemical Properties as a Na-Ion Cathode
Not Available
25 ENERGY STORAGE↗
Engineering topics
Cui, Wei
Publications and source records attributed to Cui, Wei.
Architecting a Stable High-Energy Aqueous Al-Ion Battery
Aqueous Al-ion batteries (AAIBs) are the subject of great interest due to the inherent safety and high theoretical capacity of aluminum. The high abundancy and easy accessibility of aluminum raw materials further make AAIBs appealing for grid-scale energy storage. However, the passivating oxide film formation and hydrogen side reactions at the aluminum anode as well as limited availability of the cathode lead to low discharge voltage and poor cycling stability. Here, we proposed a new AAIB system consisting of an Al x MnO 2 cathode, a zinc substrate-supported Zn-Al alloy anode, and an Al(OTF) 3 aqueous electrolyte. Through the in situ electrochemical activation of MnO, the cathode was synthesized to incorporate a two-electron reaction, thus enabling its high theoretical capacity. The anode was realized by a simple deposition process of Al 3+ onto Zn foil substrate. The featured alloy interface layer can effectively alleviate the passivation and suppress the dendrite growth, ensuring ultralong-term stable aluminum stripping/plating. The architected cell delivers a record-high discharge voltage plateau near 1.6 V and specific capacity of 460 mAh g -1 for over 80 cycles. Finally, this work provides new opportunities for the development of high-performance and low-cost AAIBs for practical applications.
25 ENERGY STORAGE↗
A Chandra Spectroscopic Survey of Persistent Black Hole Candidates
We present results from observations of persistent black hole candidates with the High-Energy Transmission Gratings on board the Chandra X-Ray Observatory. The sources include LMC X-1, LMC X-3, GRS 1758-258, and Cyg X-1. Along with the published results on 1E 1740.7-2942, we have completed a high-resolution spectroscopic survey of such systems. The observed X-ray spectra of LMC X-1 and LMC X-3 show no prominent discrete features, while absorption edges (Mg K and Si K) are detected in the spectrum of GRS 1758-258. The edges are likely to be of interstellar origin. In most cases, the X-ray continuum can be described well by models that are often adopted in low-resolution studies of black hole candidates: a multitemperature disk spectrum plus a Comptonization component. However, the relative contribution of the two components varies greatly among different sources. For instance, only the disk component is present for LMC X-1 and GRS 1758-258, while the Comptonized component is required for other sources. We discuss general issues related to obtaining disk parameters from modeling X-ray continuum.
Cui, Wei↗
Chandra Observations of Cygnus X-1 at Different Spectral States and Different Orbital Phases
Cygnus X-1 has been observed in different spectral states and at different orbit phases with the Chandra High Energy Transmission Grating Spectrometer. The observed absorption line and edge features are different in these observations. These differences may be caused by the variations of the column density at different orbit phases in a photoionized-wind accretion system. The variations of the absorption features observed in different states may also provide information about changes in the configuration of the corona and accretion disk around the black hole. We present results of our data analysis and discuss the physical implications of these results.
Feng, Yixin↗
Evolution of Iron K Alpha Line Emission in the Black Hole Candidate GX 339-4
GX 339-4 was regularly monitored with the Rossi X-Ray Timing Explorer during a period (in 1999) when its X-ray flux decreased significantly (from 4.26 x 10(exp -10) to 7.6 x 10(exp -12) ergs in the 3-20 keV band), as the source settled into the 'off state.' Our spectral analysis revealed the presence of a prominent iron K alpha line in the observed spectrum of the source for all observations. The line shows an interesting evolution: it is centered at approx. 6.4 keV when the measured flux is above 5 x 10(exp -1) ergs per sq cm/s but is shifted to approx. 6.7 keV at lower fluxes. The equivalent width of the line appears to increase significantly toward lower fluxes, although it is likely to be sensitive to calibration uncertainties. While the fluorescent emission of neutral or mildly ionized iron atoms in the accretion disk can perhaps account for the 6.4 keV line, as is often invoked for black hole candidates, it seems difficult to understand the 6.7 keV line with this mechanism because the disk should be less ionized at lower fluxes (unless its density changes drastically). On the other hand, the 6.7 keV line might be due to a recombination cascade of hydrogen- or helium-like iron ions in an optically thin, highly ionized plasma. We discuss the results in the context of proposed accretion models.
