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D S Lauretta

Publications and source records attributed to D S Lauretta.

At least 19 records

Evidence of an Extended Period of Aqueous Alteration on the Bennu Parent Body Revealed By I-Xe Analyses

NASA’s OSIRIS-REx mission delivered to Earth 121.6 g of regolith material from asteroid Bennu on 24th September 2023. We report multi-step laser pyrolysis xenon isotopic analysis to investigate the I-Xe system in individual particles separated from aggregate material (a mixture of small particles of undefined lithology). The high sensitivity of the RELAX mass spectrometer allows us to observe small excesses of individual isotopes and separate out different components, which may not be possible using a conventional noble gas mass spectrometer. The temperature resolution of RELAX is sufficient to seek an I-Xe isochron from step heating analysis of a sample mass <100 μg, which can contribute to our understanding of the nature and timing of aqueous alteration on Bennu’s parent body. We also aim to better estimate and understand the iodine concentration of CI chondrite-like material.

S A Crowther↗

Bulk Elemental Composition of Aggregate Material From Asteroid Bennu

On September 24, 2023, NASA’s OSIRIS-REx mission returned pristine carbonaceous material from asteroid Bennu. One key aspect required to understand this returned material is to establish its bulk chemical composition. This is primarily due to each chondrite group having a distinct elemental composition, which is important both as a classification tool and for establishing the connections between the different chondrite groups. As the carbonaceous and non-carbonaceous chondrites are thought to have formed in the inner and outer protoplanetary disk, respectively, measuring the bulk elemental composition of Bennu material will help test the mission hypothesis that “Bennu's parent body formed beyond the snow line by accretion of material in the protoplanetary disk”. In addition, two further mission hypotheses — paraphrased as Bennu’s bulk elemental composition reflects that of its parent asteroid and is similar to the composition of the Sun and Bennu’s dominant lithologies are comparable in composition to the most aqueously altered carbonaceous chondrites — can be directly tested by bulk elemental analyses. Elemental analyses were undertaken on sample OREX-803015-0, a 20.66 mg aggregate sourced from inside the sample collector. All analyses were conducted using an iCAP Q ICP-MS. Overall, all 54 elements analyzed for the Bennu aggregate sample show similar abundances to those of the average CI chondrite, and thus the solar photosphere composition and some of the most aqueously altered carbonaceous chondrites. The elemental data also show that Bennu is indeed a carbonaceous asteroid that formed beyond the snow line by accretion of material in the protoplanetary disk. This Bennu aggregate sample appears similar in elemental composition to samples of asteroid Ryugu, yet without the small refractory element enrichments seen in Ryugu.

P Koefoed↗

Presolar Grains in Bennu: Constraints From C and N Isotopic Compositions

Primitive chondrites, including CI and CM types, are known to contain a rich variety of presolar grains that were seeded into the protoplanetary disk from neighboring stars and stellar objects prior to aggregation into asteroidal parent bodies. Stepped combustion using the FINESSE instrument at the Open University (OU) was employed to determine whether material from Bennu contains populations of presolar grains similar to those of CI and CM chondrites as well as recently returned samples from Ryugu.

M M Grady↗

Transmission Electron Microscopy of Carbonaceous Matter in Bennu Aggregate Samples

Preliminary analyses of regolith samples from asteroid Bennu show high bulk carbon abundances (~4.7 wt.%). The organic matter is readily apparent in scanning electron microscopy (SEM), transmission electron microscopy (TEM), and NanoSIMS observations. A major objective of the OSIRIS-REx mission is to understand the nature and origin of the pre-biotic organic matter inventory in Bennu samples. Here we report on TEM studies of indigenous organic matter in Bennu aggregate samples.

