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Dalgarno, A.

Publications and source records attributed to Dalgarno, A..

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Radiative lifetimes of the second negative system of O2(+)

The dipole moment of the A2Pi(u)-X2Pi(g) transition of O2(+) is calculated as a function of internuclear distance using ab initio methods. The band absorption oscillator strengths and band transition probabilities of the second negative system are derived and the resulting lifetimes are compared with experimental data. The high-lying v double prime levels of the ground state may decay into low-lying v prime levels of the excited state. The corresponding radiative lifetimes are calculated.

Wetmore, R. W.↗
NASA NTRS1984

The dissociation of OH and OD in comets by solar radiation

Calculations of the radiative lifetimes of cometary OH are presented as a function of the radial velocity of the comet and of the velocity distributions of the hydrogen and oxygen atoms produced by photodissociation of OH. The contribution of the photodissociation of OH to the emission of the red and green lines of atomic oxygen is assessed. An estimate is made of the lifetime of OD and of the velocity distribution of the deuterium atoms.

Van Dishoeck, E. F.↗
NASA NTRS1984

The OI 989-A tropical nightglow

Attention is given to the morphology and origin of the OI 989 A emission in the tropical nightglow. Dielectronic recombination of O(+) is suggested as the mechanism responsible for populating the 3s' 3D0 state of this 2p4 3P 3s' 3D0 emission. The spectrometer used is that aboard the STP 78-1 satellite, which is in sun-synchronous orbit. The emission morphology is characterized by tropical arcs on each side of the dip equator.

Abreu, V. J.↗
NASA NTRS1984

Theory of collision-induced translation-rotation spectra: H2-He

An adiabatic quantal theory of spectral line shapes in collision-induced absorption and emission is presented which incorporates the induced translation-rotation and translation-vibration spectra. The generalization to account for the anisotropy of the scattering potential is given. Calculations are carried out of the collision-induced absorption spectra of He in collisions with H2 with ab initio electric dipole functions and realistic potentials. The anisotropy of the interaction potential is small and is not included in the calculations. The predicted spectra are in satisfactory agreement with experimental data though some deviations occur which may be significant. The rotational line shapes have exponential wings and are not Lorentzian. The connection between the quantal and classical theories is written out explicitly for the isotropic overlap induction.

Birnbaum, G.↗
NASA NTRS1983

Nitrogen escape from Mars

The escape rate of nitrogen from Mars is calculated to be 2.3 x 10 to the 5th per sec for low solar flux conditions and 8.9 x 10 to the 5th per sec for high solar flux conditions. The major source of energetic atoms is dissociative recombination of ground state and vibrationally excited N2(+) ions. The measured N-15/N-14 isotope ratio can be reproduced by postulating an early dense atmosphere during which little differentiation occurred.

Fox, J. L.↗
NASA NTRS1983

The photodissociation lifetimes of the OH and OD radicals in comets

The photodissociation rates of OH and OD molecules due to absorption of solar radiation in the X(2)Pi-A(2)Sigma(+) electronic transition are calculated to lie between 3.5 and 6.7 x 10 to the -6th/sec for OH for heliocentric velocities between -60 and +60 km/sec and at about 4.7 x 10 to the -7th/sec for OD at 1 AU from the sun. The corresponding lifetimes, which are upper bounds to the actual lifetimes, are generally consistent with the observational cometary data.

Singh, P. D.↗
NASA NTRS1983

The surface glow of the Atmosphere Explorer C and E satellites

Detailed line intensities of the rotational-vibrational spectrum of OH are calculated for various rates of population of sixteen bound vibrational levels in which the rotational level populations are in thermal equilibrium. The line intensities are convolved with the instrument function of the Visible Airglow Experiment on the AE C and E satellites to obtain spectra for comparison with the atmospheric data. Within the uncertainties, a model can be constructed that reproduces the observed spectrum. Synthetic spectra are computed for the OH Meinel system between 2000 A and 5.5 microns. The maximum intensity occurs between 1 micron and 2 microns.

Langhoff, S. R.↗
NASA NTRS1983

Data analysis and theoretical studies for atmospheric Explorer C, D and E

The research concentrated on construction of a comprehensive model of the chemistry of the ionosphere. It proceeded by comparing detailed predictions of the atmospheric parameters observed by the instrumentation on board the Atmospheric Explorer Satellites with the measured values and modifying the chemistry to bring about consistency. Full account was taken of laboratory measurements of the processes identified as important. The research programs were made available to the AE team members. Regularly updated tables of recommended values of photoionization cross sections and electron impact excitation and ionization cross sections were provided. The research did indeed lead to a chemistry model in which the main pathways are quantitatively secure. The accuracy was sufficient that remaining differences are small.