Feng, Y. X.↗
Phase Lag and Coherence Function of X-Ray Emission from Black Hole Candidate XTE J1550-564
We report the results from measuring the phase lag and coherence function of X-ray emission from black hole candidate XTE J1550-564. These temporal X-ray properties have been recognized to be increasingly important in providing important diagnostics of the dynamics of accretion flows around black holes. For XTE J1550-564, we found significant hard lag-the X-ray variability in high-energy bands lags behind that in low-energy bands-associated both with broadband variability and quasi-periodic oscillation (QPO) . However, the situation is more complicated for the QPO: while hard lag was measured for the first harmonic of the signal, the fundamental component showed significant soft lag. Such behavior is remarkably similar to what was observed of microquasar GRS 1915+105. The phase lag evolved during the initial rising phase of the 1998 outburst. The magnitude of both the soft and hard lags of the QPO increases with X-ray flux, while the Fourier spectrum of the broadband lag varies significantly in shape. The coherence function is relatively high and roughly constant at low frequencies and begins to drop almost right after the first harmonic of the QPO. It is near unity at the beginning and decreases rapidly during the rising phase. Also observed is that the more widely separated the two energy bands are, the less the coherence function between the two. It is interesting that the coherence function increases significantly at the frequencies of the QPO and its harmonics. We discuss the implications of the results on the models proposed for black hole candidates.
Cui, Wei↗
Evidence for Doppler-Shifted Iron Emission Lines in Black Hole Candidate 4U 1630-47
We report the first detection of a pair of correlated the X-ray spectrum of black hole candidate 4U 1630-47 outburst, based on Rossi X-Ray Timing Explorer (RXTE) emission lines in during its 1996 observations of the source. At the peak plateau of the outburst, the emission lines are detected, centered mostly at approx. 5.7 and approx. 7.7 keV, respectively, while the line energies exhibit random variability approx. 5%. Interestingly, the lines move in a concerted manner to keep their separation roughly constant. The lines also vary greatly in strength, but with the lower energy line always much stronger than the higher energy one. The measured equivalent width ranges from approx. 50 to approx. 270 eV for the former, and from insignificant detection to approx. 140 eV for the latter; the two are reasonably correlated. The correlation between the lines implies a causal connection; perhaps they share a common origin. Both lines may arise from a single K & alpha; line of highly ionized iron that is Doppler shifted either in a Keplerian accretion disk or in a bipolar outflow or even both. In both scenarios, a change in the line energy might simply reflect a change in the ionization state of line-emitting matter. We discuss the implication of the results and also raise some questions about such interpretations.
Cui, Wei↗
Relativistic Astrophysics in Black Hole and Low-Mass Neutron Star Binaries LTSA98
My group, in close collaboration with Dr. Zhang's group at University of Alabama-Huntsville, have been systematically analyzing and re-analyzing a substantial amount of archival data from previous and ongoing X-ray missions, in order to study possible relativistic effects around stellar-mass black holes and neutron stars. Our effort has been focused primarily on the data from the Rossi X-ray Timing Explorer. We carefully studied interesting quasi-periodic X-ray variability in newly discovered black hole candidates (XTE J1859+226 and XTE J1550-564), which, as we had proposed earlier, could be caused by general relativistic process (e.g., frame dragging) around the central black hole. We also discovered an intriguing temporal correlation between X-ray photons at different energies that is associated with the quasi-periodic signals of interest. The results provided new insights into the physical origin of the phenomena. Furthermore, we studied the spectral lines of black hole candidates which provide another avenue for studying general relativistic processes around black holes. The lines-may originate in the relativistic jets (which could be powered by the spin of the black hole) or in the disk around the black hole, as in the cases of 4U 1630-47 and GX 339-4 (two well-known black hole candidates), and may thus be distorted or shifted due to relativistic effects. Of course, neutron star systems were not forgotten either. After examining the properties of newly discovered fast quasi-periodic variability (at kiloHertz) associated with such systems, we proposed a relativistic model to explain the origin of the signals. We have also started to use new great observatories in orbit (such as Chandra and XMM-Newton) to observe the sources that are of interest to us. Finally, interesting results were also been obtained from our collaborations with other groups who are interested in some of the same objects. Such collaborative efforts have greatly enhanced the project and will likely continue in the future.
Cui, Wei↗
Three-Layered Atmospheric Structure in Accretion Disks Around Stellar-Mass Black Holes
Modeling of the x-ray spectra of the Galactic superluminal jet sources GRS 1915+105 and GRO J1655-40 reveals a three-layered atmospheric structure in the inner region of the inner accretion disks. Above the cold and optically thick disk with a temperature of 0.2 to 0.5 kiloelectron volts, there is a warm layer with a temperature of 1.0 to 1.5 kiloelectron volts and an optical depth around 10. Sometimes there is also a much hotter, optically thin corona above the warm layer, with a temperature of 100 kiloelectron volts or higher and an optical depth around unity. The structural similarity between the accretion disks and the solar atmosphere suggests that similar physical processes may be operating in these different systems.