L P Keller↗

Hydrogen Isotopic Composition of Hydrous Minerals in Particles From Bennu

On September 24, 2023, NASA’s OSIRIS-REx mission delivered to Earth ~121 g of pristine carbonaceous regolith from asteroid Bennu. A first series of mineralogical observations and chemical/isotopic analyses of Bennu aggregate samples (fine to coarse particles up to a few mm) revealed that this material resembles the most chemically primitive chondrites and the samples returned by the JAXA’s Hayabusa2 mission from the carbonaceous asteroid Ryugu. Laboratory studies have confirmed the story gleaned from the spacecraft encounter that Bennu’s rock fragments underwent extensive aqueous alteration and are predominantly composed of hydrated minerals (serpentine, smectite) and other secondary minerals (e.g., magnetite, carbonates). The secondary phases were likely formed under the presence of liquid water on Bennu’s parent asteroid. The isotopic compositions of hydrous minerals and secondary phases can increase our understanding of the source and distribution of water and volatile elements in the protoplanetary disk [e.g., 5-8]. However, direct estimates of the hydrogen isotopic ratios (D/H) in hydrous minerals cannot be obtained easily in primitive rocks due to the difficulty in estimating the organic matter (OM) contribution to the whole H budget. In order to obtain hints on the initial constituents of Bennu’s parent asteroid and to test if Bennu's parent asteroid have formed beyond the snow line (hypothesis 4 of [9]), we measured the D/H and C/H ratios in chondritic matrices by secondary ion mass spectrometry (SIMS) and obtain information on the D/H ratio of water retained in the hydrated minerals. The method also gives clues on the hydrogen isotope variability among different Bennu rock fragments made available for measurement.

L Piani↗

Genetic Relationships and the Nucleosynthetic Heritage of the Asteroid Bennu

The OSIRIS-REx sample return mission visited the B-type asteroid Bennu and delivered 121.6 gof pristine material to Earth in September 2023. Genetic links between this pristine material and different meteorite groups can be determined using nucleosynthetic isotope variations. These variations reflect the heterogeneous distribution of isotopically distinct dust from different stellar environments within the protoplanetary disk. They can therefore be used to constrain different formation locations of parent asteroids [e.g., 1]. In addition, isotope variations are powerful tracers to establish the nucleosynthetic heritage of returned samples [e.g., 2] and to evaluate mixing and reservoir formation within the disk. Here we present nucleosynthetic Ti and Fe isotope data for samples from Bennu and several carbonaceous chondrites. We also report the Ti isotope composition of hand-picked matrix fractions from CR and CV meteorites.

M Rüfenacht↗

Organic Matter and Nanoglobules in Bennu Samples Revealed By Coordinated UV Fluorescence, SEM-EDX, and Two-Step Laser Mass Spectrometry

Carbonaceous meteorites are derived from asteroids, although specific parent bodies are generally unknown. However, on September 24, 2023, NASA’s Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission delivered regolith from the carbonaceous B-type asteroid (101955) Bennu, enabling coordinated laboratory analysis of pristine samples, with a well characterized geological context, from an asteroid of known provenance. One of primary mission goals [1] was the identification and characterization of primordial organic matter present in the returned samples. We report results from the coordinated analyses of Bennu samples using UV fluorescence, two-step laser mass spectrometry (μ-L2MS) and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX).

Asteroid Bennu↗

Nanoscale Mineralogy of Bennu Samples Returned by OSIRIS-REx

The OSIRIS-REx spacecraft returned regolith samples from asteroid Bennu and an initial sample was allocated for quick-look (QL) analyses. These QL particles were recovered from the avionics deck of the sample canister and were used to test the hypothesis that this dust is broadly representative of the bulk sample. The QL sample analyses showed that the materials are dominated by hydrated silicates, sulfides, magnetite, phosphates, and abundant organic matter, in addition to other minor/trace phases. Here we report our preliminary transmission electron microscope (TEM) observations for the nanoscale mineralogy of Bennu samples.

L P Keller↗

Identifying Solar Wind and Other Volatiles in Space-Weathered Samples From Asteroid Bennu

On September 24, 2023, NASA’s Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission returned >70 g of material from asteroid Bennu to Earth. The Sample Return Capsule was opened at NASA Johnson Space Center (JSC), and a spillover sample was collected from the avionics deck to perform quick-look (QL) analyses. In addition to providing a reconnaissance investigation of its mineralogy, the sample was also examined for evidence of surface exposure on asteroid Bennu by identifying signatures of space weathering. Space weathering changes the morphology, microstructure, and chemistry of regolith on the surfaces of airless bodies. Driven by micrometeoroid bombardment and solar wind irradiation, our understanding of how space weathering modifies particles on the surfaces of carbonaceous asteroids is still developing. To bolster the interpretation of remote sensing data and to further address driving Hypothesis 10, we must investigate the nanoscale structural and chemical changes in returned samples from Bennu to understand how space weathering affects carbonaceous surface materials. Here we explore evidence for solar wind irradiation in QL samples from asteroid Bennu.