Dalgarno, A.↗
NASA NTRS1983

Photodissociation processes in the OH molecule

The potential energy curves of several excited states of OH of 2Sigma(+), 2Sigma(-), 2Pi, and 2Delta symmetries, and the transition moments connecting the excited states with the ground state and with each other, are calculated using two previously published theoretical models. The importance of the excited states in photodissociation is explored. Direct photodissociation by absorption into repulsive electronic states, as well as the contribution of absorption into bound electronic states, are discussed. Because they may participate in the photodissociation processes, several quartet states and one of the sextet spin multiplicity are investigated. The mechanism by which bound states can be dissociated are considered and estimates of the dissociation efficiencies of the mechanisms are made. Absorption into the bound 3 2Pi state may be an important dissociation channel. It is shown that OH is dissociated by the absorption of Lyman alpha radiation, a channel of particular significance in shocked interstellar gas and in cometary atmospheres.

Van Dishoeck, E. F.↗
NASA NTRS1983

The low-lying 2-sigma-minus states of OH

The configuration-interaction method is used to determine the electronic wave functions of the two lowest 2-sigma-minus states of OH using four different atomic orbital basis sets. Potential energy curves, transition moments, oscillator strengths, and photodissociation cross sections are obtained. Electronic transition dipole moments connecting the excited 1 2-sigma-minus and 2(D)2-sigma-minus states with each other and with the ground chi-2-pi state are presented as functions of internuclear distance. The theoretical absorption oscillator strengths for the D-2-sigma-minus(v prime = 0) from chi-2-pi(v double prime = 0) transition are in good agreement with the empirical value derived from astronomical measurement. The photodissociation cross sections for absorption from the v prime = 0, 1, and 2 levels of the ground state into the continuum of the 1 2-sigma-minus state are calculated, and the interstellar and cometary photodissociation rates are derived.

Van Dishoeck, E. F.↗
NASA NTRS1982

Molecular processes in comets

Potential energy curves for the two lowest 2 sigma- states of OH are computed at the configuration-interaction level using four different basis sets. Electronic transition dipole moments connecting the excited 1 2 sigma- and 2(D) 2 sigma- states with each other and with he ground X2pi state are presented as functions of internuclear distance. The theoretical absorption oscillator strengths for the D 2 sigma-(v prime=0) reverser to X 2pi (v prime prime=0) transition are in good agreement with the empirical value derived from astronomical measurements. The photodissociation cross sections for absorption rom the v prime prime=0,1, and levels of the ground state into the continuum of the 1 2 sigma- state are calculated, and the interstellar and cometary photodissociation rates are derived.

Dalgarno, A.↗
NASA NTRS1982

Radiative lifetimes and dipole moments of the A 2Sigma/+/, B 2Sigma /+/, and C 2Sigma/+/ states of OH

After describing independent theoretical studies of the eigenfunctions of the X 2Pi and excited A 2Sigma(+), B 2Sigma(+), and C 2Sigma(+) states of OH, results are presented for the transition dipole moments connecting each excited state to the others and to the ground state. The radiative lifetimes derived from calculation of the bound-bound and bound-free vibrational band transition probabilities are compared with measured values, confirming recent measurements of the A 2Sigma(+) and C 2Sigma(+) states but not the lifetimes measured for the B 2Sigma(+) state.

Langhoff, S. R.↗
NASA NTRS1982

The 2145 A dayglow and the high altitude nitric oxide density

It is argued that dissociative photoionization of N2 by solar ultraviolet radiation at wavelengths shorter than 329 A is a large source of atmospheric N(+)(5S 0 2) ions which radiate at 2143.6 A and 2139.7 A. Calculations of the daytime production of N(+)(5S 0 2) ions are carried out. The band pass of the instrument used to measure the intensity of the NO gamma band at 2150 A contains the N(+) emission wavelengths and we suggest that the NO densities at high altitudes may be affected.

Victor, G. A.↗
NASA NTRS1980

Molecular diagnostics of interstellar shocks

The chemistry of molecules in shocked regions of the interstellar gas is considered and calculations are carried out for a region subjected to a shock at a velocity of 8 km/sec. Substantial enhancements are predicted in the concentrations of the molecules H2S, SO, and SiO compared to those anticipated in cold interstellar clouds.

Hartquist, T. W.↗
NASA NTRS1979

The photochemistry of N/+/ ions

The photochemistry of N(+) ions in the daytime thermosphere is studied using the data base of the Atmosphere Explorer C Satellite. The reaction O(+) + N(2D) yields O + N(+) is considered a major source of N(+) ions at altitudes between 250 and 500 km. At altitudes below 300 km, N(+) is removed by reactions with O2, but at higher altitudes the reactions of N(+) with O and with H are the most important loss mechanisms. The empirical rate coefficients for reactions N(+) + O yields N and O(+) and N(+) + H yields N + H(+) are derived.

Constantinides, E. R.↗
NASA NTRS1979

Studies of interstellar absorption lines with IUE

The paper deals with a survey of interstellar absorption lines in the wavelength region from 1150 to 3200 A toward 25 stars. The spectra of 10 of these stars show very strong narrow absorption lines of Si IV and C IV. Lines of N V appear in eight directions. The N V lines can arise in the same gas that is responsible for the ubiquitous interstellar lines of O VI, observed previously with a Copernicus spectrometer, but the lines of Si IV and C IV must be formed in a cooler gas. The measured lines of Si IV and C IV can be produced by normal H II regions photoionized by the observed stars.

Black, J. H.↗