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De Bergh, Catherine

Publications and source records attributed to De Bergh, Catherine.

The abundance of sulfur dioxide below the clouds of Venus

We present a new method for determining the abundance of sulfur dioxide below the clouds of Venus. Absorption by the 3nu3 band of SO2 near 2.45 microns has been detected in high-resolution spectra of the night side of Venus recorded at the Canada-France Hawaii telescope in 1989 and 1991. The inferred SO2 abundance is 130 +/- 40 ppm at all observed locations and pertains to the 35-45 km region. These values are comparable to those measured by the Pioneer Venus and Venera 11/12 entry probes in 1978. This stability stands in contrast to the apparent massive decrease in SO2 observed at the cloud tops since these space missions. These results are consistent with laboratory and modeling studies of the SO2 destruction rates in the lower atmosphere of Venus. The new spectroscopic technique presented here allows a remote monitoring of the SO2 abundance below the clouds, a likely tracer of Venusian volcanism.

Bezard, Bruno↗

Ices on the surface of Triton

The near-infrared spectrum of Triton reveals ices of nitrogen, methane, carbon monoxide, and carbon dioxide, of which nitrogen is the dominant component. Carbon dioxide ice may be spatially segregated from the other more volatile ices, covering about 10 percent of Triton's surface. The absence of ices of other hydrocarbons and nitriles challenges existing models of methane and nitrogen photochemistry on Triton.

Cruikshank, Dale P.↗

Surface ices and the atmospheric composition of Pluto

Observations of the 1.4- to 2.4-micrometer spectrum of Pluto reveal absorptions of carbon monoxide and nitrogen ices and confirm the presence of solid methane. Frozen nitrogen is more abundant than the other two ices by a factor of about 50; gaseous nitrogen must therefore be the major atmospheric constituent. The absence of carbon dioxide absorptions is one of several differences between the spectra of Pluto and Triton in this region. Both worlds carry information about the composition of the solar nebula and the processes by which icy planetesimals formed.

Owen, Tobias C.↗

Deuterium on Venus - Observations from earth

Absorption lines of HDO and H2O have been detected in a 0.23-wave number resolution spectrum of the dark side of Venus in the interval 2.34 to 2.43 microns, where the atmosphere is sounded in the altitude range from 32 to 42 kilometers (8 to 3 bars). The resulting value of the D/H ratio is 120 + or - 40 times the telluric ratio, providing unequivocal confirmation of in situ Pioneer Venus mass spectrometer measurements that were in apparent conflict with an upper limit set from International UIltraviolet Explorer spectra. The 100-fold enrichment of the D/H ratio on Venus compared to earth is thus a fundamental constraint on models for its atmospheric evolution.

De Bergh, Catherine↗

Deuterium enrichment in the primitive ices of the protosolar nebula

On the basis of CH3D/CH4-ratio observations in the outer planets, the present effort to estimate the D/H ratio of the protosolar nebula's primitive ices arrives at two simple, yet effectively limiting models which constrain the degree of dilution undergone by deuterated volatiles through mixing with the initial hydrogen envelopes. These volatiles would have been contributed to planetary atmospheres by evaporated primordial ices. Ice D/H ratio model results of 0.0001 to 0.001 are compared with values for other potentially primitive material-containing bodies in the solar system, as well as with D/H ratio values from interstellar polyatomic molecules.

Lutz, Barry L.↗

The deep atmosphere of Venus revealed by high-resolution nightside spectra

The first high-resolution spectroscopic observations of the night side of Venus obtained in two narrow spectral windows centered at 1.74 and 2.3 microns, where the nightside is anomalously bright, are reported. Absorption features from CO2, CO, H2O, HDO, HCl, HF, and COS are detected, and there are a number of unidentified features. A preliminary analysis indicates that the observed radiation is thermal emission from atmospheric layers in the eight-bar pressure region for the 2.3 micron window and even deeper at 1.7 micron. The derived CO and H2O abundances agree with in situ Pioneer measurements in the deep troposphere and are consistent with the high deuterium enrichment inferred from Pioneer data. The first measurements of HCl and HF below the clouds are reported along with the first firm detection of COS.

Bezard, Bruno↗

Deuterium on Mars - The abundance of HDO and the value of D/H

Deuterium on Mars has been detected by the resolution of several Doppler-shifted lines of HDO near 3.7 micrometers in the planet's spectrum. The ratio of deuterium to hydrogen is (9 + or - 4) x 10 to the -4th; the abundance of H2O was derived from lines near 1.1 micrometers. This ratio is enriched on Mars over the telluric value by a factor of 6 + or - 3. The enrichment implies that hydrogen escaped more rapidly from Mars in the past than it does now, consistent with a dense and warm ancient atmosphere on the planet.

Owen, Tobias↗