M S Thompson↗

Bulk Major and Trace Elemental Composition of an Aggregate Sample From Asteroid Bennu

On September 24, 2023, NASA’s OSIRIS-REx mission returned a capsule to Earth carrying material from asteroid Bennu. This event was the first time a U.S. mission delivered pristine samples from an asteroid and is the largest asteroid sample return to date. As these samples represent some of the oldest, most primitive, and pristine materials available to us, and which originate from a known and well-studied asteroid, they allow us a rare opportunity to gain a better understanding of the formation and evolution of our solar system. Key to understanding the material returned from asteroid Bennu is establishing its bulk chemical composition. Previous studies have shown that each chondrite group has a distinct elemental composition. For the carbonaceous chondrites specifically, each group exhibits a distinct pattern of moderately and highly volatile elemental depletions, relative to CI chondrites. CI chondrites are considered the most primitive chondrite group and broadly represent the solar photosphere composition. The two most striking features of these depletion patterns is that the moderately volatile element depletions increase with decreasing 50% condensation temperature and then plateau out at abundances that roughly correlate with matrix abundance. Due to these distinctive patterns, bulk elemental composition has become an important classification tool for establishing the different chondrite groups and the connections between them. As such, determining the bulk chemical composition of the Bennu aggregates will help to test two mission hypothesis: “Bennu’s bulk elemental composition reflects that of its main parent asteroid and is similar to the composition of the Sun, with depletions in moderately to highly volatile elements” and “Bennu’s dominant lithologies are comparable in bulk mineralogy, petrology, and composition to the most aqueously altered carbonaceous chondrites” . Furthermore as the carbonaceous and non-carbonaceous chondrites are thought to have likely formed in the inner and outer protoplanetary disk, respectively (e.g., [8]), determining the bulk chemical compositions of the Bennu aggregates will also help test the major mission hypothesis that “Bennu's parent body formed beyond the snow line by accretion of material in the pro-toplanetary disk” . Regarding chondrite formation, observed elemental patterns have been successfully used to model how the mixing of volatile-rich and volatile-poor chondritic components can produce the observed carbonaceous chondrites groups. They have also been significant in investigating how volatilization processes influenced chondrite formation. As such, establishing bulk chemical compositions of the pristine Bennu samples is vital for understanding the asteroid, and solar system formation. To begin this processes, we analyzed the bulk major and trace elemental compositions of Bennu aggregates.

P Koefoed↗

The Potassium Isotope Composition of Aggregate Material From Asteroid Bennu

NASA’s OSIRIS-REx mission re-turned material from asteroid Bennu on September 24, 2023, marking the first time a U.S. mission has delivered asteroid samples to Earth, and the largest asteroid sample return to date. Due to the pristine nature of these primitive carbonaceous-rich samples, they allow us a rare opportunity to study our solar system’s formation to a degree not previously possible. Isotopes of moderately volatile elements (MVEs) have been recently developed as robust tracers for tracking different volatilization events within our Solar System. Of the MVEs, K has gained significant interest in recent years due to its ideal chemical and physical properties combined with technique improvements. Due to this, several recent studies have investigated the K isotope systematics within bulk chondrites and found an isotopic dichotomy be-tween the carbonaceous and non-carbonaceous chondrites (Figure 1), likely reflecting their different reservoirs which formed in the inner and outer protoplanetary disk respectively. Furthermore, systematic K isotope variations across the different carbonaceous chondrite groups and correlations with mass independent isotope systems such as Cr, Ti, and Ni, have also been observed. As a result, establishing the K isotope composition of bulk Bennu can be used to test the mission hypothesis that “Bennu’s parent asteroid accreted in the outer protoplanetary disk, beyond Jupiter, as recorded by distinct isotopic anomalies in a variety of elements” . In addition to early solar system processes, K isotopes can also be fractionated by space weathering as shown by comparisons between mature and immature lunar regolith. The degree of K isotope fractionation caused by space weathering correlates with the regolith maturity index and is an order of magnitude larger than what is observed in bulk meteorite samples which have not undergone strong space weathering processes. As such, the K isotope systematics of Bennu samples could provide an independent assessment of regolith maturity of the asteroid surface, helping to directly test the mission hypothesis that “Space weathering changed the chemistry and mineralogy of optically active surfaces” . In order to test both this hypothesis, and the hypothesis relating to Bennu’s accretion location, we aim to conduct high-precision K isotope analysis on bulk Bennu aggregates.

