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Davidson, J. A.

Publications and source records attributed to Davidson, J. A..

33 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Atmospheric infrared emission of ClONO2 observed by a balloon-borne Fourier spectrometer

ClONO2 was observed in high-resolution infrared emission spectra obtained on Nov. 6, 1984, by a balloon-borne Fourier spectrometer. The observations took place near 0300 LT at a latitude of 35 N. Spectral simulations are used to determine the mixing ratios of ClONO2. This analysis incorporates line by line calculations and new ClONO2 cross sections measured in the laboratory at 223 K. The inferred mixing ratios of ClONO2 are 1.3 + or - 0.45 ppb and 0.98 + or - 0.35 ppb at 14 and 34 mbar. One-dimensional photochemical model predictions are compared to the observations. The ClONO2 mixing ratio at 34 mbar appears to be larger than theory, while there is agreement at 14 mbar.

Massie, S. T.↗
NASA NTRS1987

Temperature variable long path cell for absorption measurements

The design and construction of a long path cell for absorption measurements at temperatures ranging from 215-470 K and at pressures from vacuum to 10 atm are described. The cell consists of three concentric stainless-steel tubes; the innermost tube is 6.5-in. in internal diameter, has a volume of about 47 l, and contains White-type optics, six thermocouples, and a gas input tube; and the outermost tube provides a vacuum Dewar around the inner assembly. The optical design and temperature control system for the long path temperature variable cell are examined. The long path cell is applicable for analyzing temperature and pressure dependence of spectra and reaction rates of gases, and the cell has flow and photolysis capabilities for studying transient species and photochemically initiated reactions. A diagram of the cell is provided.

Shetter, R. E.↗
NASA NTRS1987

Low-Luminosity embedded sources and their environs

A far-infrared and submillimeter study of regions within 0.03 pc of the low-luminosity sources embedded in the clouds B335, L723, B361, L1455, and L1551 is presented along with CO molecular line results on the extended environments of these sources out to 0.3 pc. Three of the embedded objects are definite bipolar outflow sources, one may be associated with an observed outflow, and one has no observable outflow. Data on the outflows are combined with determination of the luminosity of the embedded objects, and of the temperature and matter distribution about the sources, to infer the evolutionary stage of the embedded sources.

Davidson, J. A.↗
NASA NTRS1987

Carbon kinetic isotope effect in the reaction of CH4 with HO

The carbon kinetic isotope effect in the CH4 + HO reaction is measured experimentally and the use of carbon isotope ratios to diagnose atmospheric methane is examined. The chemical, photolysis, and analytical experimental conditions and procedures are described. It is determined that the CH4 + HO reaction has a carbon kinetic isotope effect of 1.010 + or 0.007 for k(12)k(13) (rate constants ratio) at 297 + or - 3 K. This value is compared with the data of Rust and Stevens (1980). Causes for the poor correlation between the data at high methane conversions are discussed. It is supposed that the difference between the k(12) and k(13) values is due to a difference in the activation energy of the two reactions.

Davidson, J. A.↗
NASA NTRS1984

Star Formation in Globules

The low mass star formation process was studied by application of submillimeter and supplementing far-infrared continuum observations by molecular line observations to the discovery and analysis of compact cores in molecular clouds with low luminosity. These dense regions are likely to be the sites where a cloud has recently collapsed or is still collapsing to form a star. Observations show that nonisotropic effects must play an important role in star formation. Four low luminosity sources embedded in the clouds L1551, B335, L1455 and L723 are presented. All these sources exhibit collimated bipolar molecular outflows of varying strengths. Data on the outflows are combined with determinations of mass, luminosity and temperature of the dust in the dense cores surrounding these embedded energy sources, to infer the evolutionary stage of the object. The possible role of the cores in channeling or generating the outflow is examined.

Davidson, J. A.↗
NASA NTRS1984

On the nature of the material surrounding Vega

Observations of Vega at 193 microns indicate that the far-infrared emission from the circumstellar material discovered by IRAS (Aumann et al. 1984) may decline more rapidly than a Planck spectrum at wavelengths greater than 100 microns. This suggests that the emitting particles may be smaller than the millimeter-sized objects proposed by Aumann et al. (1984). Small grains would be driven from the stellar system by radiation pressure, or their orbits would decay as a result of Poynting -Robertson drag. In order to maintain a state of dynamic equilibrium, a continuous supply of new particles would be required. It is hypothesized that the small grains are ejected by sublimation of volatile material from larger comet-like bodies in a partially coalesced preplanetary disk. A reservoir containing less than a few hundred earth masses could sustain the source over the lifetime of the star.

Harper, D. A.↗
NASA NTRS1984

Far-infrared and submillimeter observations of the multiple cores in S255, W3, and OMC-1 - Evidence for fragmentation?

The two cores of the S255 cloud were mapped at 60, 100, 185, and 400 microns and 40-400 microns maps were made of the cores and S255, OMC-1 and W3. Absolute flux densities were determined with an accuracy of 30 percent. The luminosities and masses of the S255 cores were equivalent to those of the other objects, including the concentration of a compact H II region around young objects. The densified regions are regarded as typical of areas where massive objects are forming. The observed 1.4-4 km/sec velocity differences between two cores in any one cloud indicates that the angular momentum of the original clouds, which drove the collapse of the cores, is transferred to the massive young stars.

