Engineering topics

De Zafra, R. L.

Publications and source records attributed to De Zafra, R. L..

At least 19 records

NASA NTRS1995

Stratospheric ClO profiles from McMurdo Station, Antarctica, spring 1992

We describe ground-based measurements of ClO made at McMurdo Station, Antarctica, during September and October 1992. Vertical profiles were retrieved from molecular rotational emission spectra at 278 GHz. Peak mixing ratios of 1.6 +/- 0.3 ppbv were seen in mid-September at approximately 18 km altitude, suggestive of somewhat larger quantities than were measured at the same site and season in 1987. As the core of the polar vortex moved away from McMurdo by early October, the ClO mixing ratio at this altitude dropped to less than 0.2 ppbv, coincident with increasing temperature, ozone, and NO2. The diurnal variation of ClO was also observed. The lower stratospheric layer from 15 to 27 km was found to reach approximately midday abundance by 2 - 3 hours after sunrise. The column abundance in this layer began to decrease by the period 4 - 2 hours before sunset and had declined to approximately one quarter of its midday value by 2 - 0 hours before sunset. In contrast, the ClO column in the upper stratosphere, from 28 to 50 km, built up slowly until midday and remained large while sunlight persisted.

Emmons, L. K.↗

NASA NTRS1994

Arctic chlorine monoxide observations during spring 1993 over Thule, Greenland, and implications for ozone depletion

We have determined the vertical distribution of chlorine monoxide (ClO), from measurements of pressure-broadened molecular-emission spectra made over Thule, Greenland, during the 1993 Arctic spring. The measurements show a weak lower stratospheric layer of chlorine monoxide inside the vortex in late February, which was, however, significantly greater in mixing ratio than that seen in observations we made in the spring of 1992. ClO was also observed in much smaller quantities in early to mid-March 1993 when Thule was outside the vortex. The amount of ClO within the vortex was severely reduced by the time it returned over Thule in late March. This reduction occurred several weeks earlier relative to the winter solstice than the decline of ClO inside the Antarctic vortex in 1993. The enhanced Arctic lower stratospheric layer seen in late February 1993 at a nearly equivalent photochemical period, and beyond. We have calculated daily ozone loss rates, due primarily to the dimer chlorine catalytic cycle, from both sets of measurements. The vertical integral of the Arctic daily percentage ozone loss when the largest ClO levels were present, at the end of February, is found to be approximately one quarter of that in the Antarctic at a photochemical period only 1 week later. The relative weakness of daily ozone depletion, combined with the early disappearance of ClO in the Arctic, suggests that hemispheric dilution by ozone-poor air from within the Arctic vortex is unlikely to be sufficient to explain the historically extreme loss of midlatitude northern hemisphere ozone which began in 1992 and persisted throughout 1993.

Shindell, D. T.↗

NASA NTRS1994

An overview of millimeter-wave spectroscopic measurements of chlorine monoxide at Thule, Greenland, February-March, 1992: Vertical profiles, diurnal variation, and longer-term trends

Measurements of chlorine monoxide in the stratosphere over Thule, Greenland (73.6 N, 68.4 W) were made quasi-continuously during the period February 8 to March 24, 1992, using a high-sensitivity ground based mm-wave spectrometer. These observations give diurnal, short term, and long term changes in the mixing ratio and vertical distribution of ClO. At an equivalent time after the Antarctic winter solstice, very large concentrations (up to approximately 1.5 ppbv) occur in lower stratospheric ClO, resulting in massive ozone destruction. We saw no evidence for large (approximately 1 top 1.5 ppbv) amounts of ClO in the 16-25 km range over Thule in February or March, in agreement with UARS (satellite) observations by the MLS mm-wave spectrometer for this period, and in marked contrast to UARS/MLS and ER-2 aircraft measurements over northern Europe and eastern Canada, respectively, during January, 1992. We have evidence for smaller enhancements (approximately 0.2 to 0.5 ppbv) in the 18-30 km range during late February-early March, which could result from transport of residual low NO2 air following earlier polar stratospheric cloud (PSC) processing (the last of which occurred at least one month earlier, however) or the result of chemical processing by Pinatubo aerosols. Direct influence of Pinatubo aerosols on Arctic ozone during the spring of 1992 has been difficult to assess, and this enhancement of low-altitude ClO might be a significant indicator of aerosol effects.