K Wang↗

Xenon Isotopic Analysis of Individual Intermediate Particles From the OSIRIS-REx Sample of Asteroid Bennu

The OSIRIS-REx mission sampled material from the B-type asteroid Bennu and delivered the sample to Earth on 24 September 2023. Here we present initial xenon isotopic analysis of individual intermediate particles of Bennu material collected by the OSIRIS-REx mission. Noble gases are key tracers of Solar System evolution. Xenon is particularly useful among the noble gases because its nine isotopes allow multiple contributing sources to be unambiguously identified. The sun, asteroids (as measured in meteorites), and comets (measured in the coma of comet 67P) have distinct xenon isotopic signatures reflecting different mixtures of nucleosynthetic components. In addition, 129 I, 238 U, and 244 Pu decay with different half-lives, producing characteristic xenon signatures. Exposure of samples containing light rare earth elements and barium to cosmic rays produces xenon from spallation and secondary neutron capture reaction. Noble gas analyses help address several of the driving hypotheses of the mission [9]. Particle-by-particle analysis can elucidate the diversity of material present and reveal distinct noble gas compositions, including the potential to detect presolar or cometary noble gas signatures on a small scale. The isotopic signature provides a fingerprint that can be used to constrain the sources of volatiles in planetary reservoirs and combined with other information (e.g. mineralogy and petrology of the material analyses) contributes to our understanding of the initial constituents, formation, and history of Bennu and its parent asteroid.

S A Crowther↗

Seismic Velocities of the Tagish Lake Meteorite: Exploring Sample Size Limits for Elastic Property Determination

Understanding the mechanical and elastic properties of rocks comprising asteroids is be-coming of greater practical importance as more spacecraft interact with them (e.g. OSIRIS-REx, Hayabusa2, DART). However, knowledge of asteroid lithologies’ physical properties is limited due to sample paucity and the resulting challenges that come with working with small samples. Measuring seismic velocities is one way to directly and indirectly (through relation-ships established with analog materials) explore elastic and strength properties, respectively, while minimizing use of available material. While sample preparation requires cutting, the seismic measurements are non-destructive.

physical properties↗

Search for Presolar Materials and Isotopically Anomalous Diffuse Insoluble Organic Matter in Samples From Asteroid 101955 Bennu

Carbonaceous asteroids allow us to study the original materials that formed the planets in the protoplanetary disk. They contain organic matter and (sub-)micrometer-size dust grains, called presolar grains, that condensed in the circumstellar envelopes of evolved stars and the ejecta of stellar explosions, such as novae and supernovae, before the formation of our Solar System. The isotopically anomalous organics are thought to have formed in the interstellar medium and the early Solar System. Whereas presolar grains provide insight into the building blocks of our Solar System, studying organics can help us understand the origin of life on Earth. These organics might have contributed to ingredients that helped life emerge. The return of samples from asteroid 101955 Bennu by NASA’s Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission gives us a new opportunity to elucidate the formation mechanism(s) and evolution of organics, as well as the abundance and distribution presolar grains in carbonaceous asteroids. Here, we report on our ongoing work to characterize the isotopic and chemical compositions, microstructure, distribution, and abundance of insoluble organic matter (IOM) and presolar grains in Bennu samples. This work supports hypotheses 2 and 3 of the OSIRIS-REx Sample Analysis Plan.

P. Haenecour↗

X-Ray Micro- and Nano-Tomography Analysis of Bennu Samples: A Preliminary Report

X-ray tomography (XCT) is an effective technique for obtaining the 3D structures of returned samples. XCT using synchrotron radiation provides high-resolution CT images with quantitative information. The XCT systems at SPring-8, an SR facility in Japan, have been used to analyze samples returned from the asteroids Itokawa and Ryugu. In this study, we plan to apply SR-XCT to samples returned from the asteroid Bennu.