Zhang, S. N.↗
X-Ray Spectral Variations of X-Ray Nova XTE J1550-564 During the Rising Phase of the 1998 Outburst
No abstract available
Wu, Xuebing↗
Evolution of the Iron K-Alpha Emission Line in the Black Hole Candidate GX339-4 During and Outburst Decay Phase
The evolution of the iron K-alpha line emission feature was found from the black hole candidate GX339-4 when its X-ray flux (2 to 10 keV) decreased significantly. With RXTE observations, a broad line emission feature around 7 keV was detected in its quiescent and low flux state; while in the high flux state, an emission line feature around 6.4 keV was detected. A similar 6.4 keV line feature was also detected with previous ASCA observations in a high flux state. We consider that the evolution could be the evidence of the variations in the geometric structure and the physical properties of the accretion flow when the accretion rate changed. This is because that the 7 keV line feature can be produced by the radiative recombination cascade, collisional excitation, and fluorescence of Fe XXVI and Fe XXV, which can exist in a very high temperature plasma; while the 6.4 keV line feature can be produced by fluorescent K-alpha line emission of neutral iron atoms in the cold accretion disk. (copyright) 1999 American Astronomical Society. All rights reserved.
Feng, Y.↗
Discovery of a Three-Layered Atmospheric Structure in Accretion Disks around Stellar-Mass Black Holes
We have carried out systematic modeling of the X-ray spectra of the Galactic superluminal jet sources GRS 1915+105 and GRO J1655-40, using our newly developed spectral fitting methods. Our results reveal, for the first time, a three-layered structure of the atmosphere in the inner region of the accretion disks. Above the conanonly known, cold and optically thick disk of a blackbody temperature 0.2-0.5 keV, there is a layer of warm gas with a temperature of 1.0-1.5 keV and an optical depth of around 10. Compton scattering of the underlying disk blackbody photons produces the soft X-ray component we comonly observe. Under certain conditions, there is also a much hotter, optically thin corona above the warm layer, characterized by a temperature of 100 keV or higher and an optical depth of unity or less. The corona produces the hard X-ray component typically seen in these sources. We emphasize that the existence of the warm layer seem to be independent of the presence of the hot corona and, therefore, it is not due to irradiation of the disk by hard X-rays from the corona. Our results suggest a striking structural similarity between the accretion disks and the solar atmosphere, which may provide a new stimulus to study the common underlying physical processes operating in these vastly different systems. We also report the first unambiguous detection of an emission line around 6.4 keV in GRO J1655-40, which may allow further constraining of the accretion disk structure. We acknowledge NASA GSFC and MFC for partial financial support. (copyright) 1999: American Astronomical Society. All rights reverved.
Zhang, S. N.↗
Revisit to the RXTE and ASCA Data for GRO J1655-40: Effects of Radiative Transfer in Corona and Color Hardening in the Disk
The results of spectral modeling of the data for a series of RXTE observations and four ASCA observations of GRO J1655-40 are presented. The thermal Comptonization model is used instead of the power-law model for the hard component of the two-component continuum spectra. The previously reported dramatic variations of the apparent inner disk radius of GRO J1655-40 during its outburst may be due to the inverse Compton scattering in the hot corona. A procedure is developed for making the radiative transfer correction to the fitting parameters from RXTE data and a more stable inner disk radius is obtained. A practical process of determining the color correction (hardening) factor from observational data is proposed and applied to the four ASCA observations of GRO J1655-40. We found that the color correction factor may vary significantly between different observations and the finally corrected physical inner disk radius remains reasonably stable over a large range of luminosity and spectral states.
Zhang, S. Nan↗
Two-temperature models of old supernova remnants with ion and electron thermal conduction
To investigate the potential effects thermal conduction may have on the evolution of old supernova remnants, we present the results of 1D (spherically symmetric) numerical simulations of a remnant in a homogeneous interstellar medium for four different cases: (1) without thermal conduction; (2) with both electron and ion thermal conduction assuming equal temperatures; (3) with electron thermal conduction only, following electron and ion temperatures separately; and (4) with both electron and ion thermal conduction following separate temperatures. We followed the entire evolution until the completion of the remnant bubble collapse. Our most significant result is that in remnant evolution studies concerned principally with either the shell or bubble evolution at late times, reasonable results are obtained with single-temperature models. When the electron and ion temperatures are followed separately, however, ion thermal conduction cannot safely be ignored.
Cui, Wei↗