De Zafra, R. L.↗

NASA NTRS1994

N2O as an indicator of Arctic vortex dynamics: Correlations with O3 over Thule, Greenland in February and March, 1992

We have recovered vertical profiles of stratospheric N2O from spectra observed using a ground-based mm-wave spectrometer during the Arctic spring. The measurements were made from Thule, Greenland (76.3 deg N, 68.4 deg W) on nine occasions from late February to late March, 1992 as part of the Upper Atmosphere Research Satellite (UARS) Correlative Measurements Program and the European Arctic Stratospheric Ozone Experiment (EASOE). During late February Thule was under inside edge of the Arctic vortex and mixing ratio profiles measured in that period are substantially reduced from typical high-latitude summer values. By late March the polar vortex had moved well away from Thule and N2O mixing ratios were greatly increased, coinciding with a basic change in circulation that brought in air from the Aleutian high. The motion of the vortex is also illustrated in the change in potential vorticity above Thule. A correlation with ozone balloonsonde data from Thule is made and compared to similar analyses of the Airborne Arctic Stratospheric Expedition (AASE) measurements. Within the sensitivity of our analysis, the correlation of N2O and O3 shows no evidence of ozone depletion within the vortex during this period; however, there is a distinct difference in the correlation inside and outside the vortex.

Emmons, L. K.↗

NASA NTRS1992

Effect of an applied magnetic field on the performance of a SIS receiver near 300 GHz

A superconductor-insulator-superconductor (SIS) receiver has been successfully constructed and tested for operation at 265 - 280 GHz using 1 micron/sq area Nb-AlO(x)-Nb tunnel junctions fabricated at Stony Brook. The best performance to date is a double sideband (DSB) receiver noise temperature of 129 K at 278 GHz. It is found that suppression of the Josephson pair currents with a magnetic field is essential for good performance and a stable dc bias point. Fields as high as 280 gauss have been used with no degradation of mixing performance. The improvement in the intermediate frequency output stability with progressively increasing magnetic fields is illustrated.

Mallison, W. H.↗

NASA NTRS1991

Measurement of the cooling capacity of an RMC-Cryosystems Model LTS 4.5-025 closed-cycle helium refrigerator

The cooling capacity of a recently purchased RMC-Cryosystems Model LTS 4.5-025 closed-cycle He refrigerator was measured over the range 4-35 K. It is found that the nominal cooling capacity of 250 mW is only met or exceeded over a narrow temperature range around 4.3 + or - 0.5 K, and that, above this range, there exists a considerable region of much lower cooling capacity, not exceeding about 100 mW. It is believed that this behavior results from use of a fixed-aperture Joule-Thompson expansion valve, and might be alleviated if the J-T valve could be adjusted to compensate for changing flow within the 5-20 K temperature range. Present performance may severely limit or prevent effective use in applications where an irreducible heat inflow exists which is greater than about 100 mW, yet substantially less than the quoted capacity at about 4 K.

De Zafra, R. L.↗

NASA NTRS1990

Measurement of atmospheric opacity at 278 GHz at McMurdo Station, Antarctica in austral spring seasons, 1986 and 1987

A quasi-continuous record is presented of atmospheric opacity measured at 278 GHz (1.1 mm wavelength) from the McMurdo Station (Antarctica) during austral spring seasons of 1986 (August 30 - October 30) and 1987 (September 4 - October 13) with measurements taken every 20 minutes (except during storms or other periods of high opacity). All data are reduced to represent opacity in the zenith direction. It was found that, during much of September, the two successive years differed considerably in tropospheric opacity. In 1986, water vapor and attendant opacity were generally lower, due to low tropospheric temperatures. Measured opacities were found to be higher than would be expected from the empirical relationships representing opacity as a function of water vapor column density at mm-wavelengths, as proposed by Rice and Ade (1979), Zammit and Ade (1981), and Liebe (1985).