A Tsuchiyama↗

Global geologic map of asteroid (101955) Bennu indicates heterogeneous resurfacing in the past 500,000 years

Global geologic maps are useful tools for efficient interpretation of a planetary body, and they provide global context for the diversity and evolution of the surface. We used data acquired by the OSIRIS-REx spacecraft to create the first global geologic map of the near-Earth asteroid (101955) Bennu. As this is the first geologic map of a small, non-spherical, rubble-pile asteroid, we discuss the distinctive mapping challenges and best practices that may be useful for future exploration of similar asteroids, such as those to be visited with the Hera and Janus missions. By mapping on two centimeter-scale global image mosaics (2D projected space) and a centimeter-scale global shape model (3D space), we generated three input maps respectively describing Bennu’s shape features, geologic features, and surface texture. Based on these input maps, we defined two geologic units: the Smooth Unit and the Rugged Unit. The units are differentiated primarily on the basis of surface texture, concentrations of boulders, and the distributions of lineaments, mass movement features, and craters. They are bounded by several scarps. The Rugged Unit contains abundant boulders and signs of recent mass movement. It also has fewer small(<20 m), putatively fresh craters than the Smooth Unit, suggesting that such craters have been erased in the former. Based on these geologic indicators, we infer that the Rugged Unit has the younger surface of the two. Differential crater size-frequency distributions and the distribution of the freshest craters suggest that both unit surfaces formed ~10–65 million years ago, when Bennu was located in the Main Asteroid Belt, and the Smooth Unit has not been significantly resurfaced in the past 2 million years. Meanwhile, the Rugged Unit has experienced resurfacing within the past ~500,000years during Bennu’s lifetime as a near-Earth asteroid. The geologic units are consistent with global diversity in slope, surface roughness, normal albedo, and thermal emission spectral characteristics. The site on Bennu where the OSIRIS-REx mission collected a regolith sample is located in the Smooth Unit, in a small crater nested within a larger one. So although the Smooth Unit is an older surface than the Rugged Unit, the impact-crater settingindicates that the material sampled was recently exposed. Several similarities are apparent between Bennu and asteroid (162173) Ryugu from a global geologic perspective, including two geologic units distinguishable by variations in the number density of boulders, as well as in other datasets such as brightness.

E R Jawin↗

Crater Population on Asteroid (101955) Bennu Indicates Impact Armouring and a Young Surface

The impactor-to-crater size scaling relationships that enable estimates of planetary surface ages rely on an accurate formulation of impactor–target physics. An armouring regime, specific to rubble-pile surfaces, has been proposed to occur when an impactor is comparable in diameter to a target surface particle (for example, a boulder). Armouring is proposed to reduce crater diameter, or prevent crater formation in the asteroid surface, at small crater diameters. Here, using measurements of 1,560 craters on the rubble-pile asteroid (101955) Bennu, we show that the boulder population controls a transition from crater formation to armouring at crater diameters ~2–3 m, below which crater formation in the bulk surface is increasingly rare. By combining estimates of impactor flux with the armouring scaling relationship, we find that Bennu’s crater retention age (surface age derived from crater abundance) spans from 1.6–2.2 Myr for craters less than a few meters to ~10–65 Myr for craters >100 m in diameter, reducing the maximum surface age by a factor of >15 relative to previous estimates. The range of crater retention ages, together with latitudinal variations in large-crater spatial density, indicate that ongoing resurfacing processes render the surface many times younger than the bulk asteroid.

Asteroids↗

Cross‐Instrument Comparison of MapCam and OVIRS on OSIRIS‐REx

Two of the instruments onboard the OSIRIS-REx spacecraft, the MapCam color imager and the OVIRS visible and 20 infrared spectrometer, observed the surface of asteroid (101955) Bennu in partially overlapping wavelengths. 21 Significant scientific advances have been enabled by using data from these two instruments in tandem, but a robust 22 statistical understanding of their relationship is needed for future analyses to cross-compare their data as accurately 23 and sensitively as possible. Here we present a cross-instrument comparison of data acquired by MapCam and 24 OVIRS, including methods and results for all global and site-specific observation campaigns in which both 25 instruments were active. In our analysis, we consider both the absolute radiometric offset and the relative 26 (normalized) variation between the two instruments; we find that both depend strongly on the photometric and 27 instrumental conditions during the observation. The two instruments have a large absolute offset (>15%) due to their 28 independent radiometric calibrations. However, they are very consistent (relative offset as low as 1%) when each 29 instrument’s response is normalized at a single wavelength, particularly at low phase angles where shadows on 30 Bennu’s rough surface are minimized. We recommend using the global datasets acquired at 12:30 pm local solar 31 time for cross-comparisons; data acquired at higher phase angles have larger uncertainties.

D R Golish↗