Darling, Robert Mason

DOE OSTI2023

Alkaline manganese redox flow battery with inhibitor

A redox flow battery includes a redox flow cell and a supply and storage system external of the redox flow cell. The supply and storage system includes first and second electrolytes for circulation through the redox flow cell. The first electrolyte is a liquid electrolyte having electrochemically active manganese species with multiple, reversible oxidation states in the redox flow cell. The electrochemically active manganese species may undergo reactions that cause precipitation of manganese oxide solids. The first electrolyte includes an inhibitor that limits the self-discharge reactions. The inhibitor includes an oxoanion compound.

Davenport, Timothy↗

DOE OSTI2022

Redox flow battery with improved efficiency

A method for a redox flow battery includes using a cell of a redox flow battery to store electrical energy and discharge the stored electrical energy. The using includes circulating a first electrolyte solution through a first circulation loop in fluid connection with the first electrode of the cell; circulating a second electrolyte solution through a second circulation loop in fluid connection with the second electrode of the cell; and at least one of a first element from the first electrolyte solution in the first electrode permeates through the separator layer and precipitates as a first solid product in the second electrode and a second element from the second electrolyte solution permeates through the separator layer and precipitates a second solid product in the first electrode. The method also includes removing at least a portion of the first solid product or the second solid product from the first electrode and the second electrode, respectively.

25 ENERGY STORAGE↗