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Debra E. Kollonige

Publications and source records attributed to Debra E. Kollonige.

An Examination of the Recent Stability of Ozonesonde Global Network Data

The recent Assessment of Standard Operating Procedures for OzoneSondes (ASOPOS 2.0; WMO/GAW Report #268) addressed questions of homogeneity and long-term stability in global electrochemical concentration cell (ECC) ozone sounding network time series. Among its recommendations was adoption of a standard for evaluating data quality in ozonesonde time series. Total column ozone (TCO) derived from the sondes compared to TCO from Aura’s Ozone Monitoring Instrument (OMI) is a primary quality indicator. Comparisons of sonde ozone with Aura’s Microwave Limb Sounder (MLS) are used to assess the stability of stratospheric ozone. This paper provides a comprehensive examination of global ozonesonde network data stability and accuracy since 2004 in light of the sudden post-2013 TCO “dropoff” of ~3-4% that was reported previously at select stations (Stauffer et al., 2020). Comparisons with Aura OMI TCO averaged across the network of 60 stations are stable within about ±2% over the past 18 years. Sonde TCO has similar stability compared to three other TCO satellite instruments, and the stratospheric ozone measurements average to within ±5% of MLS from 50 to 10 hPa. Thus, sonde data are reliable for trends, but with a caveat applied for a subset of dropoff stations in the tropics and subtropics. The dropoff is associated with only one of two major ECC instrument types. A detailed examination of ECC serial numbers pinpoints the timing of the dropoff. However, we find that overall, ozonesonde data are stable and accurate compared to independent measurements over the past two decades.

Ryan M. Stauffer↗

Chapter 4 - Ozonesondes: Instrumentation and Data Applications

The ozonesonde instrument, launched on a standard weather balloon along with a radiosonde, has been used for more than 50 years to measure ozone concentrations in the troposphere to mid-stratosphere. The measurement is based on an electrochemical reaction, avoiding associated with optical techniques, and can achieve a 5% or better accuracy and precision when careful preparation and data-processing methods are employed. Instrument details are described and the global ozonesonde network illustrated. The use of the ozonesonde in the complement of ground-based instruments that validate satellite ozone instruments is described. Satellite data in turn help maintain consistency of long-term ozonesonde measurements.

tropospheric ozone↗

Tropical Tropospheric Ozone Trends (1990 to 2022): A Re-evaluation Based on SHADOZ and IAGOS Profiles and TOMS/OMI Columns

Changes in tropical tropospheric ozone (TTO) are of importance because this region spans roughly a third of the Earth and portions of it are experiencing variability in trends of ozone precursors (CO, NO x , CH 4 and nonmethane hydrocarbons) associated with economic growth and fires. In addition to ozone changes affecting radiative forcing, tropical ozone is an important source of the OH radical and thus, the oxidizing capacity of the planet (Thompson, 1992). Recent studies examining TTO trends satellite and in-situ observations over the past ~25 years include: Thompson et al., JGR, 2021; Gaudel et al., ACP, 2023; Stauffer et al., ACP, 2023. The results show considerable regional and seasonal variability in TTO trends and sensitivity to data selection, frequency, and statistical method used. The satellite data vary most widely in method, time period and reliability. Here we revisit trends for the 1990-2022 period with the best-characterized buv-based satellite products that span that period (derived from TOMS and OMI, Ziemke et al., 2019). The satellite-based trends are compared to trends based on in-situ data from the Southern Hemisphere Additional Ozonesondes (SHADOZ) network (1998-2022), measurements from selected pre-SHADOZ and IAGOS commercial aircraft data (Gaudel et al., 2023). Among sensitivities examined are the dependence of ozone trends on start and end years, impacts of ENSO events and the COVID-19 perturbation to emissions. Two statistical methods are used, quantile regression (QR) and multiple linear regression (MLR). Trends of total TTO, ozone segments in the boundary layer (to ~700 hPa), and free troposphere (700-300 hPa) are compared.

ozone, OMI, tropospheric ozone, SHADOZ↗