De Zafra, R. L.↗

NASA NTRS1989

Measurements of stratospheric hydrogen cyanide at McMurdo Station, Antarctica - Further evidence of winter stratospheric subsidence?

Measurements of hydrogen cyanide in the springtime Antarctic stratosphere were made using ground-based millimeter wave spectroscopy. A steeper decrease in volume mixing ratio with altitude was found, than that found at tropical latitudes, from an assumed value of about 160 pptv in the troposphere to a value of 65 + or - 30 pptv at 40 km, which may be further evidence of substantial vertical subsidence of the Antarctic winter stratosphere.

Jaramillo, M.↗

NASA NTRS1989

New observations of a large concentration of ClO in the springtime lower stratosphere over Antarctica and its implications for ozone-depleting chemistry

New measurements of stratospheric chlorine monoxide (ClO) were made at McMurdo Station, Antarctica, during the austral spring of 1987. Rotational emission line spectroscopy, employing a ground-based detector, was used to determine mixing ratio profiles over the range about 17-45 km. A spectral band pass double that was used for similar measurements in 1986 allowed an improvement to be made in the definition of the anomalous low-altitude stratospheric ClO layer associated with springtime ozone depletion. A peak mixing ratio of 1.6 + or - 0.4 parts per billion by volume (ppbv) (95 percent confidence level) was found at 19.5 + or - 1 km at midday during the period September 20-24, 1987. The observed peak mixing ratio and diurnal behavior are discussed in relation to chemical depletion theories. Calculations indicate that the large observed ClO concentration provides an efficient closure for a catalytic Cl cycle through the ClO dimer mechanism, yielding good agreement with various observed features of O3 depletion.

De Zafra, R. L.↗

NASA NTRS1988

Formation of the Antarctic ozone hole by the ClO dimer mechanism

New measurements of the low-altitude ClO profile, made during September 1987, are presented along with detailed observations of ozone depletion over McMurdo Station, Antarctica during the same period. The results show that both the rate and altitude range of ozone depletion can be quantitatively accounted for by a mechanism in which the ClO dimer is the important intermediary in the catalytic destruction of ozone. An alternative bromine mechanism appears capable of contributing only 5-15 percent to the ozone loss rate.

Barrett, J. W.↗

NASA NTRS1988

Extremely low N2O concentrations in the springtime stratosphere at McMurdo Station, Antarctica

Measurements have been made of stratospheric N2O using the Stony Brook millimeter-wave remote sensing spectrometer at McMurdo Station, and NO2 mixing ratios are found that are less than 1.5 at 20 km and less than 1.10 at 25 km compared to values measured during the Antarctic summer. The observed mixing ratios are also much less than those predicted by global-scale models of stratospheric chemistry and dynamics. As the NO2 signal remained very weak when McMurdo was at the edges of the ozone hole and showed no signs of recovering during October, it is concluded that the geographical and temporal extent of the region of low NO2 is comparable to or greater than that of the ozone hole. These results argue against theories that require springtime upwelling to explain the Antarctic ozone hole. It is suggested that the air in the Antarctic lower stratosphere during late winter and early spring has been subjected to considerable downward transport.

Parrish, A.↗

NASA NTRS1988

mm-wave observations of stratospheric HCN at tropical latitudes

Middle and upper stratospheric HCN has been measured using ground-based mm-wave emission spectroscopy during a series of observations made in Mauna Kea, HI, in June 1986. A volume mixing ratio of 190 + or - 40 pptv at about 40 km, and a decrease of concentration with altitude that is considerably slower than that predicted by current models are found. This could be an indication of an atmospheric source of HCN as yet unidentified.

Jaramillo, M.↗

NASA NTRS1987

Nitrous oxide in the tropical middle atmosphere, observed by ground-based mm-wave spectrometry

Measurements of stratospheric N2O were made from Mauna Kea in Hawaii in June 1983, and in May and June 1986, by observing thermal emission of the molecule in a rotational transition at about 1 mm wavelength. Analyses of the data yield altitude profiles in the middle and upper stratosphere. Useful measurements of N2O may be made in one to two hours. The N2O profiles agree reasonably well with model predictions and with published satellite data, though significantly more N2O is reported near the stratopause than shown by the satellite measurement, and significantly more N2O in the middle stratosphere than in one of the models. The discrepancy between these data and the satellite measurement may be due in part to variations induced by the solar cycle.