Jaffe, D. T.↗
NASA NTRS1984

Far-infrared and submillimeter observations of the low-luminosity protostars L1455 FIR and L1551 IRS 5 - The confinement of bipolar outflows

Far-IR observations of L1455 FIR and L1551 IRS 5 obtained in December, 1981, and in September, 1982, and January, 1983, respectively, using the H-1 and G-2 bolometer systems on the 91-cm telescope of the NASA Kuiper Aiborne Observatory are reported. Additional observations at 400 microns were obtained with UKIRT in November, 1981, (L1551) and with NASA IRTF in November, 1982 (L1455). The results are presented in tables and graphs, and L1455 and L1551 are compared with other objects in terms of central-star parameters, clouds, and overflows. The characteristics calculated for L1455 and L1551 include luminosity 1.5 and 23 solar luminosity, size less than 7 x 10 to the 16th cm, H2 density greater than or equal to 4 x 10 to the 5th and 1 x 10 to the 6th/cu cm, and 35-K dust cores of 0.2 and 0.7 solar mass, respectively. The bipolar appearance of the L1551 outflow is attributed to circumstellar material only.

Davidson, J. A.↗
NASA NTRS1983

Far-infrared detection of low-luminosity star formation in the Bok globule B335

Measurements of far-infrared intensities in the Bok globule B335, made with higher spatial and spectral resolution than two earlier studies, are described. The NASA 3-m Infrared Telescope Facility was used in February 1981 and the Kuiper Airborne Observatory 0.9-m telescope was used in October 1981 and August 1982 for the observations. The far-infrared source in B335 was revealed to be more compact than previously assumed, ruling out the interstellar radiation field as the dominant heat source. The new far-infrared size, luminosity, and temperature derived suggest that these may be the first observations of low-mass star formation embedded deeply within a Bok globule. The far-infrared source does not have a near-infrared or radio continuum counterpart. High angular resolution at submillimeter wavelengths will be critical in further studies of low-mass star formation.

Davidson, J. A.↗
NASA NTRS1978

Temperature dependence of the rate constants for reactions of O/1D/ atoms with a number of halocarbons

Results are reported for an experimental study of the reactions of O(1D) with CCl4, CFCl3, CF2Cl2, CHFCl2, CHF2Cl, and CF2ClCFCl2 over the temperature range from 173 to 343 K, based on the time-resolved emission of O(1D) at 630 nm. The experiments involved photolysis of O3 by Nd-YAG laser pulses and measurements of 630-nm emission intensity in mixtures with He and the various halocarbons. Pseudo-first-order rate constants are derived from plots of the logarithms of the 630-nm emission intensities as a function of time for particular He/O3/halocarbon mixtures, and second-order rate constants are then obtained from plots of these pseudo-first-order rate constants as a function of halocarbon concentration at constant He and O3 concentrations. No temperature dependence of the second-order rate constants is observed over the range studied, within the precision of the measurements. It is found that the rate constants decrease as H is substituted for Cl in a halocarbon molecule and as F is substituted for H or Cl.

Davidson, J. A.↗
NASA NTRS1978

Rate constants for the deactivation of O/1D/ by Xe, Kr, and Ar over the range 110-330 K

The rate constants for the deactivation of O(1D) by Xe, Kr, and Ar were measured over the range 110-330 K. Only Xe had a significant temperature dependence. Its Arrhenius expression is (8.5 + or - 1.7) times 10 to the -11th power exp(-103 + or - 52)/RT cu cm/molecule-sec. The rate constants for Kr and Ar are (6.4 + or - 1.3) times 10 to the -12th power and (5.0 + or - 1.5) times 10 to the -13th power cu cm/molecule-sec, respectively. The observed trend in deactivation efficiency, Xe (greatest), Kr, Ar (least), and the observed temperature effects support the results and the spin-orbit interaction mechanism for deactivation given by Husain and co-workers.

Davidson, J. A.↗
NASA NTRS1978

Temperature dependence of the deactivation of O/1D/ by CO from 113-333 K

Absolute rate constants for the deactivation of O(1D) by CO have been measured at temperatures between 113 and 333 K. A very small temperature dependence is observed and is described by the Arrhenius expression (4.7 + or - 0.9) times 10 to the -11th power exp(126 + or 33)/RT cu cm/molecule-sec, where E is in cal/mol.

Davidson, J. A.↗
NASA NTRS1976

O2/1-Sigma sub g/+// relaxation in collisions - Temperature dependence of the interaction with HBr

Rate constants for the quenching of O2(1-Sigma sub g(+)) in the temperature range 170-400 K were obtained by observing the change in the rate of decay of this oxygen emission as a function of HBr concentration. At each temperature the decay was observed at eight different HBr concentrations ranging from 0 to 6 x 10 to the -6th moles/l. It is found that long range multipolar interactions make a major contribution to the quenching of the oxygen molecule by H2, with the quenching shown to be most effective at low temperatures. Short range repulsive interactions may also contribute to the quenching process, especially at high temperatures. The suggestion that the quenching process is dominated by the ability of the quencher to take up the energy of the oxygen molecule transition in vibrational and rotational motion is confirmed.

Braithwaite, M.↗
NASA NTRS1976

Absolute rate constant determinations for the deactivation of O/1D/ by time resolved decay of O/1D/ yields O/3P/ emission

Absolute rate constants for the deactivation of O(1D) atoms by some atmospheric gases have been determined by observing the time-resolved emission of O(1D) at 630 nm. O(1D) atoms were produced by the dissociation of ozone via repetitive laser pulses at 266 nm. Absolute rate constants for the relaxation of O(1D) at 298 K are reported for N2, O2, CO2, O3, H2, D2, CH4, HCl, NH3, H2O, N2O, and Ne. The results obtained are compared with previous relative and absolute measurements reported in the literature.

Davidson, J. A.↗