Connor, Brian J.↗

NASA NTRS1987

Ozone over McMurdo Station, Antarctica, austral spring 1986 - Altitude profiles for the middle and upper stratosphere

In the austral spring of 1986, a program of measurements of the ozone altitude profile (for the z values between 25 and 55 km), relevant to an understanding of the ozone hole, was conducted at McMurdo Station, Antarctica. The measurements were performed using ground-based millimeter-wave spectrometry. It was found that the ozone mixing ratio peaked at altitudes ranging from 28 to 34 km, with peak values between 5 and 9 ppm by volume. During the period between September 12 and October 29, the ozone mixing ratio decreased, with great variability, by about 15 percent at 25 km, with no significant decrease at higher altitudes. The observation of the depletion occurring only below 25 km is consistent with ozone-sonde observations during previous years.

Connor, Brian J.↗

NASA NTRS1987

Additional atmospheric opacity measurements at lambda = 1.1 mm from Mauna Kea Observatory, Hawaii

Atmospheric opacity values in the zenith direction are given for a wavelength of 1.1 mm (278 GHz) at the summit of Mauna Kea in the Hawaiian Islands. A total of 75 days is covered during the period 1983-1986. Observations were made on a quasi-continuous basis, with opacity measured every 20 minutes around the clock for significant periods of time. A conversion from opacity at lambda = 1.1 mm to the equivalent precipitable water vapor column is given from the measurements of Zammit and Ade (1981), from which opacities at other wavelengths may be derived.

Parrish, A.↗

NASA NTRS1987

Feasibility of observations of stratospheric trace gases using the Hubble Space Telescope

The stellar occultation method has been successfully used in the past from orbiting observatories to measure concentrations of certain trace gases in the earth's mesosphere. The greatly improved spectroscopic capabilities of the Hubble Space Telescope (HST) have prompted recent suggestions for its use to measure stratospheric C10. This possibility is examined along with that for other species relevant to the chemistry of the ozone layer. It is concluded that stratospheric (as opposed to mesospheric) observations with HST are not practical, in part because of its orbital and pointing characteristics, but primarily because the high opacity of stratospheric ozone over most of the bandpass of the HST's most suitable spectrometer will obscure observation of other trace species, such as C10, having mixing ratios of less than 0.001.

Jaramillo, M.↗

NASA NTRS1985

An observed upper limit on stratospheric hydrogen peroxide

Observations collected by a ground-based heterodyne receiver of an emission from the 7(0.7)-6(1.5) rotational torsional transition of H2O2 at 270.610 GHz are studied. An integrated spectrometer output of the data obtained at Mauna Kea, Hawaii in late May and early June of 1983 is presented. The removal of the ozone line background profile from the data is described. With no signal detected in the output of a 256-channel filter spectrometer the calculation of an upper limit on stratospheric H2O2 is possible. The utilization of the mixing ratio profile of Sze and Ko (1984) to compute the limit of H2O2 is examined. An upper limit for H2O2 of approximately 1 x 10 to the 14th/cu cm between 30-50 km is established.

De Zafra, R. L.↗

NASA NTRS1984

A measurement of stratospheric HO2 by ground-based millimeter-wave spectroscopy

Stratospheric perhydroxyl (HO2) was measured by using a sensitive mm-wave receiver to obtain spectroscopic line profiles of three rotational emission lines in the vicinity of 265.8 GHz. The observations were carried out over four days in September-October 1982 at Mauna Kea, Hawaii and yield good agreement with the column density and vertical distribution predicted above 35 km by three representative two-dimensional photochemical models employing JPL 82-57 reaction rates and chemistry. Contrasts between current theoretical predictions and previous observations by Anderson et al. (1981) are pointed out for HO2 in the 28 to 37-km range, along with the difficulty of joining the latter with the present measurements through a monotonically varying vertical profile for HO2. A possible explanation involving strong temporal and spatial variation in stratospheric water vapor content is suggested.

De Zafra, R. L.↗